Deckblatt zum Sicherheitsdatenblatt Alkohol /...

Deckblatt erstellt: März 2017/jt

Deckblatt zum Sicherheitsdatenblatt überarbeitet am März 2017/ ersetzt alle bisherigen Versionen __________________________________________________________________________________

Handelsname: Alkohol / Ethanol Artikel-Nr. C0180 Verwendungszweck: Schulversuche gemäss Lehrmittel __________________________________________________________________________________ Lieferant: Bachmann Lehrmittel AG Lenzbüel 15 CH-8370 Sirnach Tel: 071 912 1910 [email protected] Nationale Notfallnummer: 145 (24h erreichbar, Schweizerisches Toxikologisches Zentrum, Zürich; für Anrufe aus der Schweiz, Auskünfte auf Deutsch, Französisch und Italienisch) __________________________________________________________________________________

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Sicherheitsdatenblatt gemäß Verordnung (EG) Nr. 1907/2006 Ausführung nach (EU) Nr. 453/2010

S15 Ethanoldenaturiert mit 2% Methylethylketon und 0.5% Methylisobutylketon

SDB Nr. 2.161, Erstellt am: 15.01.2015 / Revidiert am ... Version 1 / Ersetzt Version ...

| = Markierung von Änderungen gegenüber der Vorversion (bei späteren Versionen)

ABSCHNITT 1: Bezeichnung des Produkts und des Unternehmens

1.1 ProduktidentifikatorDieses Sicherheitsdatenblatt gilt für:

REACH-Registriernummer von Alcosuisse für Ethanol: 01-2119457610-43-0098 CAS-Nr. von Ethanol: 64-17-5

1.2 Relevante identifizierte Verwendungen des Gemischs und Verwendungen, von denen abgeraten wirdIdentifizierte Verwendungen gemäss der Verordnung (EG) Nr. 1907/2006 siehe:Beilage 1, Identifizierte Verwendungen, in der Datei "Beilage1_SDB_Ethanol_identif_Verwendungen.pdf" (siehe Abschnitt 16.4)Identifizierte Verwendungen, von denen abzuraten ist: keine Informationen verfügbar.

1.3 Einzelheiten zum Lieferanten, der das Sicherheitsdatenblatt bereitstelltHersteller / LieferantStraße / PostfachPostleitzahl / OrtTelefon / Telefax E-Mail für Auskünfte über das Sicherheitsdatenblatt:

Chemira GmbHAlpenblickstrasse 9CH-8853 Lachen+41 (0)71 971 48 80 / +41 (0)71 971 48 87 [email protected]

1.4 Notrufnummern

Nationale Notfallnummer: 145(Schweizerisches Toxikologisches Zentrum (STIZ), Zürich, 24 h erreichbar, für Anrufe aus der Schweiz)Schweizerisches Toxikologisches Zentrum für Anrufe aus dem Ausland: +41 (0)44 251 51 51

ABSCHNITT 2: Mögliche Gefahren

Denaturiertes Ethanol gilt gemäss Definition der Verordnung (EG) Nr. 1907/2006 als Gemisch

2.1 Einstufung des Gemischs Flam. Liq. 2; GHS02; H225 Flüssigkeit und Dampf leicht entzündbar.Eye Irrit. 2; GHS07; H319 Verursacht schwere Augenreizungen (bei Konzentration > 50 %).

2.2 Kennzeichnungselemente des GemischsPiktogramme:

GHS02, Flamme: GHS07, Ausrufzeichen:

Signalwort: Gefahr

Gefahrenhinweise:H225 Flüssigkeit und Dampf leicht entzündbar. H319 Verursacht schwere Augenreizungen.

Sicherheitshinweise:P210 Von Hitze/Funken/offener Flamme/heißen Oberflächen fernhalten. Nicht rauchen.P233 Behälter dicht verschlossen halten.P241 Explosionsgeschützte elektrische Betriebsmittel/Lüftungsanlagen/Beleuchtung verwenden.P243 Vorbeugende Massnahmen gegen elektrostatische Aufladungen treffen.P280 Schutzhandschuhe/Schutzkleidung/Augenschutz/Gesichtsschutz tragen.P305+P351+ P338 BEI KONTAKT MIT DEN AUGEN einige Minuten lang behutsam mit Wasser ausspülen. Eventuell vorhandene Kontaktlinsen entfernen, sofern leicht möglich. Weiter spülen.

2.3 Sonstige GefahrenEthanol entspricht nicht den Kriterien für vPvB und/oder PBT gemäss der Verordnung (EG) Nr. 1907/2006, Anhang XIII.EUH018: Kann bei Verwendung explosionsfähige/entzündbare Dampf/Luftgemische bilden.


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ABSCHNITT 3: Zusammensetzung/Angaben zu Bestandteilen

3.1 Stoffe: Denaturiertes Ethanol gilt gemäss der Definition der Verordnung (EG) Nr. 1907/2006 als Gemisch.

3.2 GemischeBeschreibung: Gemisch aus den nachfolgend angeführten Stoffen:

ETHANOL Registriernummer: 01-2119457610-43-0098EG-Nr.: 200-578-6CAS-Nr.: 64-17-5Indexnummer: 603-002-00-5Anteil : ca. 91.5 % (m/m)Einstufung gemäß Verordnung (EG) Nr. 1272/2008: Flam. Liq. 2; GHS02; H225

Eye Irrit. 2; GHS07; H319Signalwort: Gefahr

METHYLETHYLKETON (MEK); 2-BUTANONEG-Nr.: 201-159-0CAS-Nr. : 78-93-3Anteil : 2 % (m/m)Einstufung gemäß Verordnung (EG) Nr. 1272/2008: Flam. Liq. 2; GHS02; H225

Eye Irrit. 2; GHS07; H319STOT SE 3; GHS07; H336Signalwort: Gefahr

4-METHYL-2-PENTANON; (Methylisobutylketon, MIBK)EG-Nr.: 203-550-1CAS-Nr. : 108-10-1Anteil: 0.5 % (m/m)Einstufung gemäß Verordnung (EG) Nr. 1272/2008: Flam. Liq. 2; GHS02; H225

Acute Tox. 4; GHS07; H332Eye Irrit. 2; GHS07; H319STOT SE 3; GHS07; H335EUH066Signalwort: Gefahr

Wassergehalt: ca. 5.8 % (m/m)

Für den Wortlaut der in den Abschnitten 2 und 3 verwendeten Abkürzungen siehe Abschnitt 16.

ABSCHNITT 4: Erste-Hilfe-Maßnahmen

4.1 Beschreibung der Erste-Hilfe-MaßnahmenBei Auftreten von Beschwerden / Gesundheitsstörungen Arzt zuziehen.Nach Einatmen:Person an die frische Luft bringen. Bei Reizung der Atemwege durch das Produkt, Arzt aufsuchen.Bei Bewußtlosigkeit: Lagerung und Transport in stabiler Seitenlage.Nach Hautkontakt:Sofort mit Wasser abwaschen, nachspülen. Verunreinigte Kleidungsstücke unverzüglich entfernen.Bei andauernder Hautreizung Arzt aufsuchen. Nach Augenkontakt:Sofort einige Minuten lang vorsichtig mit Wasser ausspülen. Eventuell vorhandene Kontaktlinsen entfernen, sofern leicht möglich. Weiter ausspülen.Bei anhaltender Augenreizung ärztliche Hilfe hinzuziehen.Nach Verschlucken:Sofort gründliches Ausspülen des Mundes und Wasser (etwa 2 Trinkgläser) nachtrinken. Kein Erbrechen herbeiführen, sofort Arzthilfe zuziehen. Nie einer bewusstlosen Person etwas einflössen.Falls Erbrechen eintritt, sicherstellen, dass die Atemwege frei bleiben, damit keine Erstickungsgefahr besteht.

4.2 Wichtigste akute und verzögert auftretende Symptome und Wirkungen: Kopfschmerz, Benommenheit, Schwindel, Bewusstlosigkeit, Übelkeit.Kontakt mit den Augen verursacht schwere Augenreizung.

4.3 Hinweise auf ärztliche Soforthilfe oder Spezialbehandlung:Bei Bewusstlosigkeit: sofort Notarzt alarmieren.

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ABSCHNITT 5: Maßnahmen zur Brandbekämpfung

5.1 LöschmittelCO2, Löschpulver oder Wassersprühstrahl.Größeren Brand mit Wassersprühstrahl oder alkoholbeständigem Schaum bekämpfen. Aus Sicherheitsgründen ungeeignete Löschmittel: Wasser im Vollstrahl.

5.2 Besondere vom Gemisch ausgehende GefahrenExplosionsfähige Gemische der Dämpfe mit Luft können sich schon bei Raumtemperatur bilden.Entweichende Dämpfe sind schwerer als Luft und können sich in Gruben, Kellern etc. ansammeln (Explosionsgefahr).Dämpfe können dem Boden entlang grössere Strecken bis zu einer Zündquelle zurücklegen und zurückzünden.In die Kanalisation gelangendes Ethanol und dessen Dämpfe können darin eine Explosion bewirken.Bei Brand können schwarzer Rauch und gefährliche Dämpfe/Gase entstehen: Kohlenmonoxid, Kohlendioxid.Bei Erhitzung können die Fässer platzen und dadurch explosionsfähige Dampf-Luftgemische freigesetzt werden.

5.3 Hinweise für die BrandbekämpfungNicht geschützte Personen fernhalten. Rauch, Brandgase und Dämpfe nicht einatmen.Aufenthalt im Gefahrenbereich nur mit umluftunabhängigem Atemschutzgerät und Vollschutzanzug. Gefährdete Behälter aus sicherer Entfernung mit Wassersprühstrahl kühlen. Eindringen des Löschwassers in Oberflächen- und Grundwasser sowie in den Boden verhindern.Hautkontakt durch Tragen geeigneter Schutzkleidung und durch Einhalten eines Sicherheitsabstandes vermeiden.

5.4 Hinweis auf die Explosionseigenschaften des Dampf-Luft-GemischsSiehe Abschnitte 9.1 und 9.2.

ABSCHNITT 6: Maßnahmen bei unbeabsichtigter Freisetzung

6.1 Personenbezogene Vorsichtsmaßnahmen, Schutzausrüstungen und in Notfällen anzuwendende VerfahrenSchutzausrüstung gemäss Abschnitt 8.2.2 tragen. Ungeschützte Personen vom Gefahrenbereich fernhalten. Ausreichende Lüftung sicherstellen. Dämpfe nicht einatmen.Bei unzureichender Lüftung Atemschutz verwenden (gemäss Abschnitt 8.2.2). Improvisierte Ventilations- und Beleuchtungseinrichtung muss explosionsgeschützt sein.Zündquellen entfernen. Elektrostatische Aufladungen vermeiden. Nicht rauchen.Abfliessen von Dämpfen in Kanalisation, Gruben und Keller verhindern (Explosionsgefahr).Schutzmaßnahmen gemäss Abschnitt 7.1 beachten und Persönliche Schutzausrüstung gemäss Abschnitt 8.2.2 tragen.

6.2 UmweltschutzmaßnahmenWeitere Freisetzung in die Umwelt verhindern, sofern gefahrlos möglich.Nicht in die Kanalisation/Oberflächenwasser/Grundwasser, resp. in Gruben oder Keller gelangen lassen. Beim Umgang mit grösseren Mengen Notsperren, Schachtabdeckungen etc. vorsorglich bereithalten.Bei Eindringen in Gewässer oder Kanalisation die zuständige Behörde benachrichtigen.

6.3 Methoden und Material für Rückhaltung und ReinigungFür ausreichende Lüftung sorgen. Nur explosionsgeschützte Geräte und funkenfreie Werkzeuge etc. einsetzen.Nicht mit Wasser oder wässrigen Reinigungsmitteln wegspülen.Mit flüssigkeitsbindendem Material (Sand, Kieselgur, Säurebinder, Universalbinder, Sägemehl) aufnehmenund in geeigneten, verschliessbaren, etikettierten Behältern sammeln. Vorsicht: Mit Ethanol getränkte Flüssigkeitsbindemittel, auch Putztücher sind extrem feuergefährlich!Wenn bei grösseren Mengen Abpumpen erforderlich ist: Nur explosionsgeschützte Pumpen oder Sauggeräte verwenden!Das aufgenommene Material kann normalerweise im Einvernehmen mit den zuständigen Behörden über eine Kläranlage entsorgt werden. Andernfalls gemäss Abschnitt 13 entsorgen.

6.4 Verweis auf andere AbschnitteInformationen zur sicheren Handhabung siehe Abschnitt 7. Informationen zur persönlichen Schutzausrüstung siehe Abschnitt 8.2.2Informationen zur Entsorgung siehe Abschnitt 13.

ABSCHNITT 7: Handhabung und Lagerung

Achtung: Ungereinigte "leere" Behälter können Dampf-Luftgemische enthalten, die hoch explosionsgefährlich sind. Daran oder in deren Nähe nie bohren, schneiden, schleifen, löten, schweissen etc.! Keine "leeren" Fässer an Mitarbeitende/Private abgeben!

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7.1 Schutzmaßnahmen zur sicheren HandhabungKritische Eigenschaften von EthanolAuslaufendes Ethanol ist hoch entzündlich! Es können sich schon bei Raumtemperatur explosible Dampf-Luftgemische bilden.Entweichende Dämpfe sind schwerer als Luft und können sich in Gruben, Kellern etc. ansammeln (Explosionsgefahr).Ethanol kann sich elektrostatisch aufladen.

VorsichtsmassnahmenGefäße nicht offen stehen lassen. Das Einatmen von Dämpfen, Aerosolen und Nebeln vermeiden. Für gute Belüftung/lokale Absaugung am Arbeitsplatz sorgen. Lösungsmittelbeständige, funkenfreie Geräte verwenden.Für gute Raumbelüftung auch im Bodenbereich sorgen (Bodenabsaugung, konzentrierte Dämpfe sind schwerer als Luft). Alle für den Umgang mit hochentzündlichen Lösungsmitteln üblichen Explosionsschutzmassnahmen treffen, zum Beispiel:. ATEX-konforme mobile elektrische Geräte, sowie Einrichtungen für Beleuchtung, Ventilation und Handhabung.Behälter und Geräte zum Umfüllen leitend miteinander verbinden und erden, um statisch Aufladung zu vermeiden.Schuhe mit leitfähigen Sohlen tragen. Leitfähigkeit des Fussbodens gewährleisten (keine Plastikfolien, Chemikalienbeläge etc.)Ethanol nie mit Druckluft fördern! Nur explosionsgeschützte Pumpen verwenden.Expositions-Schutzmassnahmen gemäss Abschnitt 8 treffen. Schutzbrille tragen! Am Arbeitsplatz muss eine Augendusche verfügbar sein.Am Arbeitsplatz nicht essen, trinken oder rauchen.

7.2 Bedingungen zur sicheren Lagerung unter Berücksichtigung von Unverträglichkeiten.Hinweise zum Brand- und ExplosionsschutzExplosionsfähige Dampf/Luft-Gemische können sich schon bei Raumtemperatur (ab etwa 9 °C) bilden. Verschüttetes Material ist feuergefährlich. Explosionsfähige Dämpfe sind schwerer als Luft. Eindringen von Dämpfen in Kanalisation, Gruben und Keller verhindern.Zündquellen fernhalten/entfernen - nicht rauchen.Generell Maßnahmen gegen elektrostatische Aufladung treffen. Schuhe mit leitfähigen Sohlen tragen etc.Explosionsgeschützte Geräte/Armaturen und funkenfreie Werkzeuge verwenden. Von oxidierend wirkenden, brandfördernden und weiteren im Abschnitt 10.3 erwähnten Stoffen fernhalten.

Angaben zu den Lagerbedingungen Nur explosionsgeschützte Elektromaterialien, elektrische Geräte, Beleuchtung, Lüftung etc. verwenden.In etikettierten, gut verschlossenen Gebinden (Ethanol ist hygroskopisch) bei 5 bis 35 °C und trocken in gut belüfteten, explosionsgeschützten Räumen oder im Freien lagern. Vor Hitze und Sonneneinstrahlung schützen.Über Bodenwanne mit lösungsmittelbeständigem und dichtem Fußboden ohne Abfluss lagern. Nur Original-Behälter oder Behälter verwenden, die für Ethanol zugelassen sind (Ethanol korrodiert Aluminium!).Zutritt von unbefugten Personen verhindern.

Zusammenlagerungshinweise Lagerklasse VCI: 3A (Entzündliche flüssige Stoffe) Getrennt von Lebensmitteln und Futtermitteln lagern. Nicht zusammen mit oxidierenden, sauren und anderen nicht mit der Klasse 3A kompatiblen Stoffen lagern.

Mengenbegrenzungen Die Mengenbegrenzungen für die gelagerten Mengen in Abhängigkeit von den Lagerbedingungen beachten, siehe: "Brandschutzrichtlinie/Brennbare Flüssigkeiten" der Vereinigung Kantonaler Feuerversicherungen VKF, Bern.Die Mengenschwelle für die Unterstellung des Betriebs unter die Schweizer Störfallverordnung ist 20 000 kg.

7.3 Spezifische EndanwendungenBreites Anwendungsgebiet, siehe Beilage 1 "Identifizierte Verwendungen" in der Datei:"Beilage1_SDB_Ethanol_identif_Verwendungen.pdf", siehe Abschnitt 16.4 "Ergänzende Dokumente".

ABSCHNITT 8: Begrenzung und Überwachung der Exposition / Persönliche Schutzausrüstung

8.1 Zu überwachende Parameter (Schweizer Grenzwerte am Arbeitsplatz 2015)ETHANOL (CAS-Nr.: 64-17-5)Kurzzeitgrenzwert (4 x 15 Minuten): 1920 mg/m3, 1000 ml/m3MAK-Wert: 960 mg/m3, 500 ml/m3Hinweise:Schwangerschaftsgruppe C (keine Schädigung des Fötus bei Einhaltung der Grenzwerte)

METHYLETHYLKETON (CAS-Nr.: 78-93-3)Kurzzeitgrenzwert (4 x 15 Minuten): 590 mg/m3, 200 ml/m3MAK-Wert: 590 mg/m3, 200 ml/m3Hinweise:B: Methode für biologisches Monitoring ist verfügbar.BAT-Wert (Urin-Probenahme bei Expositionsende): 5 mg/lC: Schwangerschaftsgruppe C (keine Schädigung des Fötus bei Einhaltung der Grenzwerte) H: Hautgängig (Vergiftung über Hautkontakt ist möglich)

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4-METHYL-2-PENTANON (CAS-Nr.: 108-10-1)Kurzzeitgrenzwert (4 x 15 Minuten): 164 mg/m3, 40 ml/m3MAK-Wert: 82 mg/m3, 20 ml/m3Hinweise:B: Methode für biologisches Monitoring ist verfügbar.BAT-Wert (Urin-Probenahme bei Expositionsende): 2 mg/lC: Schwangerschaftsgruppe C (keine Schädigung des Fötus bei Einhaltung der Grenzwerte)H: Hautgängig (Vergiftung über Hautkontakt ist möglich),

Gemeinschaftliche Grenzwerte (gemäss den Richtlinien 91/322/EWG, 2000/39/EG, 2006/15/EG)METHYLETHYLKETON (CAS-Nr.: 78-93-3)Kurzzeitgrenzwert: 900 mg/m3, 300 ml/m3MAK-Wert (8 Stunden): 600 mg/m3, 200 ml/m3

4-METHYL-2-PENTANON (CAS-Nr.: 108-10-1)Kurzzeitgrenzwert: 208 mg/m3, 50 ml/m3MAK-Wert (8 Stunden): 83 mg/m3, 20 ml/m3

DNEL- und PNEC-Werte von ETHANOLDNEL = Derived No Effect Level (Konzentration oder Dosis, unterhalb welcher keine Wirkung auf den Menschen zu erwarten ist).

PNEC = Predicted No Effect Concentration (Konzentration, bei der keine Wirkung auf die Umwelt zu erwarten ist)

Exp-F = Extrapolationsfaktor

DNEL-Werte ArbeitsplatzwerteLokal akut, inhalativ DNEL = 1900 mg/m3Systemische Toxizitätseffekte chronisch, oral DNEL = 343 mg/kg pro TagSystemische Toxizitätseffekte chronisch, dermal DNEL = 343 mg/kg pro TagSystemische Toxizitätseffekte chronisch, inhalativ DNEL = 950 mg/m3

PNEC-Werte für die UmweltSüsswasser PNEC = 0.96 mg/l; (Exp-F = 10)Salzwasser PNEC = 0.79 mg/l; (Exp-F = 100)Sediment-Mikroorganismen PNEC = 3.6 mg/kg Sediment; (kein Exp-F)Land-Mikroorganismen PNEC = 0.63 mg/kg Erde; (Exp-F = 1000)Kläranlagen-Mikroorganismen PNEC = 580 mg/l; (Exp-F = 10)

8.2 Begrenzung und Überwachung der ExpositionZur orientierenden Kontrolle des Ethanolgehalts der Luft am Arbeitsplatz eignen sich Prüfröhrchen, z.B. Compur (549 210 Typ 104 SA), Dräger (81 01631 Typ Alkohol 25/a), Auer (5085-818 Typ Ethanol 100)oder Passivsampler, z.B. 3M Organic Vapor Monitor 3500, Dräger Orsa5.Nicht analytische Methoden zur Expositionsbegrenzung sind in der "Beilage 2: Expositionsszenarien" beschrieben(siehe Abschnitt 16.4).

8.2.1 Technische SchutzmassnahmenNur mit ausreichender Ventilation verwenden, speziell bei geschlossenen Räumen.Durch technische Massnahmen, z.B. Ventilation, lokale Absaugungen etc. dafür sorgen, dass die Grenzwerte am Arbeitsplatz nicht überschritten werden.Diese Massnahmen, besonders Absaugungen am Boden, sind auch wichtig, um die Bildung explosionsfähiger Dampf-Luft-Gemische zu verhindern.Explosionsgeschützte Ventilationseinrichtung verwenden.

8.2.2 Individuelle Schutzmassnahmen, zum Beispiel Persönliche SchutzausrüstungDie Persönliche Schutzausrüstung ist in ihrer Ausführung in Abhängigkeit von Gefahrstoffkonzentration und -mengearbeitplatzspezifisch auszuwählen. Dabei sind die Anforderungen der Schweizer Maschinenverordnung (SR 819.14) resp. der EU-Maschinenrichtlinie 2006/42/EG, sowie die auch von der Schweiz übernommenen EN-Normen über Persönliche Schutzausrüstungen DIN EN 482 und DIN EN 689 (vgl. Richtlinie 89/686/EWG) zu beachten.

Atemschutz:Persönlicher Atemschutz ist bei guter Raumbelüftung und/oder wirksamer lokaler Absaugung nicht erforderlich.Je nach Risikobeurteilung in Sondersituationen (Havarien etc.) Vollmaske mit Filter A (braun) oder ABEK (EN 14387) zusätzlich zu den technischen Massnahmen, (z.B. Ex-geschützte mobile Lüftungseinrichtung) verwenden. Filter A1 eignen sich bis 1000 ppm, Filter A2 bis 5000 ppm und Filter A3 bis 10000 ppm (bei dicht anliegender Maske!).Je nach Risikobeurteilung umluftunabhängigen Atemschutz mit Vollmaske verwenden.

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Handschutz:Chemieschutzhandschuhe der Kategorie III (nach EN 374, mit CE-Zeichen) verwenden. Geeignet sind die folgenden Handschuhmaterialien für direkten Produktkontakt:Butylkautschuk (0.5 mm, Durchbruchzeit >8 h)Fluorkautschuk (0.4 mm, Durchbruchzeit >8 h)Polychloropren (Neopren) (0.5 mm, Durchbruchzeit ca. 2 h) Für den direkten Produktkontakt (ausser als Spritzschutz) nicht geeignete Handschuhmaterialien sind:Naturkautschuk/Latex (NR), Nitrilkautschuk (NBR), PVC.

Augen- und Gesichtsschutz:Gestell-Schutzbrille mit Seitenschutz gemäss EN 166:2001 verwenden. Je nach Risikosituation Gesichtsschild oder Atemschutz mit Vollmaske anwenden.Am Arbeitsplatz muss eine Augendusche verfügbar sein.

Körperschutz:Lösemittelbeständige, antistatische Schutzkleidung aus schwer entflammbarem Stoff.Schuhwerk mit leitfähiger Sohle tragen (und den Boden der exponierten Räume leitfähig halten!)

8.2.3 Begrenzung und Überwachung der Umweltexposition In der Schweizer Luftreinhalteverordnung ist Ethanol als organischer Stoff der Klasse 3 eingestuft. Dies bedeutet, dass die Emissionskonzentration in der Abluft 150 mg/m3 nicht übersteigen darf, wenn der Massenstrom 3.0 kg/h oder mehr beträgt.

8.3 ExpositionsszenarienDie Expositionsszenarien finden sich in der Beilage 2 "Expositionsszenarien", in der Datei: "Ethanol_exposition_scenarios_E.pdf" (siehe Abschnitt 16.4.)

ABSCHNITT 9: Physikalische und chemische Eigenschaften

9.1 Angaben zu den grundlegenden physikalischen und chemischen Eigenschaften, ErscheinungsbildDie nachfolgend angegebenen Werte gelten für nicht denaturiertes Ethanol.Aussehen: farblose, klare FlüssigkeitGeruch: nach AlkoholGeruchsschwelle 93 ppm (49 - 716 ppm) ; 178 mg/m3pH-Wert wässriger Lösungen (10 g/l) neutralGefrierpunkt -114 °CSiedebeginn (bei 1013 hPa ): 78 °CFlammpunkt: 12 - 13 °CVerdunstungszahl (Ether = 1): 8Entzündbarkeit: leicht entzündlichUntere Explosionsgrenze: 3,5 Vol%Obere Explosionsgrenze: 15 Vol%Dampfdruck (20 °C): 59 hPa (= 59 mBar)Relative Dampfdichte (Luft = 1): 1.6Relative Dichte (20 °C ): ca. 0.81 g/cm3Wasserlöslichkeit (20 °C ): vollständig mischbarLöslichkeit in Lösungsmitteln (20 °C ): mit den meisten Lösungsmitteln mischbarVerteilungskoeffizient (n-Octanol/Wasser): log Kow = -0.3Selbstentzündungstemperatur: 425 °CZersetzungstemperatur (bei Luftabschluss): !700!°C

Viskosität dynamisch (20 °C): 1.2 mPa sViskosität kinematisch (20 °C): 1.52 mm2/s Brandfördernde Eigenschaften: keineOxidierende Eigenschaften: keineExplosive Eigenschaften ohne Luft nicht explosiv

9.2 Sonstige Angaben Wassergehalt: ca. 5.8 % (m/m)Organische Lösemittel / VOC-Anteil: ca. 94 % (m/m)Fettlöslichkeit: gut fettlöslichGasgruppe (Explosionsgruppe) IIATemperaturklasse: T2 (max. 300 °C)

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ABSCHNITT 10: Stabilität und Reaktivität

10.1 ReaktivitätReagiert mit starken Oxidationsmitteln und starken Reduktionsmitteln, sowie Säuren, Säureanhydriden, Alkalimetallen, Peroxiden unter heftiger Wärmeentwicklung.

10.2 Chemische StabilitätDas Produkt ist unter normalen Lagerbedingungen (dicht verschlossen, bei Raumtemperatur) chemisch stabil.

10.3 Möglichkeit gefährlicher ReaktionenExplosionsgefahr bei Kontakt mit: Alkalimetallen, Alkalioxiden, Calciumhypochlorit, Dischwefeldifluorid, Essigsäureanhydrid + Salzen + Säuren, Perchlorylnitril, Quecksilbernitrat, Silber/Salpetersäure, Silbernitrat, Silbernitrat/Ammoniak, Silberoxid/Ammoniak, Stickstoffdioxid, Wasserstoffperoxid.Ethanol kann in gefährlicher Weise reagieren mit: Acetylbromid, Acetylchlorid, Bromtrifluorid,Chromtrioxid, Chromylchlorid, Ethylenoxid, Fluor, Kalium-tert.-Biozid, Lithiumhydrid, Phosphortrioxid, Platinschwarz, Uranhexafluorid, Zirkon(IV)-chlorid, Zirkon(IV)-iodid.Bildung explosiver Dampfgemische mit Luft: Temperaturen ab 9° C begünstigen das Verdampfen und die Bildungexplosionsfähiger Atmosphären.Ungereinigte Leergebinde können Dampf-Luftgemische enthalten, die ein Explosionsrisiko bedeuten.

10.4 Zu vermeidende BedingungenNicht erhitzen. Flammen, Funken und statische Aufladungen verhindern. Nicht rauchen.Nicht in der Ex-Zone bohren, schneiden, schleifen, löten, schweissen etc. (ausser mit schriftlicher Schweissbewilligung).Nicht zulassen, dass sich explosionsfähige Dampf-Luft-Gemische in Kellern, Gruben, Kanalisation etc. ansammeln können.

10.5 Inkompatible MaterialienSiehe Abschnitte 10.1 und 10.3.

10.6 Gefährliche ZersetzungsprodukteEntzündliche Gase (z.B. Wasserstoff) oder Dämpfe können bei Kontakt mit starken Oxidationsmitteln, Alkalimetallen oder mit Säuren entstehen.

ABSCHNITT 11: Toxikologische Angaben

Abkürzungen, welche in diesem Abschnitt verwendet werden:LD50 = Letale Dosis 50 % DNEL = Derived no effect level LC50 = Letale Konzentration 50 % NOAEL = No observed adverse effect levelKMR (auch CMR) = Kanzerogen, mutagen, reproduktionstoxisch NOAEC = No observed adverse effect conc.Exp-F = Extrapolationsfaktor ATE = Acute Toxicity Estimate

SIEF = Substance Information Exchange Forum

11.1 Angaben zu den toxikologischen Wirkungen von EthanolDie Angaben in diesem Abschnitt gelten für normales, nicht denaturiertes Ethanol. Sie sind im Stoffsicherheitsberichtdes REACH-Registrierdossiers von Ethanol enthalten. Teilweise sind sie der Gefahrstoffdatenbank GESTIS entnommen.

Akute Toxizität:Einstufungsrelevante LD/LC50-Werte (= ATE gemäss Entscheid des für die Registrierung des Ethanols zuständigen SIEFs)LD50, oral, Ratte, Maus 10470 mg/kgLD50, dermal, Kaninchen 15800 mg/kgLC50, inhalativ, Ratte, Maus (Dauer 4 h) 30000 mg/m3

Reizwirkungauf die Haut: nicht reizendauf die Augen: reizendauf die Atemwege: konzentrationsabhängigÄtzwirkung: Ethanol ist nicht ätzendSensibilisierung der Haut: Ethanol ist nicht sensibilisierendSensibilisierung der Atemwege: Ethanol ist nicht sensibilisierend

Lokale Toxizitätseffekte (Arbeitsplatz) ArbeitsplatzwerteAkut, oral kein SchwellenwertAkut, inhalativ DNEL = 1900 mg/m3 (Exp-F = 1)Akut, dermal kein SchwellenwertSubchronisch, oral NOAEL = 1730 mg/kg pro TagChronisch, inhalativ kein SchwellenwertChronisch, dermal kein Schwellenwert

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Lokale Toxizitätseffekte (Bevölkerung) Werte für die BevölkerungAkut, oral keine Daten verfügbarAkut, inhalativ DNEL = 950 mg/m3 (Exp-F = 1)Akut, dermal kein SchwellenwertSubchronisch, oral keine Daten verfügbarChronisch, inhalativ kein SchwellenwertChronisch, dermal keine Daten verfügbar

Systemische Toxizitätseffekte (Arbeitsplatz) ArbeitsplatzwerteAkut, oral kein SchwellenwertAkut, dermal kein SchwellenwertAkut, inhalativ kein SchwellenwertChronisch, oral DNEL = 343 mg/kg pro TagChronisch, oral NOAEL = 1730 mg/kg pro TagChronisch, dermal DNEL = 343 mg/kg pro Tag (Exp-F = 24)Chronisch, dermal NOAEL = 8232 mg/kg pro Tag Chronisch, inhalativ DNEL = 950 mg/m3 (Exp-F = 1)

Systemische Toxizitätseffekte (Bevölkerung) Werte für die BevölkerungAkut, oral kein SchwellenwertAkut, dermal kein SchwellenwertAkut, inhalativ kein SchwellenwertChronisch, oral DNEL = 87 mg/kg pro Tag (Exp-F = 20)Chronisch, oral NOAEL = 1730 mg/kg pro TagChronisch, dermal DNEL = 206 mg/kg pro Tag (Exp-F = 40)Chronisch, dermal NOAEL = 8240 mg/kg pro TagChronisch, inhalativ DNEL = 114 mg/m3 (Karzinogenität)

KarzinogenitätKarzinogenität (Ratte) NOEL >3000 mg/kgKarzinogenität (Maus) weiblich: NOAEL > 44000 mg/kgKarzinogenität (Maus) männlich: NOAEL > 4250 mg/kg

MutagenitätMutagenität (Bakterien) Tests negativ

Toxizität für die FortpflanzungFruchtbarkeitsstörungen (oral) NOAEL = 13800 mg/kg pro TagFruchtbarkeitsstörungen (dermal) keine Daten verfügbarFruchtbarkeitsstörungen (inhalativ) NOAEC = 30400 mg/m3Entwicklungstoxizität (oral) NOAEL = 5200 mg/kg pro TagEntwicklungstoxizität (dermal) keine Daten verfügbarEntwicklungstoxizität (inhalativ, Ratte) NOAEC = 39 000 mg/m3

Die Deutsche Forschungsgemeinschaft DFG hat die KMR-Eigenschaften von Ethanol wie folgt eingestuft:Genotoxizität: DFG-Gruppe 2 der mutagenen Stoffe Karzinogenität: DFG-Kategorie 5 der kanzerogenen Stoffe Fötotoxizität: DFG-Gruppe C der fötotoxischen StoffeDiese Einstufungen der DFG sind nicht rechtskräftig.

Aspirationstoxizität Ethanol ist nicht mit Asp. Tox. 1 eingestuft

Erfahrungen über Toxizitätseffekte beim MenschenBei akuter Exposition:Wirkung auf die Augen / Schwere Augenreizung: Brennen/Stechen, Fremdkörpergefühl, Rötung.Wirkung auf die Atmungsorgane: Atemwegreizung, Benommenheit, Schwindel, Störung des zentralen Nervensystems.Wirkung auf die Haut: Keine signifikanten akuten Effekte oder kritischen Gefährdungen.Verschlucken: Reizung von Mund, Kehle und Magen, Brechreiz, Störungen des Zentralen Nervensystems.Bei subakuter Exposition:Die inhalative Toxizität ist bei Mensch und Tier gering. Einmalige Expositionen bis 5000 ml/m3 bleiben beim Menschen ohne lokale oder systemische Wirkung. Erst bei viel höheren Dosen treten zentralnervöse Effekte auf. Dämpfe in hohen Konzentrationen haben narkotische Wirkung.Bei chronischer Exposition:Wiederholte inhalative Expositionen beim MAK-Wert resultieren in Blut-Ethanolkonzentrationen, die weit unterhalb der Schwelle für erste zentralnervöse Effekte liegen. Der langfristige Konsum hoher Alkoholmengen führt in nahezu allen Organsystemen zu toxischen Effekten.

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11.2 Toxikologische Eigenschaften von Denaturierungsstoffen mit Konzentration !0.5 %

Datenquelle: Dossier der REACH-Registrierung (auf der Website der ECHA)METHYLETHYLKETON (MEK), 2-BUTANON CAS-Nr.: 78-93-3Konzentration 2 % (m/m)

0 Akute Toxizität, oral LD50 Ratte = 4.29 mL/ kg / 3450 mg/kgAkute Toxizität, dermal LD50 (Kaninchen) >10 mL mg/kg / >8000 mg/kgAkute Toxizität, inhalativ keine Daten verfügbarWiederholte Dosis-Toxizität, oral keine Daten verfügbarWiederholte Dosis-Toxizität, dermal keine Daten verfügbarWiederholte Dosis-Toxizität, inhalativ NOAEC, Ratte = 5041 ppm / 15.1 mg/LHautätzung/reizung keine Daten verfügbarAugenschädigung/reizung Kaninchen: reizend (Kategorie 2)Hautsensibilisierung Meerschweinchen: nicht sensibilisierendAtemwegssensibilisierung keine Daten verfügbarLokale Wirkungen, akut, inhalativ, Arbeitsplatz keine Daten verfügbarLokale Wirkungen, Langzeitexposition, inhalativ, Arbeitsplatz keine Daten verfügbarSystemische Wirkungen, Langzeitexposition, inhalativ, Arbeitsplatz DNEL = 600 mg/m3Systemische Wirkungen, Langzeitexposition, dermal, Arbeitsplatz DNEL = 1161 mg/kg /TagKarzinogenität/Mutagenität/Reproduktionstoxizität keine Klassierung

4-METHYL-2-PENTANON, (Methylisobutylketon, MIBK) CAS-Nr.: 108-10-1Konzentration 0.005Akute Toxizität, oral LD50 Ratte = 2080 mg/kgAkute Toxizität, dermal LD50 (Kaninchen) >20 mL/kg / >16000 mg/kgAkute Toxizität, inhalativ LC50 (4 h) Ratte > 2000 ppm / >8.3 mg/LWiederholte Dosis-Toxizität, oral NOAEL, Ratte = 250 mg/kgWiederholte Dosis-Toxizität, dermal keine Daten verfügbarWiederholte Dosis-Toxizität, inhalativ NOAEC, Ratte = 450 ppm / 1.9 mg/LHautätzung/reizung Kaninchen: nicht reizendAugenschädigung/reizung Kaninchen: leicht reizendHautsensibilisierung Meerschweinchen: nicht sensibilisierendAtemwegssensibilisierung keine Daten verfügbarLokale Wirkungen, akut, inhalativ, Arbeitsplatz DNEL = 208 mg/m3Lokale Wirkungen, Langzeitexposition, inhalativ, Arbeitsplatz DNEL = 83 mg/m3Systemische Wirkungen, akut, inhalativ, Arbeitsplatz DNEL = 83 mg/m3Systemische Wirkungen, Langzeitexposition, inhalativ, Arbeitsplatz DNEL = 83 mg/m3Systemische Wirkungen, Langzeitexposition, dermal, Arbeitsplatz DNEL = 11.8 mg/kg /TagKarzinogenität/Mutagenität/Reproduktionstoxizität keine Klassierung

ABSCHNITT 12: Umweltbezogene Angaben

Die Angaben in diesem Abschnitt gelten für normales, nicht denaturiertes Ethanol. Sie sind im Stoffsicherheitsberichtdes REACH-Registrierdossiers von Ethanol enthalten. Teilweise sind sie der Gefahrstoffdatenbank GESTIS entnommen.

Abkürzungen, welche in diesem Abschnitt verwendet werden:LC50 = Letale Konzentration 50 % EC50 = Effektkonzentration 50 % (Effekt: z.B. Immobilisierung von Wasserflöhen)EC10 = Effektkonzentration 10 % (10 % der Versuchstiere vom Effekt betroffen)PNEC = Predicted no effect concentration (für Umwelttoxizität) Exp-F = ExtrapolationsfaktorPBT = Persistent, bioakkumulierbar, toxischvPvB = sehr persistent, sehr bioakkumulierbar

12.1 UmwelttoxizitätLC50 akut, für Süsswasserfische 11200 mg/lLC50 langzeit, für Süsswasserfische keine Daten verfügbarEC50/LC50 akut, für wirbellose Süsswasserlebewesen 5012 mg/lEC50/LC50 akut, für wirbellose Salzwasserlebewesen 857 mg/lEC10/LC10 oder NOEC langzeit, für wirbellose Süsswasserlebewesen 9.6 mg/l EC10/LC10 oder NOEC langzeit, für wirbellose Salzwasserlebewesen 79 mg/l EC50/LC50 akut, für Süsswasseralgen 275 mg/lEC50/LC50 akut, für Salzwasseralgen 1970 mg/lEC10/LC10 oder NOEC langzeit, für Süsswasseralgen 11.5 mg/lEC10/LC10 oder NOEC langzeit, für Salzwasseralgen 1580 mg/lLC50 für Sediment-Organismen 8200 -10000 mg/lEC50/LC50 für Landpflanzen 633 mg/kg ErdeEC50/LC50 für die Mikroorganismen der Gewässer 5800 mg/l

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PNEC-Werte (Predicted No Effect Concentration)Süsswasserlebewesen PNEC = 0.96 mg/l (Exp-F = 10)Salzwasserlebewesen PNEC = 0.79 mg/l (Exp-F = 100)Süsswasser-Sediment-Mikroorganismen PNEC = 3.6 mg/kg Sediment (Verteil.-koeff.)Salzwasser-Sediment-Mikroorganismen PNEC = 2.9 mg/kg Sediment (keine F.-Angabe)Land-Mikroorganismen PNEC = 0.63 mg/kg Erde (Exp-F = 1000)Kläranlagen-Mikroorganismen PNEC = 580 mg/l (Exp-F = 10)"Intermittent release" PNEC = 2.75 mg/l (Exp-F = 100)

12.2 Persistenz und Abbaubarkeit:Abbaubarkeit im modifizierten OECD Screening Test 0.94Biologischer Sauerstoffbedarf BSB5 0.93 - 1.67 g/g

12.3 Bioakkumulationspotenzial: Biokonzentrationsfaktor (BCF): 0.66Verteilungskoeffizient Octanol/Wasser log Kow = -0.3

12.4 Mobilität im BodenEthanol verdunstet leicht an der Bodenoberfläche.

12.5 Ergebnis der PBT- und vPvB-Beurteilung: PBT Nicht zutreffendvPvB Nicht zutreffendAufgrund des Verteilungskoeffizienten n-Octanol/Wasser und der leichten biologischen Abbaubarkeit ist eine nennenswerte Anreicherung in Organismen nicht zu erwarten.

12.6 Andere schädliche Wirkungen keine Daten verfügbar

ABSCHNITT 13: Hinweise zur Entsorgung

Ethanol darf nicht über die Kanalisation entsorgt werden.

13.1 Verfahren der AbfallbehandlungRecycling beispielsweise mittels Destillation. Wenn eine Verwertung nicht möglich ist, müssen Abfälle als Sonderabfallunter Beachtung der örtlichen, behördlichen Vorschriften, d.h. durch einen anerkannten Abfallentsorger beseitigt werden.Abfallschlüssel gemäß VeVA-Code (Schweiz): S 20 01 13 LösungsmittelAbfallschlüssel gemäss EU-Abfallcode: 20 01 13* Lösemittel

Für mit dem Produkt hergestellte Gemische kann ein anderer Abfallcode gelten. Abfallschlüssel für Filter- und Aufsaugmaterialien, verschmutzte Kleidung etc.: S 15 02 02 (CH), resp. 15 02 02* (EU)

Nicht gereinigte VerpackungRestentleerte, nicht ausgetrocknete Gebinde sind extrem explosionsgefährlich und sollten gereinigt werden.Keinesfalls ungereinigte Fässer an Private abgeben oder selbst daran bohren, schneiden, schleifen, löten etc.!Die Abfallcodes für "Verpackungen, die Rückstände gefährlicher Stoffe enthalten oder durch gefährliche Stoffe

verunreinigt sind", sind: S 15 01 10, (CH), resp. 15 01 10* (EU)

Gereinigte VerpackungNicht kontaminierte, gereinigte Verpackungen können wieder verwendet werden. Empfohlenes Reinigungsmittel: Wasser

ABSCHNITT 14: Angaben zum Transport

14.1 UN-Nummer (UN/ID-Nummer) 1170

14.2 Ordnungsgemäße UN-VersandbezeichnungenADR/RID (normale Qualitäten bis 96 %): 1170 ETHANOL, LÖSUNG (ETHYLALKOHOL, LÖSUNG)

ADR/RID (Qualität "absolutus" > 96 %): 1170 ETHANOL (ETHYLALKOHOL)

IMDG-Code (normale Qualitäten bis 96 %): ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION)

IMDG-Code (Qualität "absolutus" > 96 %): ETHANOL (ETHYL ALCOHOL)

ICAO-TI / IATA-DGR: ETHANOL oder ETHANOL SOLUTION

14.3 Transportgefahrenklassen Alle Transportarten: Klasse 3 (Entzündbare flüssige Stoffe) Gefahrzettel / Label: 3

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14.4 VerpackungsgruppeAlle Transportarten: II

14.5 UmweltgefahrenKennzeichen GHS09 "umweltgefährdende Stoffe" (alle Transportarten): Nein / (ADN/(ADNR: Ja)Marine Pollutant: Nein

14.6 Besondere Vorsichtshinweise für den Verwender Achtung: Entzündbare flüssige Stoffe

14.7 Massengutbeförderung gemäß Anhang II des MARPOL-Übereinkommens 73/78 und gemäß IBC-Code:Der Versand erfolgt ausschließlich in Verpackungen, die verkehrsrechtlich für Ethanol zugelassen sind.

14.8 Weitere AngabenGefahrennummer zur Kennzeichnung der Gefahr (ADR/RID): 33Tunnelbeschränkungscode (ADR): D/EEMS-Nummern (für IMDG): F-E,S-DUN "Model regulation": UN 1993, ENTZÜNDBARER FLÜSSIGER STOFF, 3, II

Mengenbegrenzung (ADR/RID): LQ4

ABSCHNITT 15: Rechtsvorschriften

15.1 Produktspezifische Rechtsvorschriften zu Sicherheit, sowie Gesundheits- und Umweltschutz Spezifische EU-Vorschriften:Verordnung (EG) Nr. 2037/2000 (Stoffe, die zum Abbau der Ozonschicht führen): Nicht zutreffend

Verordnung (EG) Nr. 850/2004 (Persistente organische Schadstoffe): Nicht zutreffend

Verordnung (EG) Nr. 689/2008 (Aus- und Einfuhr gefährlicher Chemikalien): Nicht zutreffend

Richtlinie 2002/95/EG (RoHS-Richtlinie, Stoffe der RoHS-Liste): Nicht zutreffend

Verordnung (EU) Nr. 528/2012 über Biozidprodukte: Status von Ethanol als Wirkstoff ist "in Diskussion"

Zulassungspflicht gemäss Titel VII der REACH-Verordnung (EG) Nr. 1907/2006: Nein

Beschränkungen gemäß Titel VIII der REACH-Verordnung (EG) Nr. 1907/2006: Keine

Maschinenrichtlinie 2006/42/EG (Teil über Persönliche Schutzausrüstungen): siehe Abschnitt 8.2.2

Richtlinie 89/686/EWG (Persönliche Schutzausrüstungen und EN-Normen): siehe Abschnitt 8.2.2

Nationale Vorschriften Deutschland: Wassergefährdungsklasse gemäß VwVwS, Anhang 4: WGK = 1 (schwach wassergefährdend)

VOC-Anteil gemäss Lösemittelverordnung (31. BImSchV); VOC-Anteil: ca. 94 % (m/m)

Nationale Vorschriften Schweiz: Für Schweizer Verordnungstexte siehe: http://www.admin.ch/bundesrecht/00566/index.html?lang=de (Suche: Nummer eingeben)

Biozidprodukteverordnung, 813.12 Status von Ethanol als Wirkstoff ist "in Diskussion"

Risikoreduktionsverordnung, 814.81 Keine Beschränkung

PIC-Verordnung, 814.82 Keine Beschränkung

Störfallverordnung, 814.012 Siehe Abschnitt 7.2

Maschinenverordnung, 819.14 Siehe Abschnitt 8.2.2

Luftreinhalteverordnung, 814.318.142.1 Siehe Abschnitt 8.2.3

Technische Verordnung über Abfälle, 814.600 Allgemeine Bestimmungen über Abfälle

Verordnung über den Verkehr mit Abfällen, 814.610 Siehe Abschnitt 13.1

Verordnung über die VOC-Lenkungsabgabe, 814.018; VOC-Anteil: ca. 94 % (m/m)

Mutterschutzverordnung, 822.111.52

Jugendarbeitsschutzverordnungen , 822.115 und 822.115.2

Schweizer Wassergefährdungsklasse B (= nur in grossen Mengen relevant)

15.2 Stoffsicherheitsbeurteilung Dieses Gemisch wurde keiner Sicherheitsbeurteilung unterzogen, jedoch liegt ein Stoffsicherheitsbericht für nicht denaturiertes Ethanol vor. Die darin enthalten Daten wurden in diesem Sicherheitsdatenblatt berücksichtigt. In Anbetracht der niedrigen Konzentration der verwendeten Denaturierungsmittel dürften die Daten desStoffsicherheitsberichts weitgehend auch für das vorliegende Gemisch gelten.

ABSCHNITT 16: Sonstige Angaben

Die Angaben dieses Sicherheitsdatenblatts stützen sich auf den heutigen Stand unserer Kenntnisse, sie stellenjedoch keine Zusicherung von Produkteigenschaften dar und begründen kein vertragliches Rechtsverhältnis.

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16.1 Gefahrenhinweise die in den Abschnitten 2 und 3 mit Abkürzungen angegeben sind.Eye Irrit. 2 = Schwere Augenschädigung/Augenreizung, Kategorie 2Flam. Liq. 2 = Entzündliche Flüssigkeit, Kategorie 2STOT SE 3 = Spezifische Zielorgan-Toxizität, Kategorie 3Acute Tox. 3 = Akute Toxizität, Kategorie 3

Relevante H-CodesH225 = Flüssigkeit und Dampf leicht entzündbar.H319 = Verursacht schwere Augenreizung.H332 = Gesundheitsschädlich bei Einatmen.H335 = Kann die Atemwege reizen.H336 = Kann Schläfrigkeit und Benommenheit verursachen.H370 = Schädigt die Organe.H371 = Kann die Organe schädigenEUH066 = Wiederholter Kontakt kann zu spröder oder rissiger Haut führen.

PiktogrammeGHS01 = Explodierende BombeGHS02 = FlammeGHS03 = Flamme über KreisGHS04 = GasflascheGHS05 = ÄtzwirkungGHS06 = Totenkopf mit gekreuzten KnochenGHS07 = AusrufzeichenGHS08 = GesundheitsgefahrGHS09 = Umwelt

16.2 Alle P-Codes, welche dem Ethanol zugeordnet sind (gemäss dem Chemikaliensicherheitsbericht):Hinweise: Auf der Etikette sollten nicht mehr als 6 P-Codes erscheinen.

Bei Produkten für die breite Öffentlichkeit gehören die P-Codes P102 und P501 auf die Etikette.P102 = Darf nicht in die Hände von Kindern gelangen.P210 = Von Hitze/Funken/offener Flamme/heißen Oberflächen fernhalten. Nicht rauchen.P233 = Behälter dicht verschlossen halten.P240 = Behälter und zu befüllende Anlage erden.P241 = Explosionsgeschützte elektrische Betriebsmittel/Lüftungsanlagen/Beleuchtung verwenden.P242 = Nur funkenfreies Werkzeug verwenden.P243 = Vorbeugende Massnahmen gegen elektrostatische Aufladungen treffen.P264 = Nach Handhabung Hände gründlich waschen.P280 = Schutzhandschuhe/Schutzkleidung/Augenschutz/Gesichtsschutz tragen.P303+P361+P353 = BEI BERÜHRUNG MIT DER HAUT (oder dem Haar): Alle kontaminierten Kleidungsstücke sofort

ausziehen. Haut mit Wasser abwaschen/duschen.P305+P351+P338 = BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang vorsichtig mit Wasser ausspülen.

Eventuell vorhandene Kontaktlinsen entfernen, sofern leicht möglich. Weiter ausspülen.P337+P313 = Bei anhaltender Augenreizung: Ärztliche Rat einholen/ärztliche Hilfe hinzuziehen.P370+P378!=!Bei!Brand:!�!zum!Löschen!verwenden!(siehe!Abschnitt!5.1)

P403+P235 = An einem gut belüfteten Ort lagern. Kühl halten.P501= Entsorgung des Inhalts / des Behälters gemäß den örtlichen / nationalen / internationalen Vorschriften.

16.3 Abkürzungen und AkronymeADR = Europäisches Übereinkommen über die internationale Beförderung gefährlicher Güter auf der Straße

BlmSchV = Verordnung zur Durchführung des Bundes-Immissionsschutzgesetzes (Deutschland)

CAS = Chemical Abstracts Service

DIN = Norm des Deutschen Instituts für Normung

EC = Effekt-Konzentration (z.B. EC50 bei akuter Toxizität für Daphnien, Effekt: 50 % der Daphnien werden bewegungsunfähig)

EG = Europäische Gemeinschaft

EMS = Emergency procedures for ships carrying dangerous goods (IMDG)

EN = Europäische Norm

GHS = Globally Harmonised System

IATA = International Air Transport Association

IATA-DGR = International Air Transport Association - Dangerous Goods Regulations

IBC-Code = Internationaler Code für den Bau und die Ausrüstung von Schiffen zur Beförderung gefährlicher Chemikalien als Massengut

ICAO-TI = International Civil Aviation Organization-Technical Instructions

IMDG-Code = International Maritime Code for Dangerous Goods

ISO = Norm der Internation Standards Organization

IUCLID = International Uniform Chemical Information Database

LC50 = Letale Konzentration, 50 %

LD50 = Letale Dosis, 50%

Log Kow = Verteilungskoeffizient zwischen Oktanol und Wasser

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MARPOL = Maritime Pollution Convention = Übereinkommen zur Verhütung der Meeresverschmutzung durch Schiffe

OECD = Organisation for Economic Cooperation and Development

PBT = Persistent, bioakkumulierbar, toxisch

RID = Ordnung für die internationale Eisenbahnbeförderung gefährlicher Güter

TRGS = Technische Regeln für Gefahrstoffe (Deutschland)

UN = United Nations (Vereinte Nationen)

VOC = Volatile Organic Compounds (flüchtige organische Verbindungen) (USA, EU, CH)

VOCV = Verordnung über die Lenkungsabgabe auf flüchtigen organischen Verbindungen (Schweiz, SR 814.018)

vPvB = Sehr persistent und sehr bioakkumulierbar

VwVwS = Verwaltungsvorschrift wassergefährdender Stoffe (Deutschland)

WGK = Wassergefährdungsklasse (Deutschland)

16.4 VerschiedenesWichtige InformationsquellenDer Stoffsicherheitsbericht des REACH-Registrierdossiers von Ethanol und seine Expositionsszenarien. Die GESTIS-Datenbank, die einschlägigen Verordnungen und Richtlinien sowie die technische Literatur.Die REACH-Registrierungsdossiers der Denaturierungsmittel auf der Website der ECHA.

SchulungshinweiseDas Personal, welches mit gefährlichen Stoffen und Erzeugnissen umzugehen hat, ist beim Neueintritt und in regelmässigen Abständen über alle mit seiner Tätigkeit verbundenen Gefahren und über die zu treffenden Schutz-Massnahmen bezüglich Arbeitssicherheit, Gesundheits- und Umweltschutz sowie über dieErste-Hilfe-Leistungen zu instruieren und auch praktisch auszubilden.Ohne entsprechende Instruktion dürfen keine risikobehafteten Tätigkeiten veranlasst werden.

EinstufungsmethodeDie Einstufung erfolgte mit dem in der Verordnung (EG) Nr. 1272/2008 beschriebenen Vorgehen für die Einstufung von Gemischen auf Basis ihrer Inhaltsstoffe, wenn für alle Bestandteile Daten vorhanden sind.

Ergänzende Dokumente:Die folgenden ergänzenden Dokumente finden sich ebenfalls auf der Sicherheitsdatenblatt-CD:"Beilage 1, Identifizierte Verwendungen" in der Datei "1.231Anhang 1_Identifizierte Verwendungen.pdf""Beilage 2, Exposure scenarios (Expositionsszenarien)" in der Datei "1.532Anhang 2_Ethanol _Exposure_scenarios.pdf" Die CD-ROM enthält zusätzlich kurz gefasste "Chemikalienkurzmerkblätter" in den folgenden Dateien:"1.221CMK_Ethanol_rein.pdf" oder "1.222CMK_Ethanol_denaturiert.pdf" oder "1.223CMK_Ethanol_mit_Methanol.pdf".

13 von 13

Sicherheitsdatenblatt gemäß Verordnung (EG) Nr. 1907/2006 / (EU) Nr. 453/2010

Anhang 1 zum Sicherheitsdatenblatt von Ethanol

Datei Nr. 1.301 Erstellt am: 12.01.2015 / Revidiert am: --- Version: 1 / Ersetzt Version: ---

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Anhang 1 Die im Abschnitt 1.2 des Sicherheitsdatenblatts anzugebenden identifizierten Verwendungen von Ethanol (gemäss dem Stoffsicherheitsbericht)

1. Identifizierte Konsumentenanwendungen: SU 21

Identifizierte Verwendung (IU)

No. und Bezeichnung

Verwendungsdeskriptoren

10

Konsumenten-Verwendung als Motorentreibstoff, enthaltend Ethanol

Produktkategorie (PC):

PC 13: Treibstoffe

Umweltfreisetzungskategorie (ERC):

ERC 9a: Breite dispersive Innenverwendung von Stoffen in geschlossenen Systemen

ERC 9b: Breite dispersive Aussenverwendung von Stoffen in geschlossenen Systemen

Nachfolgende Nutzungsdauer in Erzeugnissen für diese Verwendung?: keine

11

Konsumenten-Verwendung als Brennstoff, enthaltend Ethanol


PC 13: Treibstoffe


ERC 8a: Breite dispersive Innenverwendung von Stoffen in offenen Systemen

ERC 8d: Breite dispersive Aussenverwendung von Stoffen in offenen Systemen


12

Konsumenten-Verwendung von Produkten, enthaltend <50g/? Ethanol


PC 1: Klebstoffe, Dichtstoffe

PC 3: Luftbehandlungsprodukte

PC 8: Biozidprodukte, Desinfektionsmittel etc.

PC 12: Düngemittel

PC 14: Produkte zur Behandlung von Metalloberflächen, inkl. Galvanisierprodukte

PC 15: Produkte zur Behandlung von Nichtmetall-Oberflächen

PC 18: Tinten und Toner

PC 23: Lederbehandlungsmittel, Gerbstoffe, Farben etc.

PC 24: Schmiermittel, Schmierfette, Trennmittel

PC 27: Pflanzenschutzmittel

PC 28: Parfüme, Duftstoffe

PC 30: Photochemikalien

PC 31: Poliermittel, Wachsmischungen

PC 34: Textilfarben, -imprägniermittel, -farben, inklusive Bleich- und Verarbeitungshilfsmittel

PC 39: Kosmetika, Körperpflegeprodukte





IU = Identified Uses




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1. Identifizierte Konsumentenanwendungen: SU 21 (Fortsetzung)

Identifizierte Verwendung (IU)

No. und Bezeichnung

Verwendungsdeskriptoren

13

Konsumenten- Verwendung von Ethanol in geschlossenen Systemen


PC 16: Wärmeübertragungsflüssigkeiten

PC 17: Hydraulikflüssigkeiten





14

Konsumenten- Verwendung von Ethanol in Beschichtungs-Produkten und Farben


PC 9a: Beschichtungen, Farben, Verdünner, Farbentferner





15

Konsumenten- Verwendung von Ethanol in Frostschutz-, Enteisungs- und Scheibenwasch-mitteln


PC 4: Frostschutz- und Enteisungsmittel




16

Konsumenten- Verwendung von Ethanol in Wasch- und Reinigungsmitteln


PC 35: Wasch- und Reinigungsmittel (inklusive Produkte auf Lösemittelbasis)








3 von 6

2. Professionelle/gewerbliche Verwendungen: SU 22

Identifizierte Verwendung (IU) No. und Bezeichnung

Angewendete Substanzform

Verwenduntgsdeskriptoren

7

Professionelle Verwendung von Ethanol als Brennstoff-quelle

Substanz als solche

auch in Gemischen

Prozesskategorie (PROC):

PROC 16: Verwendung von Material als Brennstoffquelle, begrenzte Exposition gegenüber unverbranntem Produkt ist zu erwarten





8

Professionelle Verwendung von Ethanol in Anwendungen ohne Sprühen

Substanz als solche

auch in Gemischen


PROC 10: Auftragen durch Rollen, Streichen (= Verwendung mit geringer Energie)

PROC 13: Behandlung von Erzeugnissen durch Tauchen und Gießen

PROC 14: Produktion von Zubereitungen/Gemischen oder Erzeugnissen durch Tablettieren, Pressen, Extrudieren, Pelettieren

PROC 19: Handmischen mit engem Kontakt und nur persönlicher Schutzausrüstung.





9

Professionelle Anwendung von Farben, Beschichtungen, Klebstoffen, Reinigern und anderen Gemischen/ Produkten, die Ethanol enthalten durch Sprühen

in Gemischen


PROC 11: Nicht industrielles Sprühen





18

Industrielle und professionelle Verwendung von Ethanol als Wärmeübertra-gungsflüssigkeit

Substanz als solche


PROC 20: Wärme- und Druckübertragungsflüssigkeiten in dispersiver, gewerblicher Verwendung, jedoch in geschlossenen Systemen








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3. Industrielle Verwendungen von Stoffen und Zubereitungen: SU 3 (Fortsetzung)


Ange-wendete

Substanz-form


1

Herstellung oder Verwendung als Zwischenpro-dukte oder Prozess-chemikalie

Substanz als solche


PROC 1: Verwendung in geschlossenen Systemen, keine Expositionswahr-scheinlichkeit

PROC 2: Verwendung in geschlossenen Systemen, gelegentliche kontrollierte Exposition

PROC 3: Verwendung in geschlossenen Chargenverfahren (Synthese oder Formulierung)

PROC 4: Verwendung in Chargen- und anderen Verfahren (Synthese), bei denen die Möglichkeit einer Exposition besteht

PROC 8a: Transfer des Stoffes oder der Zubereitung (Beschickung/Entleerung) aus/in Gefäße/große Behälter in nicht speziell für nur ein Produkt vorgesehenen Anlagen

PROC 8b: Transfer des Stoffes oder der Zubereitung (Beschickung/Entleerung) aus/in Gefäße/große Behälter in speziell für nur ein Produkt vorgesehenen Anlagen

Umweltfreisetzungskategorien (ERC):

ERC 1: Herstellung von Stoffen

ERC 4: Industrielle Verwendung von Verarbeitungshilfsstoffen, die nicht Bestandteil von Erzeugnissen werden, in Verfahren und Produkten

ERC 6a: Industrielle Verwendung, die zur Herstellung eines anderen Stoffs führt (Verwendung von Zwischenprodukten)

Sector of end use (SU):

SU 8: Herstellung von Massenchemikalien (einschliesslich Mineralölprodukte)

SU 9: Herstellung von Feinchemikalien


2

Vertrieb von Ethanol

Substanz als solche


PROC 8a: Transfer des Stoffes oder der Zubereitung (Beschickung/Entleerung) aus/in Gefäße/große Behälter in nicht speziell für nur ein Produkt vorgesehenen Anlagen


PROC 9: Transfer des Stoffes oder der Zubereitung in kleine Behälter (spezielle Abfüllanlage, einschließlich Wägung)


ERC 2: Formulierung von Zubereitungen/Gemischen


SU 8: Herstellung von Massenchemikalien (einschliesslich Mineralölprodukte)

SU 9: Herstellung von Feinchemikalien





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Ange-wendete

Substanz-form


3

Industrielles Formulieren und (Um-) Verpacken von Ethanol und Ethanol enthaltenden Gemischen

Substanz als solche


PROC 3: Verwendung in geschlossenen Chargenverfahren (Synthese oder Formulierung)

PROC 5: Mischen oder Vermengen in Chargenverfahren zur Formulierung von Zubereitungen/Gemischen und Erzeugnissen (mehrfacher und/oder erheblicher Kontakt)

PROC 8a: Transfer des Stoffes oder der Zubereitung/des Gemischs (Beschickung/Entleerung) aus/in Gefäße/große Behälter in nicht speziell für nur ein Produkt vorgesehenen Anlagen


PROC 9: Transfer des Stoffes oder der Zubereitung in kleine Behälter (spezielle Abfüllanlage, einschließlich Wägung)

PROC 14: Produktion von Zubereitungen/Gemischen oder Erzeugnissen durch Tablettieren, Pressen, Extrudieren, Pelettieren




SU 10: Formulieren (Mischen) von Zubereitungen/Gemischen und/oder Umverpackungen (ausser Legierungen)


4

Industrielle (End-) Verwendung von Ethanol in Anwendungen ohne Sprühen

Substanz als solche

auch in Gemischen


PROC 10: Auftragen durch Rollen oder Streichen

PROC 13: Behandlung von Erzeugnissen durch Tauchen und Gießen




5

Industrielle (End-) Verwendung von Ethanol in Anwendungen mit Sprühen

Substanz als solche

auch in Gemischen


PROC 7: Industrielles Sprühen







6 von 6



Ange-wendete

Substanz-form


6

Industrielle Verwendung von Ethanol als Brennstoff-quelle

Substanz als solche

auch in Gemischen


PROC 16: Verwendung von Material als Brennstoffquelle, begrenzte Exposition gegenüber unverbranntem Produkt ist zu erwarten


ERC 7: Industrielle Verwendung von Stoffen in geschlossenen Systemen


17

Industrielle Verwendung als Laborreagenz

Substanz als solche


PROC 15: Verwendung als Laborreagenz




ERC 8a: Breite dispersive Innenverwendung von Verarbeitungshilfsstoffen in offenen Systemen


18

Industrielle und professionelle (End-) Verwendung als Wärmeüber-tragungs-flüssigkeit

Substanz als solche)


PROC 20: Wärme- und Druckübertragungsflüssigkeiten in dispersiver, gewerblicher Verwendung, jedoch in geschlossenen Systemen


ERC 7: Industrielle Verwendung von Stoffen in geschlossenen Systemen


EC number:

200-578-6

Ethanol (64-17-5 EtOHRA dossier) CAS number:

64-17-5

2010-05-24 CSR-PI-5.2.1 EXPOSURE SCENARIOS 1

EXPOSURE SCENARIOS

Substance Name: ethanolEC Number: 200-578-6

CAS Number: 64-17-5

Registrant's Identity: Intertek Testing Service (UK) Ltd

Table of Contents

9. EXPOSURE SCENARIOS............................................................................................................................... 3

9.1 Title: Exposure Scenario for Industrial manufacturing of Ethanol, or use as intermediate or process

chemical.......................................................................................................................................................... 3

Ethanol REACH Association reference no. ES1 ........................................................................................ 3

9.2 Title: Exposure Scenario for Industrial distribution of Ethanol................................................................ 5


9.3 Title: Exposure Scenario for Industrial formulation and (re)packing of Ethanol, and its mixtures .......... 7

9.4 Title: Exposure Scenario for Industrial use of Ethanol in non-spray applications.................................... 9


EC number:

200-578-6

ETHANOL CAS number:

64-17-5

Created: 2010-05-24 EXPOSURE SCENARIOS 2

9.5 Title: Exposure Scenario for Industrial use of Ethanol in spray applications ......................................... 11

Ethanol REACH Association reference no. ES5 ...................................................................................... 11

9.6 Title: Exposure Scenario for Industrial use of Ethanol as fuel source .................................................... 13

Ethanol REACH Association reference no. ES6a .................................................................................... 13

9.7 Title: Exposure Scenario for Professional use of Ethanol as fuel source................................................ 15

Ethanol REACH Association reference no. ES6b .................................................................................... 15

9.8 Title: Exposure Scenario for Professional use of Ethanol in non-spray applications ............................. 17


9.9 Title: Exposure Scenario for Professional use of Ethanol in spray applications..................................... 19


9.10 Title: Exposure Scenario for Consumer use of Ethanol as automotive fuel ......................................... 21

Ethanol REACH Association reference no. ES9a .................................................................................... 21

9.11 Title: Exposure Scenario for Consumer use of Ethanol as domestic fuel ............................................. 23

Ethanol REACH Association reference no. ES9b .................................................................................... 23

9.12 Title: Exposure Scenario for Consumer use of Ethanol in products (<50g per event).......................... 25

Ethanol REACH Association reference no. ES9c .................................................................................... 25

9.13 Title: Exposure Scenario for Consumer use of Ethanol in enclosed systems ....................................... 27

Ethanol REACH Association reference no. ES9d .................................................................................... 27

9.14 Title: Exposure Scenario for Consumer use of Ethanol in coatings and paints .................................... 29

Ethanol REACH Association reference no. ES9e .................................................................................... 29

9.15 Title: Exposure Scenario for Consumer use of Ethanol in antifreeze, deicing and screenwash products

...................................................................................................................................................................... 31

Ethanol REACH Association reference no. ES9f..................................................................................... 31

9.16 Title: Exposure Scenario for Consumer use of Ethanol in washing and cleaning products.................. 33

Ethanol REACH Association reference no. ES9g .................................................................................... 33

9.17 Title: Exposure Scenario for Industrial and Professional use of Ethanol as laboratory agent .............. 35

Ethanol REACH Association reference no. ES10 .................................................................................... 35

9.18 Title: Exposure Scenario for Industrial and Professional use of Ethanol as heat transfer fluid, or other

functional fluid ............................................................................................................................................. 37

Ethanol REACH Association reference no. ES11 .................................................................................... 37

9.19. Regional Exposure Assessment ........................................................................................................... 39

APPENDIX 1 TO CHAPTER 9 - USE MAPPING FOR ETHANOL........................................................ 41

APPENDIX 2 TO CHAPTER 9 � LIST OF EXPOSURE SCENARIOS .................................................... 43

APPENDIX 3 TO CHAPTER 9 � DETAILS OF CSA-worker exposure.................................................... 45

APPENDIX 4 TO CHAPTER 9 � ECETOC TRA tool calculation for environmental exposure scenarios 62

APPENDIX 5 TO CHAPTER 9 � Ethanol Consumer Exposure Calculation ............................................. 65

10. RISK CHARACTERISATION .................................................................................................................. 67

Notes on risk characterisation...............................................................................................................................

10.1 Title: Exposure Scenario for Industrial manufacturing of Ethanol, or use as intermediate or

process chemical........................................................................................................................................... 67

10.2 Title: Exposure Scenario for Industrial distribution of Ethanol............................................................ 67

10.3 Title: Exposure Scenario for Industrial formulation and (re)packing of Ethanol, and its mixtures ...... 68

10.4 Title: Exposure Scenario for Industrial use of Ethanol in non-spray applications................................ 68

10.5 Title: Exposure Scenario for Industrial use of Ethanol in spray applications ....................................... 69

10.6 Title: Exposure Scenario for Industrial use of Ethanol as fuel source .................................................. 69

10.7 Title: Exposure Scenario for Professional use of Ethanol as fuel source.............................................. 70

10.8 Title: Exposure Scenario for Professional use of Ethanol in non-spray applications ........................... 70

10.9 Title: Exposure Scenario for Professional use of Ethanol in spray applications................................... 71

10.10 Title: Exposure Scenario for Consumer use of Ethanol as automotive fuel ....................................... 71

10.11 Title: Exposure Scenario for Consumer use of Ethanol as domestic fuel ........................................... 72

10.12 Title: Exposure Scenario for Consumer use of Ethanol in products (<50g per event)........................ 72

10.13 Title: Exposure Scenario for Consumer use of Ethanol in products in enclosed systems................... 73

10.14 Title: Exposure Scenario for Consumer use of Ethanol in products in coatings and paints................ 73

10.15 Title: Exposure Scenario for Consumer use of Ethanol in antifreeze, deicing, and screenwash

products ........................................................................................................................................................ 74

10.16 Title: Exposure Scenario for Consumer use of Ethanol in washing and cleaning products................ 74

EC number:

200-578-6


64-17-5


9. EXPOSURE ASSESSMENT

9.1 Title: Exposure Scenario for Industrial manufacturing of Ethanol, or use asintermediate or process chemical

Ethanol REACH Association reference no. ES1

Systematic title based on use descriptor

SU3, SU8, SU9PROC1, PROC2, PROC3, PROC4, PROC8a, PROC8bERC1, ERC4, ERC6A

Processes, tasks, activities coveredCovers the industrial manufacture of Ethanol at controlled manufacturing plants in continuousand batch processes. Includes recycling/ recovery, material transfers, filling, storage,maintenance and loading, sampling and use as an intermediate or process chemical.

Assessment Method Ecetoc TRA integrated model version 2, EUSES v.2.

9.1.1 Exposure Scenario

9.1.1.1. Operational conditions and risk management measures

Process categories: Continuous process in high integrity contained systems with little potential for exposure (sampling via closed loop system)and continuous process not specifically aimed at minimizing emissions. Occasional exposure possible through e.g. maintenance and sampling.Sampling, loading, filling, storage and transfer under controlled conditions at the manufacturing site is also included.

Environmental release categories: Manufacture, and industrial use as intermediate or process chemical of organic substances usingcontinuous processes or batch processes applying dedicated or multi-purpose equipment, either technically controlled or operated by manualinterventions.

Number of sites using the substance: Substance widely used.

9.1.1.2 Control of workers exposurePhysical state liquid

Concentration of substance in product Up to 100 %Product characteristic (including packagedesign affecting exposure)

Vapour pressure of substance 5,73 kPa

Amounts used n.a. in tier1 TRA model

Frequency of exposure (weekly) > 4 Days/week

Frequency of exposure (annual) 240 Days/yearFrequency and duration of use/exposure

Duration of exposure > 4 Hours/day

Potentially exposed body parts

Two hands face side only (automatedprocesses/PROC1, 2)

Two hands (transfer, filling, etc./PROC8a,b)Human factors not influenced by riskmanagement

Exposed skin surface480 cm

2(automated processes/PROC1, 2,

3,4)960 cm

2(transfer, filling, etc./PROC8a,b)

Assumes a good basic standard of occupational hygiene is implemented.Other given operational conditionsaffecting workers exposure

Setting (indoor/outdoor) Outdoor

Technical conditions and measures atprocess level (source) to prevent release

No specific technical prevention measures required for process in high integrity containedsystems with little potential for exposure or with only occasional minor exposure through e.g.maintenance and sampling.

Ventilation None requiredTechnical conditions and measures tocontrol dispersion from source towardsthe worker Efficiency rate 95 %

Organisational measures to prevent /limitreleases, dispersion and exposure

Handle substances within a predominantly closed system. Ensure material transfers are undercontainment or extract ventilation. No specific organizational measures required forprocesses in high integrity contained systems with little potential for exposure or with onlyoccasional minor exposure through e.g. maintenance and sampling.Provide extract ventilationto points where emissions occur. Wear suitable gloves tested to EN374 during the activitieswhere skin contact is possible.

Conditions and measures related topersonal protection, hygiene and healthevaluation

PPE: Respiratory Protection - not required for normal operations. PPE: Eye Protection �suitable eye protection should be worn when handling product if there is a risk of splashing .

EC number:

200-578-6

ETHANOL CAS number:

64-17-5


9.1.1.3 Control of environmental exposurePhysical state liquid

Product characteristicsConcentration of substance in product Up to 100 %

Daily at point source n.a.

Annually at point source 400,000 t/year (maximum plant size, worstcase)

Amounts used

Annually total 4,600,000 t/year total market

Frequency and duration of use Pattern of release Continuous 350 days per year

Environment factors not influenced byrisk management

Flow rate of receiving surface water 18,000m3/day (default)

Processing setting (indoor/outdoor) Indoor and/or outdoor

Processing temperature AmbientOther given operational conditionsaffecting environmental exposure

Processing pressure Ambient


Keep containers tightly closed. Store in a bounded area. Do not discharge into sewers ordrains. Use appropriate emission abatement equipment from LEV systems if required by locallegislation. Waste product and empty containers should be disposed of as hazardous waste inaccordance with all local and national regulations

Apply technical measures aiming at reducingreleases to air (containment by preference orcatalytic or thermal gas oxidation)

Efficacy >70% (for ethanol)Technical onsite conditions and measuresto reduce or limit discharges, airemissions and releases to soil Apply technical measures aiming at reduction

and cleaning of waste water (WWTP /localSTP (e.g. biological treatment))

Efficacy >87% (for ethanol)

Organizational measures to prevent/limitrelease from site

Do not release wastewater directly intoenvironment

Wastewater release into local or municipalSTP.

Size of STP >= 2000 m3/day

Degradation efficacy 90% (for ethanol)Conditions and measures related tomunicipal sewage treatment plant

Sludge treatment Disposal or recovery

Conditions and measures related totreatment of waste

Hazardous waste incineration or dispose for use in recycled fuels

9.1.2. Exposure estimationWorkers exposure estimation is calculated with Ecetoc TRA model v2.. Below given exposure estimates are based on the PROC with thehighest exposure levels in this scenario (PROC8a).

Workers exposure Exposure estimate DNEL Comment

Inhalation (mg/m3) 96.04 950 (OEL)

Dermal (mg/kd/day) 13.71 343

Combined (mg/kg/day) 27.43 343

PROC 8a results in the highest exposure in thisexposure scenario

Environmental exposure estimation is calculated with EUSES 2.0 model. Ethanol is fully soluble in water, readily biodegradable, not bio-accumulative, does not accumulate in the sediments or soil and is assumed to degrade by 90% in the local and/or municipal STP underevaluated conditions.

Release times per year (day/year) 350 Local release to air (kg/day) 226.0

Fraction used at main local source 0.086 Local release to waste water (kg/day) 11.3

Amount used locally (kg/day) 0 Local release to soil (kg/day) 0

Environmental exposure PEC PNEC Comment

In STP / untreated wastewater(mg/l) 5.65 580 -

In local freshwater (mg/l) 0,0000264 0,96 -

In local soil 0.00119 (mg/kg) 0,63 (mg/kgwwt) -

In local marine water (mg/l) 0,00000224 0,79 -

Total daily intake via local environment(mg/kgdw/d)

Negligible compared to daily dietary intake and endogenous formation.

Guidance to DU to evaluate whether he works inside the boundaries set by the ESThe workers exposure and environmental emissions have been evaluated using Ecetoc TRA integrated tool version 2 and EUSES v2.0respectively.If the local environmental emission conditions deviate significantly from the used default values, please use the algorithm below to estimate thecorrect local emissions and RCRs:PECcorrected = PECcalculated * (local emission fraction) * (local WWTP flow rate fraction) * (local river flow rate fraction) * (local STPefficiency fraction)Example for calculating your local freshwater PEC:Corrected local freshwater PEC = 0,0000264* (your local emission [kg/day] / 350) * (2000 / your local WWTP flow rate [m3/day]) * (18000 /your local river flow rate [m3/day]) * ((1 � your local WWTP efficiency)/0.1)

EC number:

200-578-6


64-17-5


9.2 Title: Exposure Scenario for Industrial distribution of Ethanol



SU3, SU8, SU9PROC8a, PROC8b, PROC9ERC2

Processes, tasks, activities covered

Covers transfer of substance or preparation (charging/discharging) from/to vessels/largecontainers at non-dedicated and dedicated facilities, loading (including marine vessel/barge,rail/road car and IBC loading), storage, and repacking (including drums and small packs) ofsubstance, including its distribution.

Intended for e.g. traders, distributors, transporters, etc.

Assessment Method Ecetoc TRA integrated model version 2



Process categories: Sampling, loading, filling, transfer, drumming, bagging in non-dedicated facilities. Exposure related to vapour, aerosols orspillage, and cleaning of equipment to be expected.

Environmental release category: Mixing, blending, diluting, transferring, filling, drumming and distributing activities of substances in all types ofdrumming, distribution and trading industry. Also includes drumming, filling and distribution activities in formulating industries, such as paintsand do-it-yourself products, pigment pastes, fuels, household products (cleaning products), cosmetics, lubricants etc.









Potentially exposed body partsTwo hands

Human factors not influenced by riskmanagement

Exposed skin surface 960 cm2


Setting (indoor/outdoor) Outdoor or in ventilated (open) spaces


No specific technical prevention measures required

Outdoors No specific measures identified.

Technical conditions and measures tocontrol dispersion from source towardsthe worker If indoors

Provide a good standard of general orcontrolled ventilation (5 to 15 air changesper hour). Ensure material transfers areunder containment or extract ventilation.Provide good ventilation to points whereemissions occur.


No specific measures identified.


PPE: Eye Protection � suitable eye protection should be worn when handling product if thereis a risk of splashing . Wear suitable gloves tested to EN374 during the activities where skincontact is possible.

EC number:

200-578-6

ETHANOL CAS number:

64-17-5





Annually at point source 75,000 t/year (worst case scenario, at pointsource)

Amounts used

Annually total 3,800,000 t/year total market

Frequency and duration of use Pattern of release 300 days per year



Processing setting (indoor/outdoor) Outdoor




Keep containers tightly closed. Store in a bounded area. Do not discharge into sewers ordrains. Waste product and empty containers should be disposed of as hazardous waste inaccordance with all local and national regulations



Wastewater release into local or municipalSTP.

Size of STP >2000 m3/day

Degradation efficacy >90% (for ethanol)Conditions and measures related tomunicipal sewage treatment plant






Inhalation (mg/m3) 96.04 950 (OEL)




Environmental exposure estimation is based on Ecetoc TRA model v2 including the data from TGD A&B tables (MC-Ib, IC-2, UC-48, fractionmain source 0,1) and based on the worst-case scenario with point-source production volume of 15,000 tpa.Ethanol is fully soluble in water, readily biodegradable, not bio-accumulative, does not accumulate in the sediments or soil and is assumed todegrade for 90% in the local and/or municipal STP under evaluated conditions.

Release times per year (day/year) 300 Local release to air (kg/day) 50

Fraction used at main local source 0.1 Local release to waste water (kg/day) 15









Guidance to DU to evaluate whether he works inside the boundaries set by the ESThe workers exposure and environmental emissions have been evaluated using Ecetoc TRA integrated tool version 2 and EUSES v2.0respectively.If the local environmental emission conditions deviate significantly from the used default values, please use the algorithm below to estimate thecorrect local emissions and RCRs:PECcorrected = PECcalculated * (local emission fraction) * (local WWTP flow rate fraction) * (local river flow rate fraction) * (local STPefficiency fraction)Example for calculating your local freshwater PEC:Corrected freshwater PEC = 0,104 * (your local emission [kg/day] / 15) * (2000 / your local WWTP flow rate [m3/day]) * (18000 / your local riverflow rate [m3/day]) * ((1 � your local WWTP efficiency)/0.1)

Additional good practice advice beyondthe REACH CSANote: The measures reported in this section have not been taken intoaccount in the exposure estimates related to the exposure scenarioabove. They are not subject to obligation laid down in Article 37 (4) ofREACH

Use specific measures expected to reduce the predicted exposurebeyond the level estimated based on the exposure scenario whenpossible.

EC number:

200-578-6


64-17-5


9.3 Title: Exposure Scenario for Industrial formulation and (re)packing of Ethanol, andits mixtures



SU3, SU10PROC3, PROC5, PROC8a, PROC8b, PROC9, PROC14ERC 2

Processes, tasks, activities coveredCovers industrial formulation, packing and re-packing of the substance and its mixtures inbatch or continuous operations, including storage, materials transfers, mixing, large and smallscale packing, maintenance. Includes formulation of fuels containing ethanol.

Assessment Method Ecetoc TRA integrated model version 2, EUSES v.2.



Process category: Manufacture or formulation of chemical products or articles using technologies related to mixing and blending of solid orliquid materials, and where the process is in stages and provides the opportunity for significant contact at any stage. Filling lines specificallydesigned to both capture vapour and aerosol emissions and minimise spillage. Sampling, loading, filling, transfer, dumping, bagging in non-dedicated and dedicated facilities with possible exposure related to dust, vapour, aerosols or spillage, and cleaning of equipment.

Environmental release category: Manufacture of organic and inorganic substances in chemical, petrochemical, primary metals and mineralsindustry including intermediates, monomers using continuous processes or batch processes applying dedicated or multi-purpose equipment,either technically controlled or operated by manual interventions










Two hands face side only (automatedprocesses/PROC3)

Two hands (transfer, filling, etc./PROC8a,b)Human factors not influenced by riskmanagement


2(automated processes/PROC3)

960 cm2

(transfer, filling, etc./PROC8a,b)


Setting (indoor/outdoor) Indoors



Technical conditions and measures tocontrol dispersion from source towardsthe worker

Ensure material transfers are under containment or extract ventilation. Provide goodventilation to points where emissions occur. Provide a good standard of general or controlledventilation (5 to 15 air changes per hour).




PPE: Eye Protection � suitable eye protection should be worn when handling product if thereis a risk of splashing . Wear suitable gloves tested to EN374 during the activities whereexcessive skin contact is possible.



Amounts used Daily at point source n.a.

EC number:

200-578-6

ETHANOL CAS number:

64-17-5


Annually at point source 280,000 t/year (maximum at point source inworst case)

Annually total 3,800,000 t/year




Processing setting (indoor/outdoor) Indoor




Keep containers tightly closed. Store in a bounded area. Do not discharge into sewers ordrains. Waste product and empty containers should be disposed of as hazardous waste inaccordance with all local and national regulations. Formulation activity is assumed to be apredominantly enclosed process.

Technical onsite conditions and measuresto reduce or limit discharges, airemissions and releases to soil

Apply technical measures aiming at reductionand cleaning of waste water (WWTP/localSTP (e.g. biological treatment))

Efficacy >90%



Wastewater release into municipal STP.








Inhalation (mg/m3) 96.04 950




Environmental exposure estimation is based on Ecetoc TRA model v2 including the data from TGD A&B tables (MC-Ib, IC-9, UC-27, fractionmain source 0,1) and based on the worst-case scenario.Ethanol is fully soluble in water, readily biodegradable, not bio-accumulative, does not accumulate in the sediments or soil and is assumed todegrade by 90% in the local and/or municipal STP under evaluated conditions.



Amount used locally (kg/day) 93.333 Local release to soil (kg/day) 9








Guidance to DU to evaluate whether he works inside the boundaries set by the ESThe workers exposure and environmental emissions have been evaluated using Ecetoc TRA integrated tool version 2.

If the local environmental emission conditions deviate significantly from the used default values, please use the algorithm below to estimate thecorrect local emissions and RCRs:PECcorrected = PECcalculated * (local emission fraction) * (local WWTP flow rate fraction) * (local river flow rate fraction) * (local STPefficiency fraction)Example for calculating your local freshwater PEC:Corrected local freshwater PEC = 0,185 * (your local emission [kg/day] / 28) * (2000 / your local WWTP flow rate [m3/day]) * (18000 / your localriver flow rate [m3/day]) * ((1 � your local WWTP efficiency)/0.1)



EC number:

200-578-6


64-17-5


9.4 Title: Exposure Scenario for Industrial use of Ethanol in non-spray applications



SU3PROC10, PROC13ERC4


Covers industrial (end) use of ethanol as such or in preparations in non-sprayapplication (e.g. as processing aid, cleaning agent, solvent or ingredient incoatings). Indoor roller application, brushing and treatment of surfaces,treatment of articles by dipping/ pouring/ immersing/ soaking, etc.




Process category: Low energy spreading of e.g. coatings. Including cleaning of surfaces. Substance can be inhaled as vapours, skin contactcan occur through droplets, splashes, working with wipes and handling of treated surfaces. Immersion operations. Treatment of articles bydipping, pouring, immersing, soaking, washing out or washing in substances; including cold formation or resin type matrix. Includes handling oftreated objects (e.g. after dying, plating,). Substance is applied to a surface by low energy techniques such as dipping the article into a bath orpouring a preparation onto a surface. Use of substances at small-scale laboratory (< 1 l or 1 kg). Covers also the use of the substance as fuelsources (including additives) where limited exposure to the product in its unburned form is expected.

Environmental release category: Industrial use of processing aids in a batch process, not becoming part of an article using dedicated or multi-purpose equipment, either technically controlled or operated by manual interventions. For example, solvents used in chemical reactions or the�use� of solvents during the application of paints, lubricants in metal working fluids, anti-set off agents in polymer moulding/casting.










Two hands, face side only (PROC13)Two hands (PROC10)



2(PROC13)

960 cm2

(PROC10)


Setting (indoor/outdoor) Indoors and outdoors




Provide a good standard of general or controlled ventilation (5 to 15 air changes per hour)when working indoors. Ensure material transfers are under containment or extract ventilation.Provide good ventilation to points where emissions occur.




PPE: Eye Protection � suitable eye protection should be worn when handling product if thereis a risk of splashing .Wear suitable gloves tested to EN374 during the activities where prolonged or frequent skincontact is possible.

EC number:

200-578-6

ETHANOL CAS number:

64-17-5





Annually to the region 2,750 t/year (general)

Amounts used

Annually total 27,500 t/year (general) total market




Processing setting (indoor/outdoor) Indoors and outdoors




Do not discharge into sewers or drains. Waste product and empty containers should bedisposed of as hazardous waste in accordance with all local and national regulations.



Efficacy >70%














PROC 10 results in the highest exposure in thisexposure scenario

Environmental exposure estimation is based on Ecetoc TRA model v2 including the data from TGD A&B tables (MC-Ib, IC-14, UC-48,fraction main source 0,1 using local STP and MC-Ic, IC-9, UC-27 fraction main source 0,1 using local STP). Below values are those related toprocesses with the highest risk characterization ratio (related to industrial use of coatings, inks and adhesives). All other activities covered inthis exposure scenario result in lower environmental exposure estimates.Ethanol is fully soluble in water, readily biodegradable, not bio-accumulative, does not accumulate in the sediments or soil and is assumed todegrade by 90% in the local and/or municipal STP under evaluated conditions.











Guidance to DU to evaluate whether he works inside the boundaries set by the ESThe workers exposure and environmental emissions have been evaluated using Ecetoc TRA integrated tool version 2.If the local environmental emission conditions deviate significantly from the used default values, please use the below algorithm to estimate thecorrect local emissions and RCRs:PECcorrected = PECcalculated * (local emission fraction) * (local WWTP flow rate fraction) * (local river flow rate fraction) * (local STPefficiency fraction)Example for calculating your local freshwater PEC:Corrected freshwater PEC = 0,039 * (your local emission [kg/day] / 5) * (2000 / your local WWTP flow rate [m3/day]) * (18000 / your local riverflow rate [m3/day]) * ((1 � your local WWTP efficiency)/0.1)



EC number:

200-578-6


64-17-5


9.5 Title: Exposure Scenario for Industrial use of Ethanol in spray applications



SU3PROC7ERC4


Covers industrial (end) use of ethanol as such or in preparations byspraying (e.g. as processing aid, cleaning agent, solvent or ingredient incoatings). Indoor painting, application of coatings, adhesives,polishes/cleaners, air-care products and other mixtures containing Ethanolby automated spraying techniques in factories or comparable industrialsettings.




Process category: Industrial-spraying (air dispersive techniques). Substances can be inhaled as aerosols. The energy of the aerosol particlesmay require advanced exposure controls.

Environmental release category: Industrial use of processing aids in a batch process, not becoming part of an article using dedicated or multi-purpose equipment, either technically controlled or operated by manual interventions.









Potentially exposed body parts Two hands and forearmsHuman factors not influenced by riskmanagement







Provide a good standard of general or controlled ventilation (5 to 15 air changes per hour)when working indoors. Ensure material transfers are under containment or extract ventilation.Provide good ventilation to points where emissions occur.




Avoid excessive and frequent skin contact as much as possible. Wear suitable gloves testedto EN374 during the activities where excessive or frequent skin contact is possible.Wear a respirator conforming to EN140 with Type A filter or better if vented booth with laminarflow is not available.

EC number:

200-578-6

ETHANOL CAS number:

64-17-5





Annually to the region 2,750 t/year (maximum in worst case)

Amounts used

Annually total 27,500 t/year total market











Efficacy >70%









9.5.2. Exposure estimationWorkers exposure estimation is calculated with Ecetoc TRA model v2..





Exposure estimates and RCRs given here arecalculated for conditions without LEV (worst casescenario).

Environmental exposure estimation is based on Ecetoc TRA model v2 including the data from TGD A&B tables (MC-Ib, IC-14, UC-48,fraction main source 0,1 using local STP ). Below values are those related to processes with the highest risk characterization ratio (related toindustrial use of coatings, inks and adhesives). All other activities covered in this exposure scenario result in lower environmental exposureestimates.Ethanol is fully soluble in water, readily biodegradable, not bio-accumulative, does not accumulate in the sediments or soil and is assumed todegrade by >90% in the Local and Municipal STP under evaluated conditions.











Guidance to DU to evaluate whether he works inside the boundaries set by the ESThe workers exposure and environmental emissions have been evaluated using Ecetoc TRA integrated tool version 2.If the local environmental emission conditions deviate significantly from the used default values, please use the below algorithm to estimate thecorrect local emissions and RCRs:PECcorrected = PECcalculated * (local emission fraction) * (local WWTP flow rate fraction) * (local river flow rate fraction) * (local STPefficiency fraction)Example for calculating your local freshwater PEC:Corrected freshwater PEC = 0,039 * (your local emission [kg/day] / 5) * (2000 / your local WWTP flow rate [m3/day]) * (18000 / your local riverflow rate [m3/day]) * ((1 � your local WWTP efficiency)/0.1)



EC number:

200-578-6


64-17-5


9.6 Title: Exposure Scenario for Industrial use of Ethanol as fuel source

Ethanol REACH Association reference no. ES6a


SU3PROC16ERC7

Processes, tasks, activities covered Use as fuel or fuel additive in industrial setting.




Process category: Covers the use of material as fuel sources (including additives) where limited exposure to the product in its un-burned formis expected. Does not cover exposure as a consequence of spillage or combustion.

Environmental release category: Industrial use of substances in closed systems. Use in closed equipment, such as the use of liquids inhydraulic systems, cooling liquids in refrigerators and lubricants in engines and di-electric fluids in electric transformers and oil in heat exchang-ers. No intended contact between functional fluids and products foreseen, and thus low emissions via waste water and waste air to beexpected.









Potentially exposed body parts One hand, face side onlyHuman factors not influenced by riskmanagement







No specific measures identified




No specific PPE measures identified.

EC number:

200-578-6

ETHANOL CAS number:

64-17-5





Annually to the region 30,000 t/year (maximum in worst case)

Amounts used












Efficacy >70%





Degradation efficacy 90%Conditions and measures related tomunicipal sewage treatment plant









-

Environmental exposure estimation is based on Ecetoc TRA model v2 including the data from TGD A&B tables (MC-Ic, IC-9, UC-27, fractionmain source 0,02 using local STP, 350 emission days per year ).Ethanol is fully soluble in water, readily biodegradable, not bio-accumulative, does not accumulate in the sediments or soil and is assumed todegrade by 90% in the STP under evaluated conditions.











Guidance to DU to evaluate whether he works inside the boundaries set by the ESThe workers exposure and environmental emissions have been evaluated using Ecetoc TRA integrated tool version 2.If the local environmental emission conditions deviate significantly from the used default values, please use the algorithm below to estimate thecorrect local emissions and RCRs:PECcorrected = PECcalculated * (local emission fraction) * (local WWTP flow rate fraction) * (local river flow rate fraction) * (local STPefficiency fraction)Example for calculating your local freshwater PEC:Corrected freshwater PEC = 0,0152 * (your local emission [kg/day] / 5) * (2000 / your local WWTP flow rate [m3/day]) * (18000 / your local riverflow rate [m3/day]) * ((1 � your local WWTP efficiency)/0.1)



EC number:

200-578-6


64-17-5


9.7 Title: Exposure Scenario for Professional use of Ethanol as fuel source

Ethanol REACH Association reference no. ES6b


SU22PROC16ERC 9a, ERC 9b

Processes, tasks, activities covered Use as fuel or fuel additive in professional setting.




Process category: Covers the use of material as fuel sources (including additives) where limited exposure to the product in its unburned form isexpected. Does not cover exposure as a consequence of spillage or combustion.

Environmental release category: Professional use of substances in closed systems. Use in closed equipment, such as the use of liquids inhydraulic systems, cooling liquids in refrigerators and lubricants in engines and dielectric fluids in electric transformers and oil in heatexchangers. No intended contact between functional fluids and products foreseen, and thus low emissions via waste water and waste air to beexpected.




















No specific PPE measures identified.

EC number:

200-578-6

ETHANOL CAS number:

64-17-5





Annually to the region 380,000 t/year

Amounts used

Annually total 3,800,000 t/year total market for industrial,professional and consumer use

Frequency and duration of use Pattern of releaseContinuous wide dispersive: 365 days peryear







Do not discharge into sewers or drains.


Do not discharge directly into environment. Use in predominantly enclosed systems














-

Environmental exposure estimation is based on Ecetoc TRA model ERC9a, and TGD-A&B table (MC-IV, IC-6, UC-27). Below values arethose related to TGD A&B table calculation.Ethanol is fully soluble in water, readily biodegradable, not bio-accumulative, does not accumulate in the sediments or soil and is assumed todegrade by 90% in the STP under evaluated conditions.

Release times per year (day/year) 365 Local release to air (kg/day) n.a. wide dispersive

Fraction used at main local source 0,002 Local release to sewage (kg/day) n.a. wide dispersive

Amount used locally (kg/day) 2082 Local release to soil (kg/day) n.a. wide dispersive


In STP (mg/l) 0,065 580 -


In local soil (mg/kg) 0,0273 0,63 (mg/kgwwt) -




Guidance to DU to evaluate whether he works inside the boundaries set by the ESThe workers exposure and environmental emissions have been evaluated using Ecetoc TRA integrated tool version 2.If the local environmental emission conditions deviate significantly from the used default values, please use the algorithm below to estimate thecorrect local emissions and RCRs:PECcorrected = PECcalculated * (local emission fraction) * (local WWTP flow rate fraction) * (local river flow rate fraction) * (local STPefficiency fraction)Example for calculating your local freshwater PEC:Corrected freshwater PEC = 0,0240 * (your local emission [kg/day] / 5) * (2000 / your local WWTP flow rate [m3/day]) * (18000 / your local riverflow rate [m3/day]) * ((1 � your local WWTP efficiency)/0.1)



EC number:

200-578-6


64-17-5


9.8 Title: Exposure Scenario for Professional use of Ethanol in non-spray applications



SU22PROC10, PROC13, PROC14, PROC19ERC8a, ERC8d


Covers professional (end) use of ethanol as such or in preparations in non-spray application (e.g. as processing aid, cleaning agent, application ofcoatings). Indoor roller application, brushing and treatment of surfaces.Treatment of articles by dipping and pouring. Includes stabilization ofexplosives.




Process category: Low energy spreading of e.g. coatings. Including cleaning of surfaces. Substance can be inhaled as vapours, skin contactcan occur through droplets, splashes, working with wipes and handling of treated surfaces. Immersion operations. Treatment of articles bydipping, pouring, immersing, soaking, washing out or washing in substances; including cold formation or resin type matrix. Includes handling oftreated objects (e.g. after dying, plating,). Substance is applied to a surface by low energy techniques such as dipping the article into a bath orpouring a preparation onto a surface. Use of substances at small-scale laboratory (< 1 l or 1 kg). Addresses also occupations and activitieswhere intimate and intentional contact with substances occurs without any specific exposure controls other than PPE.

Environmental release category: Wide dispersive indoor use of processing aids by the public at large or professional use. Use (usually) resultsin direct release into the sewage system, for example, cosmetics, detergents in fabric washing, machine wash liquids and lavatory cleaners,automotive and bicycle care products (polishes, lubricants, de-icers), solvents in paints and adhesives or fragrances and aerosol propellants inair fresheners.










Two hands, face side only (PROC13, 14)Two hands (PROC10)Two hands and forearms (PROC19



2(PROC13, 14)

960 cm2

(PROC10)1980 cm

2(PROC19)


Setting (indoor/outdoor) Indoors and outdoors


If >4 hours/day (PROC19)Limit the substance concentration in theproduct to 25%


Provide a good standard of general or controlled ventilation. Natural ventilation is fromwindows and doors etc. Controlled ventilation means air is supplied or removed by a poweredfan.




If PROC 19 and concentration >25%

PPE: Wear suitable gloves tested to EN374and avoid skin contactPPE: Eye Protection � suitable eye protectionshould be worn when handling product ifthere is a risk of splashing .

EC number:

200-578-6

ETHANOL CAS number:

64-17-5





Annually at point source n.a. (wide dispersive use)

Amounts used













Do not release wastewater directly into environment. Wastewater release into municipal STP.





Contain and dispose of waste in accordance with environmental legislation and according tolocal regulations.

9.8.2. Exposure estimationWorkers exposure estimation is calculated with Ecetoc TRA model v2. Below given exposure estimates are based on the PROC with thehighest exposure levels in this scenario (PROC19).


Inhalation (mg/m3) 115,25 950

Dermal (mg/kd/day) 84,86 343

Combined (mg/kg/day) 101,32 343

PROC 19 results in the highest exposure in thisexposure scenario

Environmental exposure estimation is based on Ecetoc TRA model v2 based on ERC 8 a, d and TGD A&B table (MC-Ic, IC-6, UC-9). Belowvalues are estimates based on the ERC approach calculation resulting in more conservative values.Ethanol is fully soluble in water, readily biodegradable, not bio-accumulative, does not accumulate in the sediments or soil and is assumed todegrade by 90% in the STP under evaluated conditions.



Amount used locally (kg/day) 5.5 Local release to soil (kg/day) 1








Guidance to DU to evaluate whether he works inside the boundaries set by the ESThe workers exposure and environmental emissions have been evaluated using Ecetoc TRA integrated tool version 2.If the local environmental emission conditions deviate significantly from the used default values, please use the algorithm below to estimate thecorrect local emissions and RCRs:PECcorrected = PECcalculated * (local emission fraction) * (local WWTP flow rate fraction) * (local river flow rate fraction) * (local STPefficiency fraction)Example for calculating your local freshwater PEC:Orrected local freshwater PEC = 0,045 * (your local emission [kg/day] / 5) * (2000 / your local WWTP flow rate [m3/day]) * (18000 / your localriver flow rate [m3/day]) * ((1 � your local WWTP efficiency)/0.1)



EC number:

200-578-6


64-17-5


9.9 Title: Exposure Scenario for Professional use of Ethanol in spray applications



SU22PROC11ERC8a, ERC8d


Professional application of paints, coatings, adhesives, cleaners and othermixtures containing ethanol by spraying. Non industrial / professionalspraying of mixtures and products like paints, coatings, adhesives, polishes,cleaners, etc.




Process category: Air dispersive techniques. Spraying for surface coating, adhesives, polishes/cleaners, air care products, sandblasting.Substances can be inhaled as aerosols. The energy of the aerosol particles may require advanced exposure controls;

Environmental release category: Wide dispersive indoor and outdoor use of processing aids by the public at large or professional use. Use(usually) results in direct release into the sewage system, for example, cosmetics, detergents in fabric washing, machine wash liquids andlavatory cleaners, automotive and bicycle care products (polishes, lubricants, de-icers), solvents in paints and adhesives or fragrances andaerosol propellants in air fresheners.


9.9.1.2 Control of workers exposurePhysical state Liquid (spray aerosol)

Concentration of substance in product 5-25 %Product characteristic (including packagedesign affecting exposure)





Duration of exposure Variable

Potentially exposed body parts Two hands and forearmsHuman factors not influenced by riskmanagement

Potentially exposed skin surface 1500 cm2


Setting (indoor/outdoor) Indoors and/or outdoors

If duration of exposure > 4 hours/dayLimit the substance content in the product to5%

If duration of exposure 1-4 hours/dayLimit the substance content in the product to25%


If duration of exposure < 1 hours/day No specific measures identified

Substance content in the product > 25%

Provide enhanced general ventilation bymechanical means.Provide a good standard of general orcontrolled ventilation (5 to 15 air changes perhour)

Substance content in the product 5 - 25%

Provide a good standard of generalventilation. Natural ventilation is fromwindows and doors etc. Controlled ventilationmeans air is supplied or removed by apowered fan.


Substance content in the product < 5% No specific measures identified.


Do not carry out operation for more than 1 hour when substance content in the productexceeds 25% and no enhanced mechanical ventilation (minimum efficiency 70%) is available.


PPE: Respiratory Protection with at least90% reduction in inhaled concentration of thesubstance

Condition: If no enhanced ventilationavailable and concentration of the substancein the product > 25 %

EC number:

200-578-6

ETHANOL CAS number:

64-17-5


PPE: Wear suitable gloves (chemicallyresistant gloves tested to EN374) during theactivities where excessive skin contact ispossible.

Condition: If concentration of the substancein the product > 5 %

9.9.1.3 Control of environmental exposurePhysical state Liquid (sprayed)

Product characteristicsConcentration of substance in product 5 - 25 %



Amounts used













Do not release wastewater directly into environment. Wastewater release into municipal STP.






9.9.2. Exposure estimationWorkers exposure estimation is calculated with Ecetoc TRA model v2. Below given exposure estimates are based on the PROC with thehighest exposure levels in this scenario (PROC19).





-

Environmental exposure estimation is based on Ecetoc TRA model v2 based on ERC8a default settings and TGD A&B table (MC-Ic, IC-6,UC-9). Below values are estimates based on the ERC approach calculation resulting in more conservative values.Ethanol is fully soluble in water, readily biodegradable, not bio-accumulative, does not accumulate in the sediments or soil and is assumed todegrade by 90% in the STP under evaluated conditions.


Fraction used at main local source 0.1 Local release to waste water (kg/day) n.a. wide dispersive

Amount used locally (kg/day) 5.5 Local release to soil (kg/day) n.a. wide dispersive








Guidance to DU to evaluate whether he works inside the boundaries set by the ESThe workers exposure and environmental emissions have been evaluated using Ecetoc TRA integrated tool version 2.If the local environmental emission conditions deviate significantly from the used default values, please use the algorithm below to estimate thecorrect local emissions and RCRs:PECcorrected = PECcalculated * (local emission fraction) * (local WWTP flow rate fraction) * (local river flow rate fraction) * (local STPefficiency fraction)Example for calculating your local freshwater PEC:Corrected local freshwater PEC = 0,045 * (your local emission [kg/day] / 5) * (2000 / your local WWTP flow rate [m3/day]) * (18000 / your localriver flow rate [m3/day]) * ((1 � your local WWTP efficiency)/0.1)



EC number:

200-578-6


64-17-5


9.10 Title: Exposure Scenario for Consumer use of Ethanol as automotive fuel



SU21PC13ERC9a, ERC9b

Processes, tasks, activities covered Covers the consumer use of automotive fuels which contain Ethanol

Assessment Method Ecetoc TRA integrated model version 2, ConsExpo v 4.1



Product categories: Use of ethanol as automotive (vehicle) fuel. Minor exposure to ethanol vapours is possible during filling at the fillingstations or transfer from portable fuel cans. Exposure to ethanol during the actual use of fuel (running of the engine) is not expected undernormally foreseeable conditions of use since the substance is combusted in the (enclosed) engine system.

Environmental release category: Wide dispersive outdoor use by the public. Use (usually) results in minor direct release into environmentthrough accidental spillage and evaporation during the filling.


9.10.1.2 Control of consumer exposure

Substance content in the product Can be > 25 %

Amounts of product used / applied perevent

Up to 100 litre

Exposure/release fraction 0,001 (Only to vapour and minor spills during the filling of the tank)

Frequency of exposure: weekly

Frequency and duration of use/exposure

Duration of exposure per event: < 5 minutes (only during the filling of the tank)

Setting and external conditions duringuse

Outdoors

Technical (product related) use conditions No specific measures required.

Organisational consumer protectionmeasures (e.g. recommendation and/oruse instruction information for consumer;e.g. product labelling)

No specific measures required.

9.10.1.3 Control of environmental exposurePhysical state Liquid

Product characteristicsConcentration of substance in product Can be > 25 %



Amounts used

Annually total 3,800,000 t/year total market for industrial,professional and consumer use




Processing setting (indoor/outdoor) Outdoor



Conditions and measures related tomunicipal sewage treatment plant

No release into the wastewaters or sewage is expected from this use. Only environmentalrelease form the consumer use of ethanol as fuel is evaporation during filling (<0,01 %,assuming that less than 10 gram of ethanol evaporates during the filling of 75 litre tank during2-5 minutes).

Conditions and measures related todisposal of waste resulting from the useof the products

No waste expected from this use.

Conditions and measures related torecovery of waste resulting from the use n.a.

EC number:

200-578-6

ETHANOL CAS number:

64-17-5


9.10.2. Exposure estimationConsumer exposure estimation provided below is only indicative for one particular PC. The estimates are calculated with the industry model

(draft version MasterCSA_8April2010) CSA (PC13, Automotive, refuelling at 100% concentration).

Consumer exposure Exposure estimate DNEL Comment

Dermal (mg/kg/day) 35,00 LTS 206 -

Oral (mg/kg/day) 0,00 LTS 87 -

Inhalation (mg/m3 for 24hr day) 1,54 LTS 144 -

All routes systemic - - -

Environmental exposure estimation is based on Ecetoc TRA model v2 based on ERC8d customized settings and total use of 3,800,000 tpa.


Fraction used at main local source 0.002 Local release to waste water (kg/day) n.a. wide dispersive

Amount used locally (kg/day) n.a Local release to soil (kg/day) n.a. wide dispersive


In STP (mg/l) 0,065 580 -








EC number:

200-578-6


64-17-5


9.11 Title: Exposure Scenario for Consumer use of Ethanol as domestic fuel



SU21PC13ERC8a, ERC8d

Processes, tasks, activities coveredCovers the consumer use of domestic fuel products which contain Ethanol, e.g. ethanol fuelburners, fondue sets, heaters, etc. Includes garden equipment refuelling.




Product categories: Fuels (for domestic use) like ethanol liquid/gel filling for fireplaces, fondue sets, heaters, etc. During use, minor exposure ispossible during the transfer of the liquid product from the can/packaging into the holder or (burning-) device. No exposure to ethanol isexpected during the actual burning of the fuel since the ethanol vapours are fully combusted.

Environmental release category: Wide dispersive indoor and outdoor use by public at large. Use (usually) results in direct release into thesewage system or environment. In this use, as domestic fuel, only expected environmental release is through evaporation during filling of thedevice.



Substance content in the product > 25 %


Up to 1 litre

Potentially exposed body parts Inside one hand: 210 cm2

Frequency of use: weekly


Duration of use: 5 minutes (Only during the filling of the device)


Indoors and/or outdoors

Technical (product related) use conditions No specific measures required.

Organisational consumer protectionmeasures (e.g. recommendation and/oruse instruction information for consumer)

PPE: Eye Protection � suitable eye protection should be worn when handling product if thereis a risk of splashing .





Amounts used









No release into the wastewaters or sewage is expected from this use. Only environmentalrelease form the consumer use of ethanol as domestic fuel is evaporation during filling of theburner device.



Conditions and measures related torecovery of waste resulting from the use

n.a.

EC number:

200-578-6

ETHANOL CAS number:

64-17-5



(draft version MasterCSA_8April2010) CSA (PC13, Garden equipment-liquid-refuelling at concentration 100%).






Environmental exposure estimation is based on Ecetoc TRA model v2 based on ERC8a and d settings and total use of 10.000 tpa.Ethanol is fully soluble in water, readily biodegradable, not bio-accumulative, does not accumulate in the sediments or soil and is assumed todegrade by >90% in the STP under evaluated conditions.


Fraction used at main local source 0,002 Local release to waste water (kg/day) n.a. wide dispersive

Amount used locally (kg/day) n.a. Local release to soil (kg/day) n.a. wide dispersive


In STP (mg/l) 0,340 580 -






Additional good practice advice beyond theREACH CSANote: The measures reported in this section have not been taken into accountin the exposure estimates related to the exposure scenario above. They arenot subject to obligation laid down in Article 37 (4) of REACH

Use specific measures expected to reduce the predictedexposure beyond the level estimated based on the exposurescenario when possible.

EC number:

200-578-6


64-17-5


9.12 Title: Exposure Scenario for Consumer use of Ethanol in products (<50g per event)

Ethanol REACH Association reference no. ES9c


SU21PC: 1, 3, 8, 12, 14, 15, 18, 23, 24, 27, 28, 30, 31, 34, 39ERC8a, ERC8d

Processes, tasks, activities coveredCovers the consumer use of products which contain Ethanol with amount applied in use of lessthan 50g per event




Product categories: Adhesives (other than carpet and floor glue), sealants; Air care products; Artists supply and hobby preparations; Buildingand construction preparations; Metal-surface treatment products; Non-metal-surface treatment products; Ink and toners; Lawn and gardenpreparations; Leather tanning, finishing, impregnation, dye and care products; Lubricants, greases and release products; Plant protectionproducts; Cosmetics and toiletries; Perfumes and fragrances; Photo-chemicals; Polishes and wax blends; Textile dye, finishing andimpregnation products.

Environmental release category: Wide dispersive indoor and outdoor use. Use (usually) results in direct release into the sewage system orenvironment.



Substance content in the product < 1 % 1 � 5 % 5 � 25 % > 25 %

Product characteristic (including packagedesign affecting exposure)

PC24, PC31PC5, PC10, PC22,PC23, PC27, PC30,PC34

PC1, PC8, PC14,PC15, PC18,

PC3, PC28


< 50 g < 50 g < 50 g < 10 g

Frequency of use: Up to daily


Duration of use/application: up to 4 hours


Indoors (minimum room volume 20m3) or outdoors

Technical (product related) use conditions n.a. n.a. n.a.Controlled spray orrelease device.


No specificmeasures required.



Do not spray emptyin small, enclosedareas.Avoid inhalation andskin contact.

EC number:

200-578-6

ETHANOL CAS number:

64-17-5



Product characteristicsConcentration of substance in product Could be > 25 %



Amounts used

Annually total 10,000 t/year total market, excludingcosmetics and toiletries







Size of STP > 2000 m3/day


Sludge treatment (disposal or recovery) Disposal or recovery






(draft version MasterCSA_8April2010) CSA (PC31 Polishes and wax blends for floor, furniture, shoes).






Environmental exposure estimation is based on Ecetoc TRA model v2 based on ERC8a and ERC8d default settings. Below presentedestimates are based on ERC8d with total use of 10,000 tpa. This volume excludes cosmetics and toiletries use, where a 200,000 tpa totalmarket is assumed � all emissions from this sector are assumed to be emissions to air.Ethanol is fully soluble in water, readily biodegradable, not bio-accumulative, does not accumulate in the sediments or soil and is assumed tobe degraded for >90% in the STP under evaluated conditions.





In STP (mg/l) 0,340 580 -








EC number:

200-578-6


64-17-5


9.13 Title: Exposure Scenario for Consumer use of Ethanol in enclosed systems

Ethanol REACH Association reference no. ES9d


SU21PC16 (Heat transfer fluids), PC17 (Hydraulic fluids)ERC9a, ERC9b

Processes, tasks, activities coveredCovers the consumer use of products which contain Ethanol - products in enclosed systems(with no expected exposure to ethanol during use)




Product categories: Heat transfer fluids; Hydraulic fluids and other products where ethanol is part of the enclosed system and no exposure ofconsumers during the use of the product is expected under normal and reasonably foreseeable conditions of use.

Environmental release category: Indoor and outdoor use of substances by the public at large in closed systems. Use in closed equipment, suchas the use of cooling liquids in refrigerators, oil-based electric heaters, hydraulic liquids in automotive suspension, lubricants in motor oil andbrake fluids in automotive brake systems.



Substance content in the product > 25 %


Substance is enclosed in the system and there is no consumer exposure possible undernormal and reasonably foreseeable conditions of use.


n.a. substance in enclosed system

Frequency of use: 1-5 times per year


Duration per use: divers


n.a. substance in enclosed system

Technical (product related) use conditions n.a. substance in enclosed system


Do not open, break or dismantle the container during use. Do not open, break or dismantle thecontainer before disposal. Dispose off as chemical waste. PPE: Eye Protection � suitable eyeprotection should be worn when handling product if there is a risk of splashing .




Annually at point source n.a. (wide dispersive use in closed systems)

Amounts used









No release into the wastewaters or sewage is expected from this use. Substance is used inenclosed system during its service life.




n.a.

EC number:

200-578-6

ETHANOL CAS number:

64-17-5


9.13.2. Exposure estimationConsumer exposure estimation provided below is only indicative for one particular PC. The estimates are calculated with the industry model(draft version MasterCSA_8April2010)) CSA (Heat transfer fluid category).






Environmental exposure estimation is based on Ecetoc TRA model v2 based on ERC9a and b default settings and total use of 10.000 tpa.Ethanol is fully soluble in water, readily biodegradable, not bio-accumulative, does not accumulate in the sediments or soil and is assumed todegrade by >90% in the STP under evaluated conditions.





In STP (mg/l) 0,017 580 -








EC number:

200-578-6


64-17-5


9.14 Title: Exposure Scenario for Consumer use of Ethanol in coatings and paints

Ethanol REACH Association reference no. ES9e


SU21PC9a, PC9cERC8a, ERC8d

Processes, tasks, activities covered Covers the consumer use of coatings and paint products which contain Ethanol




Product categories: Coatings, paints, thinners and paint removers. Exposure to ethanol is possible during mixing, pouring and application(roller, brushing and spraying) of the products.

Environmental release category: Wide dispersive indoor and outdoor use of processing aids by the public at large. Use (usually) results indirect release into the sewage system or into environment.



Substance content in the product 1 � 15 %


50 � 250 gram

Exposed skin area 428 cm2(Inside hands or one hand)

Frequency of exposure: 1 � 5 times per year


Duration of exposure: 20 � 60 minutes


Indoors (room volume minimum 20 m3)

Outdoors

Technical (product related) use conditions Limit the ethanol content in the product to 15%.


Do not use in small, closed and not ventilated areas. Keep the doors and windows openduring use indoors.


Product characteristicsConcentration of substance in product 1 - 15 %



Amounts used













EC number:

200-578-6

ETHANOL CAS number:

64-17-5


9.14.2. Exposure estimationConsumer exposure estimation provided below is only indicative for one particular PC. The estimates are calculated with the industry model(draft version MasterCSA_8April2010)) CSA (category waterborne latex wall paint at 15% concentration).


Dermal (mg/kg/day) (on day of application)Dermal (mg/kg/day) (chronic)

21.440.30

n/aLTS 206

-


Inhalation (mg/m3 , mean event)Inhalation (mg/m3, chronic)

~3750.50

950LTS 144

-


Environmental exposure estimation is based on Ecetoc TRA model v2 based on ERC8a and d settings and total use of 10.000 tpa. Belowpresented estimates are based on ERC8d with total use of 10,000 tpa.Ethanol is fully soluble in water, readily biodegradable, not bio-accumulative, does not accumulate in the sediments or soil and is assumed tobe degraded for >90% in the STP under evaluated conditions.





In STP (mg/l) 0,340 580 -








EC number:

200-578-6


64-17-5


9.15 Title: Exposure Scenario for Consumer use of Ethanol in antifreeze, deicing andscreenwash products

Ethanol REACH Association reference no. ES9f


SU21PC4

ERC8d

Processes, tasks, activities coveredCovers the consumer use of antifreeze, deicing and screenwash products which containEthanol




Product categories: Anti-freeze, de-icing and screen-wash consumer products. The exposure is possible during the activities related to transferfrom the packaging, mixing and application of the product.



9.15.1.2 Control of consumer exposureSubstance content in the product > 25 %


1 � 50 gram

Exposed skin area 214 cm2

Frequency of use: weekly (up to 50 days per year)


Duration of exposure per event: < 5 minutes


Indoors and / or outdoors

Technical (product related) use conditions Controlled spray or dosing delivery device.







Amounts used













EC number:

200-578-6

ETHANOL CAS number:

64-17-5



(draft version MasterCSA_8April2010)) CSA (PC24 Lock- de-icer with conc 50%).


Dermal (mg/kg/day) 17,87 LTS 206

Oral (mg/kg/day) 0,00 LTS 87

Inhalation (mg/m3 for 24hr day) 0,51 LTS 144

All routes systemic - -

Based on one use aday of 0.25hr / event

Environmental exposure estimation is based on Ecetoc TRA model v2 based on ERC8d and TGD A&B table (MC-IV, IC-6, UC-5) settings.Ethanol is fully soluble in water, readily biodegradable, not bio-accumulative, does not accumulate in the sediments or soil and is assumed todegrade by >90% in the STP under evaluated conditions.





In STP (mg/l) 0,0011 580 -








EC number:

200-578-6


64-17-5


9.16 Title: Exposure Scenario for Consumer use of Ethanol in washing and cleaningproducts

Ethanol REACH Association reference no. ES9g


SU21PC35

ERC8a, ERC8d

Processes, tasks, activities covered Covers the consumer use of washing and cleaning products which contain Ethanol




Product categories: Washing and cleaning products including for example, toilet/bathroom cleaners, dishwashing liquid, laundry detergent etc.The exposure is possible during the activities related to transfer from the packaging, mixing and application of the product.



9.16.1.2 Control of consumer exposureSubstance content in the product < 5% 5 � 25 %


Laundry liquid detergents and softenersAll purpose cleanersFloor and carpet cleaners

All purpose toilet and bathroom cleanersGlass cleanersSpecial surfaces cleanersDish washing liquids


< 250 gram per event < 250 gram per event

Frequency: daily use Frequency: daily use


Duration of exposure: 15 minutes � 1 hour Duration of exposure: 15 minutes � 1 hour


Indoors or outdoors Indoors or outdoors

Technical (product related) use conditionsWhen spray application: Controlled spray ordelivery device.

When spray application: Controlled spray ordelivery device.


No specific measures required. Do not spray empty in small, enclosed areas.

EC number:

200-578-6

ETHANOL CAS number:

64-17-5






Amounts used














(draft version MasterCSA_8April2010)) CSA (for category all-purpose liquid cleaners with concentration of the substance at 15%)


Dermal (mg/kg/day) 10,7 LTS 206

Oral (mg/kg/day) 0,00 LTS 87

Inhalation (mg/m3 for 24hr day) 1,73 LTS 144

All routes systemic - -

Daily use

Environmental exposure estimation is based on Ecetoc TRA model v2 based on ERC8a and total volume of 40.000 tpa.Ethanol is fully soluble in water, readily biodegradable, not bio-accumulative, does not accumulate in the sediments or soil and is assumed todegrade by >90% in the STP under evaluated conditions.





In STP (mg/l) 0,681 580 -








EC number:

200-578-6


64-17-5


9.17 Title: Exposure Scenario for Industrial and Professional use of Ethanol aslaboratory agent



SU3, SU22PROC15ERC2, ERC4, ERC8a

Processes, tasks, activities covered Use as small scale laboratory reagent




Process category: Use of substances at small-scale laboratory at production locations, quality control utilities etc.(< 1 l or 1 kg). Largerlaboratories and R+D installations should be treated as industrial processes.

Environmental release category: Industrial use of processing aids in a batch process, not becoming part of an article using dedicated or multi-purpose equipment, either technically controlled or operated by manual interventions.








Duration of exposure 1 - 4 Hours/day




Setting (indoor/outdoor) Indoor









EC number:

200-578-6

ETHANOL CAS number:

64-17-5





Annually to the region 500 t/year

Amounts used









No specific onsite measures identified


No specific onsite measures identified














-

Environmental exposure estimation is based on Ecetoc TRA model v2 based on ERC 8a for professional use and TGD A&B table (MC-Ic, IC-15, UC-48) for industrial use. Below values are estimates based on the ERC8a approach calculation resulting in more conservative values. Allother settings result in lower exposure estimation values.Ethanol is fully soluble in water, readily biodegradable, not bio-accumulative, does not accumulate in the sediments or soil and is assumed todegrade by 90% in the STP under evaluated conditions.


Fraction used at main local source 0,1 Local release to sewage (kg/day) 3

Amount used locally (kg/day) 2,47 Local release to soil (kg/day) 1


In STP (mg/l) 0,170 580 -






Guidance to DU to evaluate whether he works inside the boundaries set by the ESThe workers exposure and environmental emissions have been evaluated using Ecetoc TRA integrated tool version 2.If the local environmental emission conditions deviate significantly from the used default values, please use the algorithm below to estimate thecorrect local emissions and RCRs:PECcorrected = PECcalculated * (local emission fraction) * (local WWTP flow rate fraction) * (local river flow rate fraction) * (local STPefficiency fraction)Example for calculating your local freshwater PEC:Corrected local freshwater PEC = 0,027 * (your local emission [kg/day] / 3) * (2000 / your local WWTP flow rate [m3/day]) * (18000 / your localriver flow rate [m3/day]) * ((1 � your local WWTP efficiency)/0.1)



EC number:

200-578-6


64-17-5


9.18 Title: Exposure Scenario for Industrial and Professional use of Ethanol as heattransfer fluid, or other functional fluid



SU3, SU22PROC20ERC7, ERC9a, ERC9b

Processes, tasks, activities coveredCovers use in heat and pressure transfer fluids in dispersive, professional use but closedsystems




Process category: Heat and pressure transfer fluids in dispersive, professional use but closed systems.

Environmental release categories: Industrial use of substances in closed systems. Use in closed equipment, such as the use of liquids inhydraulic systems, cooling liquids in refrigerators and lubricants in engines and dielectric fluids in electric transformers and oil in heatexchangers. No intended contact with the product produced. Indoor use of substances by the public at large or professional (small scale) use inclosed systems. Use in closed equipment, such as the use of cooling liquids in refrigerators, oil-based electric heaters.






Frequency of exposure (weekly) n.a.

Frequency of exposure (annual) n.a.Frequency and duration of use/exposure

Duration of exposure n.a.

Potentially exposed body parts Two hands, face side onlyHuman factors not influenced by riskmanagement



Setting (indoor/outdoor) Indoor and outdoor


Handle substance within a closed system.


Store substance within a closed system.


Substance in a closed system. No intended exposure to the substance.



EC number:

200-578-6

ETHANOL CAS number:

64-17-5





Annually to the region 1000 t/year

Amounts used


Frequency and duration of use Pattern of release No release into environment (closed system)


Flow rate of receiving surface water n.a.





No specific measures identified. Handle substance within a closed system.


No specific measures identified. Store substance within a closed system.


Use in closed systems; no intended release into environment.





All waste products are assumed to be collected and returned for re-processing or re-use.Contain and dispose of waste in accordance with environmental legislation and according tolocal regulations.






-

Environmental exposure estimation is based on Ecetoc TRA model v2. Below values are estimates based on the ERC9a approachcalculation. Ethanol is fully soluble in water, readily biodegradable, not bio-accumulative, does not accumulate in the sediments or soil and isassumed to degrade by 90% in the municipal STP under evaluated conditions.

Release times per year (day/year) 365 Local release to air (kg/day) ~ 0 (negligible)

Fraction used at main local source 0,1 Local release to sewage (kg/day) ~ 0 (negligible)

Amount used locally (kg/day) 5,5 Local release to soil (kg/day) ~ 0 (negligible)


In STP (mg/l) ~ 0 (negligible) 580 -






Guidance to DU to evaluate whether he works inside the boundaries set by the ESThe workers exposure and environmental emissions have been evaluated using Ecetoc TRA integrated tool version 2.If the local environmental emission conditions deviate significantly from the used default values, please use the algorithm below to estimate thecorrect local emissions and RCRs:PECcorrected = PECcalculated * (local emission fraction) * (local WWTP flow rate fraction) * (local river flow rate fraction) * (local STPefficiency fraction)



EC number:

200-578-6


64-17-5


9.19. Regional Exposure Assessment

The detail required for the regional exposure assessment should take into account the fact that this substance is

readily biodegradable and not bioaccumulative. The exposure assessment is modelled using the Mackay Level

III fugacity model v 2.80.1, with the following input parameters:

Regional model as specified in table R16-14 of the guidance.

The following half life values:

Compartment Half life (h)

Air 38

Water 96

Soil 96

Sediment 750

Suspended particles 96

Fish 96

Aerosol 96

Emission volumes used.

It should be noted that these volumes are based on the TOTAL volume of ethanol used in the EU � data

provided by the Ethanol REACH Association, The Hague, Netherlands for the exposure scenarios and

uses covered by the CSR. This regional exposure assessment therefore covers ALL market volumes of

ethanol used in listed scenarios and is not just limited to the individual registrants volume.

Emissions to water include allowance for degradation where waste water treatment plants (WWTP) are assumed

to be present in the exposure scenarios. Water emissions are reduced and air emissions increased as per

appendix R16-3 of the guidance. For wide dispersive uses (professional and consumer uses) it is assumed that

80% of water emissions pass through a WWTP.

Regional environmental missions (from

exposure scenarios ES1-18)

Air Water Soil

REACH Ethanol Association

emission scenario reference

number kg/day kg/day kg/day

ES1 (manuf of intermediates) 23 1.1 0

ES2 253 76 5.1

ES3 637 38 12.2

ES4 367 5 1

ES5 367 5 1

ES6a 9 1 2

ES7 49 5 1

ES10 3 3 1

ES11 0 0 0

ES8 2466 42 0

ES9a+ES6b 104 0 0

ES9b 3 0 0

ES9c (cosmetics) 49183 0 0

ES9c (all other uses) 1973 67 0

ES9d 137 42 137

ES9e 2144 36 0

ES9f 30985 496 0

ES9g 2087 2538 0

kg/day 91419 3354 160

kg/hr 3809 140 6.7

EC number:

200-578-6

ETHANOL CAS number:

64-17-5


Predicted regional

Exposure

Concentrations

value unit

Explanation / source of measured

data

Freshwater 7.72 µg/l Mackay Fugacity Level III model

Freshwater sediments 0.060 µg/kg Mackay Fugacity Level III model

Soil 0.252 µg/kg Mackay Fugacity Level III model

Air 1.11 µg/m3 Mackay Fugacity Level III model

Figures above exclude base level for continental exposure. To allow for this, concentrations need to be

increased by approximately 10%.

Predicted regional

Exposure

Concentrations

value unit

Explanation / source of measured

data

Fish 1.85E-04 µg/g Mackay Fugacity Level III model

As ethanol is both readily biodegradable and non bioaccumulative, regional concentration calculations in food

can be considered as likely to be substantially below any possible levels of concern.

ECnumber:

200-578-6

Ethanol(64-17-5EtOHRAdossier)

CASnumber:

64-17-5

2010-05-24CSR-PI-5.2.1

EXPOSURESCENARIOS

41

APPENDIX1TOCHAPTER9-USEMAPPINGFORETHANOL

(AdditionalguidancetoassistinidentifyingappropriateES�stouse)

ETHANOLACTIVITIEScoveredbyExposureScenariosunderREACH

23rdJune2010

Use/Activity

AreaofApplicationSectorofUse

ProcessCategory

(mandatory)

ProductCategory

Environmental

ReleaseCategory

EtOHREACHAssociation

ESreferencenumber

SU

PROC

PC

ERC

Manufacture,oruseasanintermediateor

processchemical

Industrial

3,8,9

1,2,3,4,8a,8b

1,4,6A

ES1,ES10

Bulkloading/unloadingofethanoland

blends(egmarine,road,rail,IBC)and

repacking(egdrums,smallpacks)

Industrial

3,8,9

8a,8b,9

2ES2

Formulationofpreparations,including

manufactureofcosmetics,detergents,

inksandcoatings

Industrial

3,10

3,5,8a,8b,9,14

2ES3,ES10

Detergentandcleaneruse(spray&non-

spray)

Industrial

37,10,13

4ES4,ES5

Professional

22

10,11,13,19

8A,8D

ES7,ES8

Consumer

21

3,4,9a,35

8A

ES9

Useindeicers/screenwash

Professional

22

11

8D

ES8

Consumer

21

48D

ES9

Cosmeticsuse(spray&non-spray)-

environmentandoccupationalonly

Consumer

21

28,39

8A,8D

ES9

Useincoatings,inks,andadhesives

Industrial

37,10,13,

4ES4,ES5

Professional

22

10,11,13,19

8A,8D

ES7,ES8

Consumer

21

1,4,9a,9c,15,

18,23,24,31

8A,8D

ES9

Laboratoryreagentsuse

Industrial

315

4ES10

ECnumber:

200-578-6

ETHANOL

CASnumber:

64-17-5

Created:2010-05-24

EXPOSURESCENARIOS

42

Use/Activity

AreaofApplicationSectorofUse

ProcessCategory

(mandatory)

ProductCategory

Environmental

ReleaseCategory

EtOHREACHAssociation

ESreferencenumber

Professional

22

15

8A

ES10

Explosivesmanufactureanddistribution

Professional

22

10,13,14,19

8A,8D

ES7

Heattransferfluiduse

Industrial

320

7ES11

Professional

22

20

9A

ES11

Consumer

21

16,17

9A

ES9

Manufactureoffuel,includingblending

Industrial

3,8,9

1,2,3,4,8a,8b,

1ES1,ES10

Formulationandpackingoffuel

preparationsandmixtures

Industrial

3,10

3,5,8a,8b,9,14

2ES3,ES10

Useasafuel

Industrial

316

7ES6a

Professional

22

16

9a,9b

ES6b

Consumer

21

13

9a,9b

ES9

Distributionoffuel

Industrial

3,8,10

8a,8b,9

2ES2

Otherconsumeruses

Consumer

21

1,3,4,8,9a,9c,

12,13,14,15,16,

17,18,23,24,27,

28,30,31,34,35,

39

8A,8B,8D

ES9

ECnumber:

200-578-6


CASnumber:

64-17-5

2010-05-24CSR-PI-5.2.1

EXPOSURESCENARIOS

43

APPENDIX2TOCHAPTER9�LISTOFEXPOSURESCENARIOS

(AdditionalguidancetoassistinidentifyingappropriateES�stouse)

ListofExposureScenarios

ES

DescriptiveTitle

SU

PROCs

ERC

PCs

Descriptionofactivities

ES1

Industrialmanufacturingofethanoland

useasintermediateorprocesschemical.

SU3,

SU8,

SU9

PROC1,

PROC2,

PROC3,

PROC4,

PROC8a,b

ERC1,

4,6a

n.a.

CoverstheindustrialmanufactureofEthanolatcontrolledmanufacturing

plantsincontinuousandbatchprocesses.Includesrecycling/recovery,

materialtransfers,filling,storage,maintenanceandloading,samplingand

useasanintermediateorprocesschemical.

ES2

DistibutionofEthanol

SU3,

SU8,

SU9

PROC8a,b,

PROC9,

ERC2

n.a.

Transferofsubstanceorpreparation(charging/discharging)from/to

vessels/largecontainersatnon-dedicatedanddedicatedfacilities.Includes

materialtransfers,storage,maintenanceandloading.Intendedfore.g.

traders,distributors,transporters,etc.Coversfuelactivities.

ES3

Industrialformulationand(re)packingof

Ethanolanditsmixtures

SU3,

SU10

PROC3,

PROC5,

PROC8a,

PROC8b,

PROC9,

PROC14

ERC2

Industrialmixingorblendinginbatchprocessesforformulationof

preparations,transferofsubstanceorpreparationintosmallcontainers

(dedicatedfillingline),andtransferofsubstanceorpreparation

(charging/discharging)from/tovessels/largecontainersatdedicatedand

non-dedicatedfacilities.

ThisExposureScenariocoversactivitiesofformulators/producersof

industrial,professionaland/orconsumerproductssuchascleaningagents,

cosmetics,coatings,paints,inks,lubricants,adhesives,pharmaceuticals,

fuelsetc.Intheseproductsandprocesses,ethanolisusedasaningredient,

solvent,additiveorstabilizer.

ES4

Industrial(end)useofethanolassuchor

inpreparationsinnon-sprayapplication

(e.g.asprocessingaid,cleaningagent,

solventoringredientincoatings,fuel

source)

SU3

PROC10,

PROC13

ERC4,

Indoorrollerapplication,brushingandtreatmentofsurfaces.Treatmentof

articlesbydippingandpouring.

ES5

Industrial(end)useofethanolassuchor

inpreparationsbyspraying(e.g.as

processingaid,cleaningagent,solventor

ingredientincoatings,paintsandinks)

SU3

PROC7

ERC4

Indoorpainting,applicationofcoatings,adhesives,polishes/cleaners,air

careproductsandothermixturescontainingethanolbyautomated

sprayingtechniquesinfactoriesorcomparableindustrialsettings.

ES6a

Industrialuseofethanolasfuelsource

SU3

PROC16

ERC7

Useasfuelorfueladditiveinindustrialsetting.

ECnumber:

200-578-6

ETHANOL

CASnumber:

64-17-5

Created:2010-05-24

EXPOSURESCENARIOS

44

ES6b

Professionaluseofethanolasfuelsource

SU22

PROC16

ERC9a,

9b

Useasfuelorfueladditiveinprofessionalandpublicdomainsetting.

ES7

Professional(end)useofethanolassuch

orinpreparationsinnon-sprayapplication

(e.g.asprocessingaid,cleaningagent,

applicationofcoatings,fuelsource)

SU22

PROC10,

PROC13,

PROC14,

PROC19

ERC8a,

8d

Indoorrollerapplication,brushingandtreatmentofsurfaces.Treatmentof

articlesbydippingandpouring.Useasfuelsourceinprofessionaland

publicdomainsetting.Includesstabilizationofexplosives.

ES8

Professionalapplicationofpaints,

coatings,adhesives,cleanersandother

mixtures/productscontainingethanolby

spraying.

SU22

PROC11

ERC8a,

8d

Nonindustrial/professionalsprayingofmixturesandproductssuchas

paints,coatings,adhesives,polishes,cleaners,deicers,screenwashetc.

ES9a

Consumeruseofproductswhichcontain

ethanol

SU21

n.a.

ERC9a,

9b

13

Useofautomotivefuelswhichcontainethanol

ES9b


ethanol

SU21

n.a.

ERC8a,

8d

13

Useofethanolindomesticfuelproducts(ethanolgelburners,fonduesets,

heatersetc)

ES9c


ethanol

SU21

n.a.

ERC8a,

8d

1,3,8,12,

14,15,18,

23,24,27,

28,30,31,

34,39

Useofethanolinconsumerproductswithamountappliedinuseof<50g

perevent

ES9d


ethanol

SU21

n.a.

ERC9a,

9b

16,17

Useofethanolinconsumerproductsinenclosedsystems(withno

expectedexposuretoethanolduringuse)

ES9e


ethanol

SU21

n.a.

ERC8a,

8d

9a

Consumeruseofethanolincoatingsandpaintproducts

ES9f


ethanol

SU21

n.a.

ERC8d

4Consumeruseofethanolinantifreeze,deicingandscreenwashproducts

ES9g


ethanol

SU21

n.a.

ERC8a,

8d

35

Consumeruseofethanolinwashingandcleaningproducts

ES10

Industrialuseaslaboratoryreagent

SU3

PROC15

ERC2,

4,8a

Useofsubstancesatsmallscalelaboratory(<1lor1kg).Larger

laboratoriesandR+Dinstallationsshouldbetreatedasindustrial

processes.

ES11

Industrialandprofessional(end)useof

ethanolasaheattransferfluid

SU3,

SU22

PROC20

ERC7,

9a,9b

Heatandpressuretransferfluidsindispersive,professionalusebutclosed

systems

ECnumber:

200-578-6


CASnumber:

64-17-5

2010-05-24CSR-PI-5.2.1

EXPOSURESCENARIOS

45

APPENDIX3TOCHAPTER9�DETAILSOFCSA-workerexposure

PART1

PROC

SETTINGSUSEDINECETOCTRAMODEL

ShortExposureScenario

name

ProcessCategory

(PROC)

ActivityType

Indoors/

Outdoors

Vent

Vent

eff%

Duration

(h)

inh

PPE

inh

PPE

eff%

derm

PPE

derm

PPE

MF

Prep?%

Dermal

maxexp

skinarea

(cm2)

1-Use

inclosedprocess,nolikelihoodof

exposure

Industrial

Indoors

No

>4hours

(default)

No

No

No

240

2-Use

inclosed,continuousprocess

with

occasionalcontrolledexposure

Industrial

Indoors

No

>4hours

(default)

No

No

No

480

8a-Transferofchemicalsfrom/tovessels/

largecontainersatnondedicatedfacilities

Industrial

Indoors

No

>4hours

(default)

No

No

No

960

8b-Transferofchemicalsfrom/tovessels/

largecontainersatdedicatedfacilities

Industrial

Indoors

No

>4hours

(default)

No

No

No

480

ES1

Industrialmanufacture

of

ethanolincontinuousprocesses

9-Transferofchemicalsinto

small

containers(dedicatedfillingline)

Industrial

Indoors

No

>4hours

(default)

No

No

No

480

3-Use

inclosedbatchprocess

(synthesis

orform

ulation)

Industrial

Indoors

No

>4hours

(default)

No

No

No

240

4-Use

inbatchandotherprocess

(synthesis)where

opportunityfor

exposure

arises

Industrial

Indoors

No

>4hours

(default)

No

No

No

480



Industrial

Indoors

No

>4hours

(default)

No

No

No

960



Industrial

Indoors

No

>4hours

(default)

No

No

No

480

ES1

Industrialm

anufacture

ofethanol

(anditsreactionproductsand/or

mixtures)inbatchprocesses


small


Industrial

Indoors

No

>4hours

(default)

No

No

No

480



Industrial

Indoors

No

>4hours

(default)

No

No

No

960



Industrial

Indoors

No

>4hours

(default)

No

No

No

480

ES2

Bulkdistribution,loading/

unloading,anddrumming

/repackingofethanoland

mixtures,productscontaining

ethanol(distributorandtrader

activities)


small


Industrial

Indoors

No

>4hours

(default)

No

No

No

480

3-Use


(synthesis

orform

ulation)

Industrial

Indoors

No

>4hours

(default)

No

No

No

240

Industrialuse

ES3

Industrialform

ulationof

preparations/mixturesand

products(adding,blendingand

5-M

ixingorblendinginbatchprocesses

(multistageand/orsignificantcontact)

Industrial

Indoors

No

>4hours

(default)

No

No

No

480

ECnumber:

200-578-6

ETHANOL

CASnumber:

64-17-5

Created:2010-05-24

EXPOSURESCENARIOS

46

PROC



name

ProcessCategory

(PROC)

ActivityType

Indoors/

Outdoors

Vent

Vent

eff%

Duration

(h)

inh

PPE

inh

PPE

eff%

derm

PPE

derm

PPE

MF

Prep?%

Dermal

maxexp

skinarea

(cm2)



Industrial

Indoors

No

>4hours

(default)

No

No

No

960



Industrial

Indoors

No

>4hours

(default)

No

No

No

480


small


Industrial

Indoors

No

>4hours

(default)

No

No

No

480

mixingofethanolinmixturesand

products)

14-Productionofpreparationsorarticles

bytabletting,compression,extrusion,

pelletisation

Industrial

Indoors

No

>4hours

(default)

No

No

No

480

10-Rollerapplicationorbrushing

Industrial

Indoors

No

>4hours

(default)

No

No

No

960

13-Treatm

entofarticlesbydippingand

pouring

Industrial

Indoors

No

>4hours

(default)

No

No

No

480

ES4

Industrial(end)use

ofethanolas

such

orinpreparations/products

innon-sprayapplication(e.g.as

processingaid,cleaningor

degreasingagent,applicationof

coatings,paints,inks,etc.),

includingindustrialuse

asfuel

7-Industrialspraying

Industrial

Indoors

No

>4hours

(default)

No

No

Yesat>25%

w/w

1500

ES5

Industrial(end)use/application

ofethanolassuch

orin

preparations/productsby

spraying(e.g.asprocessingaid,

cleaningordegreasingagent,

solventoringredientincoatings,

paintsandinks,etc.)


Industrial

Indoors

Yes

95

>4hours

(default)

No

No

Yesat>25%

w/w

1500

ES6a

16-Usingmaterialasfuelsources,limited

exposure

tounburnedproductto

be

expected

Industrial

Indoors

No

>4hours

(default)

No

No

No

240

ES6b

16-Usingmaterialasfuelsources,limited

exposure

tounburnedproductto

be

expected

Public

Domain

(Professional)

Indoors

No

>4hours

(default)

No

No

No

240

10-Rollerapplicationorbrushing

Public

Domain

(Professional)

Indoors

No

>4hours

(default)

No

No

No

960

Professional/Public

domainuse

ES7

Professional(end)use

ofethanol

assuch

orinpreparations/

13-Treatm

entofarticlesbydippingand

Public

Domain

Indoors

No

>4hours

No

No

Yesat>25%

480

ECnumber:

200-578-6


CASnumber:

64-17-5

2010-05-24CSR-PI-5.2.1

EXPOSURESCENARIOS

47

PROC



name

ProcessCategory

(PROC)

ActivityType

Indoors/

Outdoors

Vent

Vent

eff%

Duration

(h)

inh

PPE

inh

PPE

eff%

derm

PPE

derm

PPE

MF

Prep?%

Dermal

maxexp

skinarea

(cm2)

pouring

(Professional)

(default)

w/w

14-Productionofpreparationsorarticles

bytabletting,compression,extrusion,

pelletisation

Public

Domain

(Professional)

Indoors

No

>4hours

(default)

No

No

Yesat>25%

w/w

480

19-Hand-m

ixingwithintimate

contact

(onlyPPEavailable

Public

Domain

(Professional)

Indoors

No

>4hours

(default)

No

Yes

0.2

Yesat>25%

w/w

1980

19-Hand-m

ixingwithintimate

contact

(onlyPPEavailable

Public

Domain

(Professional)

Indoors

No

1-4

hours

No

No

Yesat>25%

w/w

1980

productsinnon-sprayapplication

(e.g.asprocessingaid,cleaningor


coatings,paintsandinks,etc.),

includingprofessionaluse

asfuel

19-Hand-m

ixingwithintimate

contact

(onlyPPEavailable

Public

Domain

(Professional)

Indoors

No

>4hours

(default)

No

No

Yesat5�

25%w/w

1980

19-Hand-m

ixingwithintimate

contact

(onlyPPEavailable

Public

Domain

(Professional)

Indoors

No

>4hours

(default)

No

No

Yesat1�

5%w/w

1980

19-Hand-m

ixingwithintimate

contact

(onlyPPEavailable

Public

Domain

(Professional)

Indoors

No

1-4

hours

No

No

Yesat5�

25%w/w

1980

19-Hand-m

ixingwithintimate

contact

(onlyPPEavailable

Public

Domain

(Professional)

Outdoors

Yes

>4hours

(default)

No

No

Yesat>25%

w/w

1980

11-Nonindustrialspraying

Public

Domain

(Professional)

Indoors

Yes

30

>4hours

(default)

No

Yes

0.2

Yesat>25%

w/w

1500


Public

Domain

(Professional)

Indoors

No

>4hours

(default)

No

No

Yesat5�

25%w/w

1500


Public

Domain

(Professional)

Indoors

No

>4hours

(default)

No

No

Yesat1�

5%w/w

1500


Public

Domain

(Professional)

Indoors

No

1-4

hours

No

Yes

0.2

Yesat5�

25%w/w

1500


Public

Domain

(Professional)

Indoors

Yes

80

>4hours

(default)

No

No

Yesat>25%

w/w

1500

ES8


coatings,adhesivesandother

mixtures/productscontaining

ethanolbyspraying.


Public

Domain

(Professional)

Outdoors

Yes

n.a.

>4hours

(default)

No

Yes

0.2

Yesat>25%

w/w

1500

ES9(Consumeruse)

15-Use

oflaboratory

reagentsinsm

all

scalelaboratories

Industrial

Indoors

No

>4hours

(default)

No

No

No

240

ES10

Industrialandprofessionaluse

as

laboratory

reagent

15-Use

oflaboratory

reagentsinsm

all

scalelaboratories

Public

Domain

(Professional)

Indoors

No

>4hours

(default)

No

No

No

240

ECnumber:

200-578-6

ETHANOL

CASnumber:

64-17-5

Created:2010-05-24

EXPOSURESCENARIOS

48

PROC



name

ProcessCategory

(PROC)

ActivityType

Indoors/

Outdoors

Vent

Vent

eff%

Duration

(h)

inh

PPE

inh

PPE

eff%

derm

PPE

derm

PPE

MF

Prep?%

Dermal

maxexp

skinarea

(cm2)

ES11


ofethanol

asaheattransferfluid

20-Heatandpressure

transferfluids

(closedsystems)indispersiveuse

Public

Domain

(Professional)

Indoors

No

>4hours

(default)

No

No

No

480

PART2

PROC

ESTIMATEOFEXPOSURES

RISKCHARACTERISATION

RATIO

RMM

phrase


name

ProcessCategory

(PROC)

Inhalative

ExpEst

(ppm)

Inhalative

ExpEst

(mg/m3)

Dermal

ExpEst

(mg/kg

bw/day)

Total

Derm

+Inh(mg/kg

bw/day)

Risk

Char-

Inh

Risk

Char

Derm

Risk

CharTotal

1-Use

inclosedprocess,no

likelihoodofexposure

0.01

0.01920833

0.3429

0.34564405

2.022E-05

0.0022123

0.00223

2-Use

inclosed,continuous

processwithoccasional

controlledexposure

10

19.2083333

1.3714

4.11544762

0.0202193

0.0088477

0.0265513

8a-Transferofchemicalsfrom/to

vessels/largecontainersatnon

dedicatedfacilities

50

96.0416667

13.7143

27.4345381

0.1010965

0.0884794

0.176997

8b-Transferofchemicals

from/tovessels/largecontainers

atdedicatedfacilities

50

96.0416667

6.8571

20.5773381

0.1010965

0.0442394

0.132757

ES1

Industrialm

anufacture

ofethanol

incontinuousprocesses


smallcontainers(dedicatedfilling

line)

50

96.0416667

6.8571

20.5773381

0.1010965

0.0442394

0.132757

3-Use


(synthesisorform

ulation)

25

48.0208333

0.3429

7.20301905

0.0505482

0.0022123

0.0464711

4-Use

inbatchandother

process(synthesis)where

opportunityforexposure

arises

20

38.4166667

6.8571

12.3451952

0.0404386

0.0442394

0.0796464



dedicatedfacilities

50

96.0416667

13.7143

27.4345381

0.1010965

0.0884794

0.176997




50

96.0416667

6.8571

20.5773381

0.1010965

0.0442394

0.132757

Industrialuse

ES1

Industrialm

anufacture

ofethanol

(anditsreactionproductsand/or

mixtures)inbatchprocesses



line)

50

96.0416667

6.8571

20.5773381

0.1010965

0.0442394

0.132757

ECnumber:

200-578-6


CASnumber:

64-17-5

2010-05-24CSR-PI-5.2.1

EXPOSURESCENARIOS

49

PROC

ESTIMATEOFEXPOSURES


RATIO

RMM

phrase


name

ProcessCategory

(PROC)

Inhalative

ExpEst

(ppm)

Inhalative

ExpEst

(mg/m3)

Dermal

ExpEst

(mg/kg

bw/day)

Total

Derm

+Inh(mg/kg

bw/day)

Risk

Char-

Inh

Risk

Char

Derm

Risk

CharTotal



dedicatedfacilities

50

96.0416667

13.7143

27.4345381

0.1010965

0.0884794

0.176997




50

96.0416667

6.8571

20.5773381

0.1010965

0.0442394

0.132757

ES2

Bulkdistribution,loading/

unloading,anddrumming

/repackingofethanolandmixtures,

productscontainingethanol

(distributorandtraderactivities)



line)

50

96.0416667

6.8571

20.5773381

0.1010965

0.0442394

0.132757

3-Use


(synthesisorform

ulation)

25

48.0208333

0.3429

7.20301905

0.0505482

0.0022123

0.0464711

5-M

ixingorblendinginbatch

processes(m

ultistageand/or

significantcontact)

50

96.0416667

13.7143

27.4345381

0.1010965

0.0884794

0.176997



dedicatedfacilities

50

96.0416667

13.7143

27.4345381

0.1010965

0.0884794

0.176997




50

96.0416667

6.8571

20.5773381

0.1010965

0.0442394

0.132757



line)

50

96.0416667

6.8571

20.5773381

0.1010965

0.0442394

0.132757

ES3

Industrialform

ulationof

preparations/mixturesand

products(adding,blendingand

mixingofethanolinmixturesand

products)

14-Productionofpreparations

orarticlesbytabletting,

compression,extrusion,

pelletisation

50

96.0416667

3.4286

17.1488381

0.1010965

0.02212

0.1106377

10-Rollerapplicationor

brushing

50

96.0416667

27.4286

41.1488381

0.1010965

0.1769587

0.2654764

13-Treatm

entofarticlesby

dippingandpouring

50

96.0416667

13.7143

27.4345381

0.1010965

0.0884794

0.176997

ES4

Industrial(end)use

ofethanolas

such

orinpreparations/productsin

non-sprayapplication(e.g.as



coatings,paints,inks,etc.),

includingindustrialuse

asfuel

ECnumber:

200-578-6

ETHANOL

CASnumber:

64-17-5

Created:2010-05-24

EXPOSURESCENARIOS

50

PROC

ESTIMATEOFEXPOSURES


RATIO

RMM

phrase


name

ProcessCategory

(PROC)

Inhalative

ExpEst

(ppm)

Inhalative

ExpEst

(mg/m3)

Dermal

ExpEst

(mg/kg

bw/day)

Total

Derm

+Inh(mg/kg

bw/day)

Risk

Char-

Inh

Risk

Char

Derm

Risk

CharTotal


250

480.208333

42.8571

111.45829

0.5054825

0.2764974

0.7190857

ES5

Industrial(end)use/applicationof

ethanolassuch

orinpreparations/

productsbyspraying(e.g.as


degreasingagent,solventor

ingredientincoatings,paintsand

inks,etc.)


12.5

24.0104167

2.1429

5.57295952

0.0252741

0.0138252

0.0359546

Minim

iseexposure

byenclosingthe

operationorequipmentandprovide

extractventilationatopenings;

Applywithinaventedcabsupplied

withfilteredairunderpositive

pressure

andwithaprotection

factorof>20

ES6a

16-Usingmaterialasfuel

sources,lim

itedexposure

to

unburnedproductto

be

expected

59.60416667

0.3429

1.71492381

0.0101096

0.0022123

0.011064

ES6b

16-Usingmaterialasfuel

sources,lim

itedexposure

to

unburnedproductto

be

expected

10

19.2083333

0.3429

3.08694762

0.0202193

0.0022123

0.0199158

10-Rollerapplicationor

brushing

100

192.083333

27.4286

54.8690762

0.202193

0.1769587

0.353994

13-Treatm

entofarticlesby

dippingandpouring

100

192.083333

13.7143

41.1547762

0.202193

0.0884794

0.2655147

14-Productionofpreparations

orarticlesbytabletting,

compression,extrusion,

pelletisation

100

192.083333

3.4286

30.8690762

0.202193

0.02212

0.1991553

19-Hand-m

ixingwithintimate

contact(onlyPPEavailable

100

192.083333

28.28572

55.7261962

0.202193

0.1824885

0.3595238

Wearsuitableglovestestedto

EN374andavoidskincontact;

19-Hand-m

ixingwithintimate


60

115.25

141.4286

157.892886

0.1213158

0.9124426

1.0186638

Donotcarryoutoperationformore

than4hours

ES7


ofethanolas

such

orinpreparations/products

innon-sprayapplication(e.g.as



coatings,paintsandinks,etc.),

includingprofessionaluse

asfuel

19-Hand-m

ixingwithintimate


60

115.25

84.85716

101.321446

0.1213158

0.5474655

0.6536867

Limitthesubstance

contentinthe

productto

25%

19-Hand-m

ixingwithintimate


20

38.4166667

28.28572

33.7738152

0.0404386

0.1824885

0.2178956

Limitthesubstance

contentinthe

productto

5%

Professional/Publicdomainuse

19-Hand-m

ixingwithintimate

36

69.15

84.85716

94.7357314

0.0727895

0.5474655

0.6111983


ECnumber:

200-578-6


CASnumber:

64-17-5

2010-05-24CSR-PI-5.2.1

EXPOSURESCENARIOS

51

PROC

ESTIMATEOFEXPOSURES


RATIO

RMM

phrase


name

ProcessCategory

(PROC)

Inhalative

ExpEst

(ppm)

Inhalative

ExpEst

(mg/m3)

Dermal

ExpEst

(mg/kg

bw/day)

Total

Derm

+Inh(mg/kg

bw/day)

Risk

Char-

Inh

Risk

Char

Derm

Risk

CharTotal


than4hours;Limitthesubstance

contentintheproductto

25%

19-Hand-m

ixingwithintimate


70

134.458333

141.4286

160.636933

0.1415351

0.9124426

1.0363673

Ensure

operationisundertaken

outdoors


350

672.291667

21.42858

117.470247

0.7076754

0.1382489

0.7578726

Provideagoodstandard

ofgeneral

ventilation.Naturalventilationis

from

windowsanddoorsetc.

Controlledventilationmeansairis

suppliedorremovedbyapowered

fan.;Wearsuitableglovestestedto

EN374


300

576.25

64.28574

146.607169

0.6065789

0.4147467

0.9458527

Limitthesubstance

contentinthe

productto

25%


100

192.083333

21.42858

48.8690562

0.202193

0.138249

0.315284

Limitthesubstance

contentinthe

productto

5%


180

345.75

21.42858

70.8214371

0.3639474

0.138249

0.4569125


than4hours;Wearsuitablegloves

testedto

EN374;Limitthesubstance


25%


100

192.083333

2.1429

29.5833762

0.202193

0.0138252

0.1908605

ES8


coatings,adhesivesandother

mixtures/productscontaining

ethanolbyspraying.


350

672.291667

21.42858

117.470247

0.7076754

0.1382489

0.7578726

Ensure

operationisundertaken

outdoors;Wearsuitablegloves

testedto

EN374ifsubstance

content

intheproductexceeds5%.

ES9(Consumeruse)

n.a.Consumeruse

isnotevaluatedwiththeEcetocTRAworkertool

15-Use

oflaboratory

reagentsin

smallscalelaboratories

10

19.2083333

0.3429

3.08694762

0.0202193

0.0022123

0.0199158

ES10


as

laboratory

reagent

15-Use

oflaboratory

reagentsin

smallscalelaboratories

10

19.2083333

0.3429

3.08694762

0.0202193

0.0022123

0.0199158

ES11


ofethanolas

aheattransferfluid

20-Heatandpressure

transfer

fluids(closedsystems)in

dispersiveuse

20

38.4166667

1.7143

7.20239524

0.0404386

0.01106

0.0464671

ECnumber:

200-578-6

ETHANOL

CASnumber:

64-17-5

Created:2010-05-24

EXPOSURESCENARIOS

52

ExposureModifiersforRefinementofECETOCTRAEstimates�WORKER

Ref3:Exposure

ModifiersforRefinementofECETOCTRAEstim

ates-WORKERS

Please

note

commentsincludedincell

annotations

1.Inhalationexposure

modifying

factor

description

ExamplesonlyofRMM-standard

phrases-SolventsIndustry

(ESIG/ESVOC)

a.

Concentration

1>25%

(notapplicable)

0.6

5-25%

Limitthesubstance


25%

[OC18]

0.2

1-5%

Limitthesubstance

inproductto

5%[OC17]

0.1

<1%

Limitthesubstance

inproductto

1%

[OC16]

b.

LEV-

professional

PROC12,24

75%

LEV:75%effective

Provideextractventilationto

pointswhere

emissionsoccur[E54]

Ensure

materialtransfersare

undercontainmentorextractventilation[E66]


materialtransferpointsandotheropenings[E82]

80%

LEV:80%effective


pointswhere

emissionsoccur[E54]

Ensure



PROC

2,3,4,5,6,8a,8b,9,10,11,

12,13,14,15,16,19,20,21,

23,25



PROC17,18

90%

LEV:90%effective

Minim

iseexposure

byenclosingtheoperationorequipmentandprovideextractventilationatopenings[E60]

Applywithinaventedcabsuppliedwithfilteredairunderpositivepressure

andwithaprotectionfactorof>20

[E70]

95%

LEV:95%effective

Carryoutinaventedbooth

orextractedenclosure

[E57]

LEV-industrial

PROC12,24

80%

LEV:80%effective


pointswhere

emissionsoccur[E54]

Ensure





90%

LEV:90%effective


pointswhere

emissionsoccur[E54]

Ensure



PROC

2,3,4,5,6,8a,9,10,13,

14,15,16,19,21,22,23,25



PROC7,8bsolids,17,18

95%

LEV:95%effective

Minim

iseexposure

byenclosingtheoperationorequipmentandprovideextractventilationatopenings[E60]

Applywithinaventedcabsuppliedwithfilteredairunderpositivepressure

andwithaprotectionfactorof>20

[E70]

PROC8bvolatiles

97%

LEV:97%effective


pointswhere

emissionsoccur[E54]

Ensure



ECnumber:

200-578-6


CASnumber:

64-17-5

2010-05-24CSR-PI-5.2.1

EXPOSURESCENARIOS

53

1.Inhalationexposure

modifying

factor

description

ExamplesonlyofRMM-standard

phrases-SolventsIndustry

(ESIG/ESVOC)



99%

LEV:99%effective

Carryoutinaventedbooth

providedwithlaminarairflow[E59]

Minim

iseexposure

byextractedfullenclosure

fortheoperationorequipment[E61]

c.Ventilation

professional/industrial

30%

30%effective

Ensure

operationisundertakenoutdoors

[E69]


ofgeneralventilation.Naturalventilationisfrom

windowsanddoorsetc.Controlled

ventilationmeansairissuppliedorremovedbyapoweredfan.[E1]

professional/industrial

70%

Controlledmechanicalventilation:

70%effective

Provideenhancedgeneralventilationbymechanicalm

eans[E48]


ofgeneralorcontrolledventilation(5

to15airchangesperhour)(E40]

d.

Durationofexposure

(note:check

alsoexposure

duringtask

againstDNEL-shortterm

)

1>4hours

(notapplicable)

0.6

1-4

hours

Avoidcarryingoutoperationformore

than4hours[OC12]

0.2

15min-1hour


than1hour[OC11]

0.1

<15min


than15minutes[OC10]

e.

RPE

0.1

halfmask

respirator

Weararespiratorconform

ingto

EN140withTypeAfilterorbetter.[PPE22]

Weararespiratorconform

ingto

EN140withTypeA/P2filterorbetter[PPE29]

0.05

fullface

respirator

Wearafullface

respiratorconform

ingto

EN140withTypeAfilterorbetter.[PPE24]

Wearafullface

respiratorconform

ingto

EN140withTypeA/P2filterorbetter.[PPE32]

0.025

(outsidescopeofTRA)

(sophisticatedform

sofRPEthatrequirespecialisedmaintenance)

2.Derm

alexposure

(toreduce

systemicexposure

andto

protectagainstsystemicadversehealth

effects)

modifying

factor

description

a.

Concentration

1>25%

(notapplicable)

0.6

5-25%

Limitthesubstance


25%

[OC18]

0.2

1-5%

Limitthesubstance

inproductto

5%[OC17]

0.1

<1%

Limitthesubstance

inproductto

1%

[OC16]

b.

LEVpresent

PROC1

0.1

PROC2

0.1

PROC3

0.1

PROC4

0.1

PROC5

0.005

Predictedderm

alexposure

value

variesbetw

eenPROCs.

Note:LEV

modifierforderm

alexposure

may

differfrom

LEVmodifiersfor

inhalatory

exposure

byPROC

ECnumber:

200-578-6

ETHANOL

CASnumber:

64-17-5

Created:2010-05-24

EXPOSURESCENARIOS

54

2.Derm

alexposure

(toreduce

systemicexposure

andto

protectagainstsystemicadversehealth

effects)

modifying

factor

description

PROC6

0.05

PROC7

0.05

PROC8a

0.01

PROC8b

0.1

PROC9

0.1

PROC10

0.05

PROC11

0.02

PROC12

0.1

PROC13

0.05

PROC14

0.1

PROC15

0.1

PROC16

0.1

PROC17

0.05

PROC18

0.05

PROC19

0.1

PROC20

0.1

PROC21

0.1

PROC22

0.3

PROC23

0.1

PROC24

0.1

PROC25

0.5

c.PPE

1nogloves,disposablegloves

withoutperm

eationdata

for

substance

0.2

wearsuitablegloves


EN374[PPE15]

0.1

chemically

resistantgloveswith

'basic'training

Wearchemically

resistantgloves(testedto

typeEN374)incombinationwith�basic�employeetraining[PPE16]

0.05

chemically

resistantgloveswith

specificactivitytraining

Wearchemically


typeEN374)incombinationwithspecificactivitytraining[PPE17]

0.02

chemically

resistantgloveswith

specificactivitytrainingand

intensivemanagementsuperv.

controls

Wearchemically


typeEN374)incombinationwithintensivemanagementsupervision

controls[PPE18]

Note:durationofexposure

isconsiderednotto

beanappropriate

modifyingfactorforderm

alexposure

ECnumber:

200-578-6


CASnumber:

64-17-5

2010-05-24CSR-PI-5.2.1

EXPOSURESCENARIOS

55

3.Additionalderm

alprotection?(toprotectagainslocaladverseskineffects;noexposure

modifyingfactor)

description

a.

ifsubstance/productiscorrosive,irritantorsensitizing-

>

Wearsuitablegloves


EN374[PPE15]

Hand,bodyandeyeprotection

Wearsuitablegloves(testedto

EN374),coverallandeyeprotection.[PPE23]

b.

ifcontributingscenario'sim

pliesdirectskin

contact

->

Recommended:Wearsuitable

gloves

{Wearsuitableglovestestedto

EN374[PPE15]}

Recommended:Hand,bodyand

eyeprotection

{Wearsuitablegloves(testedto

EN374),coverallandeyeprotection.[PPE23]}

ECnumber:

200-578-6

ETHANOL

CASnumber:

64-17-5

Created:2010-05-24

EXPOSURESCENARIOS

56

EnvironmentalExposureAssessmentforEthanol�WORKER

PART1

Exposure

scenarioinform

ation

Calculationapproach

Amountproducedorused

SewageTreatm

ent

Use

no.

Life

cyclestage

Use

mapped

ERC

approach

for

calculation

settings

Total

tonnage

foruse

Fractio

nof

tonnag

eto

region

M/I

tonnageto

region

Fmain

T(em

is)

M(use)

Use

of

local

STP?

STP

marine

?

Slud

ge

To

Soil?

STP

with

primar

y settler

?

River

(m3/d)

INDUSTRIALscenarios

ES1

Industrial

manufacture

of

ethanolincontinuous

processes

(ERC1,ERC6a)

1Manufacturing

Ind

Manufacturing

ofethanol

ERC1,6a

EUSES

MC-Ib,

IC-2,UC-

33

3000000

0.1

300000

300

yes

yes

no

yes

18000

ES1

Industrial

manufacture

of

ethanol(andits

reactionproducts

and/ormixtures)in

batchprocesses

1Manufacturing

Ind

Manufacturing

ofethanol

ERC1,6a

EUSES

MC-Ib,

IC-2,UC-

33

3000000

0.1

300000

300

yes

yes

no

yes

18000

(ERC1,ERC6a)

2Manufacturing

Ind

Manufacturing

ofethanol

(synthesis)

ERC1,6a

TGDA&B

table

MC-Ib,

IC-2,UC-

33

20000

0.1

2000

0.5

300

3333

yes

yes

no

yes

18000

ES2

3

Form

ulation

Form

ulationof

preparations

general

ERC2

TGDA&B

table

MC-Ib,

IC-2,UC-

48

150000

0.1

15000

0.1

300

5000

yes

yes

no

yes

18000

Bulkdistribution,

loading/unloading,

anddrumming

/repackingofethanol

andmixtures,

productscontaining

ethanol(distributor

andtraderactivities)

(ERC2)

ECnumber:

200-578-6


CASnumber:

64-17-5

2010-05-24CSR-PI-5.2.1

EXPOSURESCENARIOS

57

Exposure

scenarioinform

ation

Calculationapproach


SewageTreatm

ent

Use

no.

Life

cyclestage

Use

mapped

ERC

approach

for

calculation

settings

Total

tonnage

foruse

Fractio

nof

tonnag

eto

region

M/I

tonnageto

region

Fmain

T(em

is)

M(use)

Use

of

local

STP?

STP

marine

?

Slud

ge

To

Soil?

STP

with

primar

y settler

?

River

(m3/d)

ES3

3Form

ulation

Form

ulationof

preparations

general

ERC2

TGDA&B

table

MC-Ib,

IC-2,UC-

48

150000

0.1

15000

0.1

300

5000

yes

yes

no

yes

18000

Industrialform

ulation

of

preparations/mixture

sandproducts

(adding,blendingand

mixingofethanolin

mixturesand

products)

4Form

ulation

Form

ulationof

Paints,coatings

andadhesives

ERC2

TGDA&B

table

MC-Ib,

IC-14,

UC-48

100000

0.1

10000

0.2

300

6667

yes

yes

no

yes

18000

(ERC2)

5Form

ulation

Form

ulationof

fuels

ERC2

TGDA&B

table

MC-Ib,

IC-9,UC-

27

2800000

0.1

280000

0.1

300

93333

yes

yes

no

yes

18000

6Form

ulation

Form

ulationof

Cleaningagents

ERC2

TGDA&B

table

MC-Ib,

IC-5,UC-

9

65000

0.1

6500

0.1

300

2167

yes

no

no

yes

18000

7Form

ulation

Form

ulationof

cosm

etics

ERC2

TGDA&B

table

MC-Ib,

IC-5,UC-

15

200000

0.1

20000

0.1

300

6667

yes

yes

no

18000

ES4/ES6a

8Processing

Induse

in

coatings,paints,

inksand

adesives

ERC4

TGDA&B

table

MC-Ib,

IC-14,

UC-48

27500

0.1

2750

0.05

300

458

yes

yes

18000

Industrial(end)use

of

ethanolassuch

orin

preparations/

productsinnon-spray

application(e.g.as

processingaid,

cleaningor

degreasingagent,

applicationof

coatings,paints,inks,

etc.),including

industrialuse

asfuel

(ERC4)

9Processing

Induse

asfuel

ERC7

TGDA&B

table

MC-Ic,IC-

9,UC-27

300000

0.1

30000

0.02

350

1714

yes

yes

18000

ES5

8Processing

Induse

inERC4

TGDA&B

MC-Ib,

27500

0.1

2750

0.05

300

458

yes

yes

18000

ECnumber:

200-578-6

ETHANOL

CASnumber:

64-17-5

Created:2010-05-24

EXPOSURESCENARIOS

58

Exposure

scenarioinform

ation

Calculationapproach


SewageTreatm

ent

Use

no.

Life

cyclestage

Use

mapped

ERC

approach

for

calculation

settings

Total

tonnage

foruse

Fractio

nof

tonnag

eto

region

M/I

tonnageto

region

Fmain

T(em

is)

M(use)

Use

of

local

STP?

STP

marine

?

Slud

ge

To

Soil?

STP

with

primar

y settler

?

River

(m3/d)

Industrial(end)use/

applicationofethanol

assuch

orin

preparations/

productsbyspraying

(e.g.asprocessing

aid,cleaningor

degreasingagent,

solventoringredient

incoatings,paints

andinks,etc.)

(ERC4)

coatings,paints,

inksand

adesives

table

IC-14,

UC-48

PROFESSIONAL,PUBLICDOMAIN,CONSUMERSCENARIOS

ES7/ES6b

10

Processing

Professional/in

duse

in

cleaning,

coatings,paint

andinks

ERC4,

8a,b,d

TGDA&B

table

MC-Ic,IC-

6,UC-9

20000

0.1

2000

0.00 2

200

20

yes

yes

18000


ofethanolassuch

or

inpreparations/

productsinnon-spray

application(e.g.as

processingaid,

cleaningor

degreasingagent,

applicationof

coatings,paintsand

inks,etc.),including

professionaluse

as

fuel

(ERC8a,8b,8d,9a,

9b)

6Processing

Professionaluse

infuels

ERC9a,9b

TGDA&B

table

MC-Ic,IC-

6,UC-9

3800000

Total

Indust,

profess,

consume r

0.1

380000

0.00 2

365

yes

yes

18000

ECnumber:

200-578-6


CASnumber:

64-17-5

2010-05-24CSR-PI-5.2.1

EXPOSURESCENARIOS

59

Exposure

scenarioinform

ation

Calculationapproach


SewageTreatm

ent

Use

no.

Life

cyclestage

Use

mapped

ERC

approach

for

calculation

settings

Total

tonnage

foruse

Fractio

nof

tonnag

eto

region

M/I

tonnageto

region

Fmain

T(em

is)

M(use)

Use

of

local

STP?

STP

marine

?

Slud

ge

To

Soil?

STP

with

primar

y settler

?

River

(m3/d)

12

Servicelife

Private

use

in

cleaning,

coatingsand

paints

ERC8a,b,d

ERC

ERC8a

10000

0.1

1000

0.00 2

365

5.479

yes

yes

18000

ES8

Professional

applicationofpaints,

coatings,adhesives

andother

mixtures/products

containingethanolby

spraying.

10

Processing

Professional/in

duse

in

cleaning,

coatings,paint

andinks

ERC4,

8a,b,d

TGDA&B

table

MC-Ic,IC-

6,UC-9

20000

0.1

2000

0.00 2

200

20

yes

yes

18000

(ERC4,ERC8a,b,d)

12

Servicelife

Private

use

in

cleaning,

coatingsand

paints

ERC8a,b,d

ERC

ERC8a,

8d

10000

0.1

1000

0.00 2

365

5.479

yes

yes

18000

ES9

(Consumeruse)

12

Servicelife

Private/consum

eruse

of

products

containing

ethanol

ERC8a,b,d

ERC

ERC8a,

8d

10000

0.1

1000

0.00 2

365

5.479

yes

yes

18000

ES10

Industrialand

professionaluse

as

laboratory

reagent

11

Processing

Induse

of

functional

fluids;Induse

aslaboratory

agent

ERC4

TGDA&B

table

MC-Ic,IC-

15,UC-

48

10000

0.1

1000

0.05

300

166.7

yes

yes

18000

(ERC4,ERC8a,8d)

15

Processing/Serv

icelife

Professionaluse

aslaboratory

agent

ERC8a,b,d

ERC

ERC8d

5000

0.1

500

0.00 2

365

2.74

yes

yes

18000

ES11


ofethanolasaheat

transferfluid

(ERC7,ERC9a)

14

Servicelife

Prof.andcons.

use

of

functionalfluids

ERC7,9a

ERC

ERC9a

10000

0.1

1000

0.00 2

365

5.479

yes

yes

18000

ECnumber:

200-578-6

ETHANOL

CASnumber:

64-17-5

Created:2010-05-24

EXPOSURESCENARIOS

60

PART2

Localreleases

estim

ates(kg/d)

Regionalreleasesestim

ates(kg/d)

STP

Localfreshwater

Localm

arine

water

localsoil

Use

no.

Air

Water

Soil

Air

Wastewater

Soil

Freshwater

PEC

RCR

PEC

RCR

PEC

RCR

PEC

RCR

ES1

Industrialm

anufacture

ofethanolincontinuous

processes

(ERC1,ERC6a)

1100

300

8822

1970

0493

0.3100

0.1490

0.9400

0.1480

0.9300

0.0027

0.0130

ES1

Industrialm

anufacture

ofethanol(anditsreaction

productsand/ormixtures)inbatchprocesses

1100

300

8822

1970

0493

0.3100

0.1490

0.9400

0.1480

0.9300

0.0027

0.0130

(ERC1,ERC6a)

217

10

027

13

13

0.62140962

0.0011

0.0728

0.3833

0.0072

0.0451

0.0006

0.0129

ES2

Bulkdistribution,loading/unloading,anddrumming

/repackingofethanolandmixtures,products

containingethanol(distributorandtraderactivities)

(ERC2)

350

15

1411

99

424

0.93211443

0.0016

0.1039

0.5471

0.0103

0.0646

0.0014

0.0306

ES3

350

15

1411

99

424

0.93211443

0.0016

0.1039

0.5471

0.0103

0.0646

0.0014

0.0306

Industrialform

ulationofpreparations/mixturesand

products(adding,blendingandmixingofethanolin

mixturesandproducts)

467

20

1274

66

316

1.24281924

0.0021

0.1350

0.7105

0.0134

0.0840

0.0018

0.0393

(ERC2)

5467

28

93836

184

77

46

1.73994694

0.0030

0.1858

0.9781

0.0186

0.1164

0.0117

0.2533

60

217

413

142

30.08116415

0.0001

0.0188

0.0990

0.0018

0.0114

0.0002

0.0044

71

653

11

39

438

10

0.24973584

0.0004

0.0357

0.1881

0.0035

0.0220

0.0002

0.0051

ES4/ES6a

Industrial(end)use

ofethanolassuch

orin

preparations/productsinnon-sprayapplication(e.g.

asprocessingaid,cleaningordegreasingagent,

applicationofcoatings,paints,inks,etc.),including

industrialuse

asfuel

8367

50

6027

60

815

0.28481274

0.0005

0.0392

0.2061

0.0039

0.0241

0.0091

0.1963

(ERC4)

99

12

411

33

82

80.05326368

0.0001

0.0161

0.0849

0.0016

0.0098

0.0004

0.0098

ES5

Industrial(end)use/applicationofethanolassuch

or

inpreparations/productsbyspraying(e.g.as

processingaid,cleaningordegreasingagent,solvent

oringredientincoatings,paintsandinks,etc.)

8367

50

6027

60

815

0.28481274

0.0005

0.0392

0.2061

0.0039

0.0241

0.0091

0.1963

ES7/ES6b


ofethanolassuch

orin

preparations/productsinnon-sprayapplication(e.g.

asprocessingaid,cleaningordegreasingagent,

applicationofcoatings,paintsandinks,etc.),including

professionaluse

asfuel

10

020

16

04384

4384

1085

1.24281924

0.0021

0.1350

0.7103

0.0134

0.0840

0.0002

0.0042

ECnumber:

200-578-6


CASnumber:

64-17-5

2010-05-24CSR-PI-5.2.1

EXPOSURESCENARIOS

61

Localreleases

estim

ates(kg/d)


ates(kg/d)

STP

Localfreshwater

Localm

arine

water

localsoil

Use

no.

Air

Water

Soil

Air

Wastewater

Soil

Freshwater

PEC

RCR

PEC

RCR

PEC

RCR

PEC

RCR

(ERC8a,8b,8d,9a,9b)

60

20

16

04384

4384

1085

1.24281924

0.0021

0.1350

0.7103

0.0134

0.0840

0.0002

0.0042

12

55

02740

2192

0542

0.34049842

0.0006

0.0447

0.2354

0.0044

0.0276

0.0003

0.0076

ES8

Professionalapplicationofpaints,coatings,adhesives

andothermixtures/productscontainingethanolby

spraying.

10

020

16

04384

4384

1085

1.24281924

0.0021

0.1350

0.7103

0.0134

0.0840

0.0002

0.0042

(ERC4,ERC8a,b,d)

12

55

02740

2192

0542

0.34049842

0.0006

0.0447

0.2354

0.0044

0.0276

0.0003

0.0076

ES9

(Consumeruse)

12

55

02740

2192

0542

0.34049842

0.0006

0.0447

0.2354

0.0044

0.0276

0.0003

0.0076

ES10


aslaboratory

reagent

11

22

027

22

05

0.10356827

0.0002

0.0210

0.1107

0.0020

0.0128

0.0002

0.0050

(ERC4,ERC8a,8d)

15

33

01370

1096

14

271

0.17024921

0.0003

0.0277

0.1458

0.0027

0.0169

0.0002

0.0059

ES11


ofethanolasaheattransfer

fluid

(ERC7,ERC9a)

14

00

0137

00

00

0.0000

0.0107

0.0562

0.0010

0.0063

0.0002

0.0043

ECnumber:

200-578-6

ETHANOL

CASnumber:

64-17-5

Created:2010-05-24

EXPOSURESCENARIOS

62

APPENDIX4TOCHAPTER9�ECETOCTRAtoolcalculationforenvironmentalexposurescenarios

PART1

ESnr.

Exposure

scenarioinform

ation

Calculationapproach

Use

no.

Life

cycle

stage

Use

mapped

ERC

approach

settings

1,2,3

1Manufacturing

IndManufacturingofethanol

ERC1,6a

EUSES

seeEUSESreportfile

1,2,3

2Manufacturing

IndManufacturingofethanol(synthesis)

ERC1,6a

TGDA&Btable

MC-Ib,IC-2,UC-33

33

Form

ulation

Form

ulationofpreparationsgeneral

ERC2

TGDA&Btable

MC-Ib,IC-2,UC-48

34

Form

ulation

Form

ulationofPaints,coatingsandadhesives

ERC2

TGDA&Btable

MC-Ib,IC-14,UC-48

35

Form

ulation

Form

ulationoffuels

ERC2

TGDA&Btable

MC-Ib,IC-9,UC-27

36

Form

ulation

Form

ulationofCleaningagents

ERC2

TGDA&Btable

MC-Ib,IC-5,UC-9

37

Form

ulation

Form

ulationofcosm

etics

ERC2

TGDA&Btable

MC-Ib,IC-5,UC-15

4.5

8Processing

Induse

incoatings,paints,inksandadhesives

ERC4

TGDA&Btable

MC-Ib,IC-14,UC-48

6a

9Processing

Induse

asfuel

ERC4/ERC7

TGDA&Btable

MC-Ic,IC-9,UC-27

4,5,7

10

Processing

Professional/induse

incleaning

ERC4,

8a,b,d

TGDA&Btable

MC-Ic,IC-6,UC-9

11

11

Processing

Induse

offunctionalfluids;Induse

aslaboratory

agent

ERC7

TGDA&Btable

MC-Ic,IC-15,UC-48

8,9e

12

Servicelife

Private

use

incoatingsandpaints

ERC8a,b,d

ERC

ERC8a

8,9b

13

Servicelife

Private

use

asfuel(domesticfuels)

ERC8a,b,d

ERC

ERC8d

10

15

Processing

Professionaluse

aslaboratory

agent

ERC8a,b,d

ERC

ERC8d

6b,9a,11

14

Servicelife

Prof.andcons.use

offunctionalfluids,fuels

ERC7,9a

ERC

ERC9a

6b,9a,11

14

Servicelife

Prof.andcons.use

offunctionalfluids,fuels

ERC7,9b

ERC

MC-IV,IC-6,UC-27

ECnumber:

200-578-6


CASnumber:

64-17-5

2010-05-24CSR-PI-5.2.1

EXPOSURESCENARIOS

63

PART2

ESnr.


SewageTreatm

ent

Use

no.

Total

tonnagefor

use

Fractionof

tonnageto

region

M/Itonnage

toregion

Fmain

T(emis)

M(use)

Use

of

localSTP?

STP

marine?

SludgeTo

Soil?

STPwith

primary

settler?

River

(m3/d)

1,2,3

14600000

0.1

300000

350

yes

yes

no

yes

18000

1,2,3

220000

0.1

2000

0.5

300

3333

yes

yes

no

yes

18000

33

150000

0.1

15000

0.1

300

5000

yes

yes

no

yes

18000

34

100000

0.1

10000

0.2

300

6667

yes

yes

no

yes

18000

35

2800000

0.1

280000

0.1

300

93333

yes

yes

no

yes

18000

36

65000

0.1

6500

0.1

300

2167

yes

no

no

yes

18000

37

200000

0.1

20000

0.1

300

6667

yes

yes

no

18000

4.5

827500

0.1

2750

0.05

300

458

yes

yes

18000

6a

9300000

0.1

30000

0.02

350

1714

yes

yes

18000

4,5,7

10

20000

0.1

2000

0.002

200

20

yes

yes

18000

11

11

10000

0.1

1000

0.05

300

166.666667

yes

yes

18000

8,9e

12

10000

0.1

1000

0.002

365

5.47945205

yes

yes

18000

8,9b

13

10000

0.1

1000

0.002

365

5.47945205

yes

yes

18000

10

15

5000

0.1

500

0.002

365

2.73972603

yes

yes

18000

6b,9a,11

14

3800000

0.1

1000

0.002

365

2082

yes

yes

18000

6b,9a,11

14

3800000

0.1

1000

0.002

365

2082

yes

yes

18000

ECnumber:

200-578-6

ETHANOL

CASnumber:

64-17-5

Created:2010-05-24

EXPOSURESCENARIOS

64

PART3

Riskcharacterization

ESnr.

Localreleasesestim

ates

(kg/d)


ates(kg/d)

STP

Localfreshwater

Localmarine

water

localsoil

Use

no.

Air

Water

Soil

Air

Wastewater

Soil

Freshwater

PEC

RCR

PEC

RCR

PEC

RCR

PEC

RCR

1,2,3

1226

11

5.65

0.0970

0.0000

0.0001

0.0000

0.0000

0.0012

0.0360

1,2,3

217

10

027

13

13

0.62141

0.0011

0.0728

0.3833

0.0072

0.0451

0.0006

0.0129

33

50

15

1411

99

424

0.932114

0.0016

0.1039

0.5471

0.0103

0.0646

0.0014

0.0306

34

67

20

1274

66

316

1.242819

0.0021

0.1350

0.7105

0.0134

0.0840

0.0018

0.0393

35

467

28

93836

184

77

46

1.739947

0.0030

0.1858

0.9781

0.0186

0.1164

0.0117

0.2533

36

02

17

413

142

30.081164

0.0001

0.0188

0.0990

0.0018

0.0114

0.0002

0.0044

37

16

53

11

39

438

10

0.249736

0.0004

0.0357

0.1881

0.0035

0.0220

0.0002

0.0051

4.5

8367

50

6027

60

815

0.284813

0.0005

0.0392

0.2061

0.0039

0.0241

0.0091

0.1963

6a

99

12

411

33

82

80.053264

0.0001

0.0152

0.0800

0.0016

0.0099

0.0006

0.0160

4,5,7

10

020

16

04384

4384

1085

1.242819

0.0021

0.1350

0.7103

0.0134

0.0840

0.0002

0.0042

11

11

22

027

22

05

0.103568

0.0002

0.0210

0.1107

0.0020

0.0128

0.0002

0.0050

8,9e

12

55

02740

2192

0542

0.340498

0.0006

0.0447

0.2354

0.0044

0.0276

0.0003

0.0076

8,9b

13

55

02740

2192

27

542

0.340498

0.0006

0.0447

0.2354

0.0044

0.0276

0.0003

0.0076

10

15

33

01370

1096

14

271

0.170249

0.0003

0.0277

0.1458

0.0027

0.0169

0.0002

0.0059

6b,9a,11

14

104

00

104

00

00

0.0000

0.0110

0.0590

0.0013

0.0084

0.0037

0.0830

6b,9a,11

14

830

10

416000

416

103

104

0.065

0.0001

0.0240

0.1240

0.0034

0.0210

0.0273

0.6020

ECnumber:

200-578-6


CASnumber:

64-17-5

2010-05-24CSR-PI-5.2.1

EXPOSURESCENARIOS

65

APPENDIX5TOCHAPTER9�EthanolConsumerExposureCalculation

Forconsumerexposurecalculations,theGenericExposureScenario(GES)ToolwasusedthathasbeendevelopedbytheEuropeanSolvents

VOCCoordinationGroup(ESVOC),undertheaegisofCEFIC.TheversionoftheGESToolusedwasthelatest(atthattime)draftversion

dated8thApril2010.TheGESTooldefaultshavebeenapplied,usingtheHighVolatilitycase,i.e.vapourpressuregreaterthan10Pa.The

followingtableshowsthedivergencefromthedefaultvaluesusedintheGESTool.

Table2b:CharacterisingtheRisk-afterrefinementofexposureestimate

inhalation

inhalation

inhalation

Am

ountU

sed

per

even

t(g

)Location

(indo

ors

,outd

oors

,gara

ge)

Air

Exchang

eR

ate

(1/h

r)

Value

Comments

Value

Comments

PC1:Adhesives,sealants

GluesDIY-use(carpetglue,

tileglue,woodparquetglue)

50.0

0M

axim

um

accord

ing

toexp

osure

assessm

ent

indoor,typical

0.60

RIV

Mge

nera

lfa

ct

sheet


Gluefromspray

50.0

0M

axim

um

accord

ing

toexp

osure

assessm

ent

indoor,typical

0.60

RIV

Mge

nera

lfa

ct

sheet


Sealants

50.0

0M

axim

um

accord

ing

toexp

osure

assessm

ent

indoor,typical

0.60

RIV

Mge

nera

lfa

ct

sheet

PC

4_

n:A

nti-f

ree

ze

and

de-icin

gpro

ducts

Washin

gcar

win

do

w50

as

per

exposure

scenari

ooutdoor

0.60

est.

conserv

ative

va

lue

for

ou

tdo

or

PC

9a

:Co

atings

an

dpain

ts,fille

rsputt

ies,

thin

ners

Waterbornelatexwallpaint

2760

.00

est.

40

0sq

ftper

gallo

n,fo

rw

alls

of

20

m3

room

est.

304

sq

ftor

0.7

6ga

llons

=276

0g;

consis

tent

with

EP

A200

9E

FH

75

thperc

entile

indoor,ventilation

2.50

Defa

ult

for

TR

Ato

ol

with

this

sett

ing

ECnumber:

200-578-6

ETHANOL

CASnumber:

64-17-5

Created:2010-05-24

EXPOSURESCENARIOS

66

Table2b:CharacterisingtheRisk-afterrefinementofexposureestimate

inhalation

inhalation

inhalation

Am

ountU

sed

per

even

t(g

)Location

(indo

ors

,outd

oors

,gara

ge)

Air

Exchang

eR

ate

(1/h

r)

Value

Comments

Value

Comments

PC

9a

:Co

atings

an

dpain

ts,fille

rsputt

ies,

thin

ners

Solventrich,highsolid,water

bornepaint

744.0

0E

FH

2009

75th

perc

entile

oil

pain

tindoor,ventilation

2.50

Defa

ult

for

TR

Ato

ol

with

this

sett

ing

PC

9a

:Co

atings

an

dpain

ts,fille

rsputt

ies,

thin

ners

Aerosolspraycan

215.0

0E

FH

2009

75th

perc

entile

spra

ypain

tgara

ge

4.20

Guid

ance

R1

5,p

50,

all

do

ors

and

win

do

ws

op

en

PC9a:Coatingsandpaints,

fillersputties,thinners

Removers(paint-,glue-,wall

paper-,sealant-remover)

491.0

0E

FH

2009

75th

perc

entile

indoor,ventilation

2.50

Defa

ult

for

TR

Ato

ol

with

this

sett

ing

PC

15

_n:

Non-m

eta

lsurf

ace

treatm

ent

pro

ducts

Waterbornelatexwallpaint

2760

.00

est.

40

0sq

ftper

gallo

n,fo

rw

alls

of

20

m3

room

est.

304

sq

ftor

0.7

6ga

llons

=276

0g;

consis

tent

with

EP

A200

9E

FH

75

thperc

entile

indoor,ventilation

2.50

RIV

Mge

nera

lfa

ct

sheet

PC

15

_n:

Non-m

eta

lsurf

ace

treatm

ent

pro

ducts

Solventrich,highsolid,water

bornepaint

250.0

0M

axim

um

inE

Sindoor,ventilation

2.50

RIV

Mge

nera

lfa

ct

sheet

PC

15

_n:

Non-m

eta

lsurf

ace

treatm

ent

pro

ducts

Removers(paint-,glue-,wall

paper-,sealant-remover)

491.0

0E

FH

2009

75th

perc

entile

indoor,ventilation

2.50

RIV

Mge

nera

lfa

ct

sheet

EC number:

200-578-6


64-17-5


10. RISK CHARACTERISATION

10.1 Title: Exposure Scenario for Industrial manufacturing of Ethanol, or use asintermediate or process chemical


10.1.1. Human health10.1.1.1 Workers

Workers exposure Exposure estimate DNEL RCR Comment

Inhalation (mg/m3) 96.04 950 (OEL) 0.10

Dermal (mg/kd/day) 13.71 343 0.040

Combined (mg/kg/day) 27.43 343 0.080

PROC8a results in the highest exposure in thisexposure scenario

10.1.1.2 Consumer

Not applicable � No consumer exposure in this scenario

10.1.1.3 Indirect exposure to humans via the environment

Total daily intake vialocal environment(mg/kgdw/d)

Negligible compared to daily dietary intake and endogenous formation

10.1.2 Environmental10.1.2.1 Aquatic compartment PEC PNEC RCR Comment

In local freshwater (mg/l) 0.0000264 0.96 0.0000275 -

In local marine water (mg/l) 0.00000224 0.79 0.00000283 -

10.1.2.2. Terrestrial compartment PEC PNEC RCR Comment

In local soil (mg/kgwwt) 0.00119 0.63 0.00188 -

10.1.2.3. Atmospheric compartment PEC PNEC RCR Comment

Since it is not possible to derive a PNEC for this compartment, risk characterisation is not possible.

10.1.2.4. Microbiological activity in sewage treatment plants PEC PNEC RCR Comment

In STP (mg/l) 5.65 580 0.00974 -

10.2 Title: Exposure Scenario for Industrial distribution of Ethanol





Dermal (mg/kd/day) 13.71 343 0.04



10.2.1.2 Consumer













In STP (mg/l) 0.932 580 0.00161 -

EC number:

200-578-6


64-17-5


10.3 Title: Exposure Scenario for Industrial formulation and (re)packing of Ethanol, and itsmixtures





Dermal (mg/kd/day) 13.71 343 0.04



10.3.1.2 Consumer













In STP (mg/l) 1.73 580 0.00298 -

10.4 Title: Exposure Scenario for Industrial use of Ethanol in non-spray applications





Dermal (mg/kd/day) 27.43 343 0.08


PROC10 results in the highest exposure in thisexposure scenario

10.4.1.2 Consumer













In STP (mg/l) 0.285 580 0.000491 -

EC number:

200-578-6


64-17-5


10.5 Title: Exposure Scenario for Industrial use of Ethanol in spray applications





Dermal (mg/kd/day) 42.86 343 0.12


Exposure estimates and RCRs given here arecalculated for conditions without LEV (worst casescenario)

10.5.1.2 Consumer













In STP (mg/l) 0.285 580 0.000491 -

10.6 Title: Exposure Scenario for Industrial use of Ethanol as fuel source





Dermal (mg/kd/day) 0.3 343 0.0009


-

10.6.1.2 Consumer













In STP (mg/l) 0.053 580 0.0000914 -

EC number:

200-578-6


64-17-5


10.7 Title: Exposure Scenario for Professional use of Ethanol as fuel source





Dermal (mg/kd/day) 0.3 343 0.0008


-

10.7.1.2 Consumer













In STP (mg/l) 0.065 580 0.000112 -

10.8 Title: Exposure Scenario for Professional use of Ethanol in non-spray applications





Dermal (mg/kd/day) 84.86 343 0.247


PROC19 results in the highest exposure in thisexposure scenario

10.8.1.2 Consumer













In STP (mg/l) 0.34 580 0.000586 -

EC number:

200-578-6


64-17-5


10.9 Title: Exposure Scenario for Professional use of Ethanol in spray applications





Dermal (mg/kd/day) 21.43 343 0.06


-

10.9.1.2 Consumer













In STP (mg/l) 0.34 580 0.000586 -

10.10 Title: Exposure Scenario for Consumer use of Ethanol as automotive fuel



Not applicable � No worker exposure in this scenario

10.10.1.2 Consumer

Consumer exposure Exposure estimate DNEL RCR Comment

Dermal (mg/kd/day) 35.00 LTS 206 0.170

Oral (mg/kd/day) 0.00 LTS 87 0.00

Inhalation (mg/m3) 1.54 LTS 114 0.014

All routes systemic - - 0.184

-












In STP (mg/l) 0.065 580 0.000112 -

EC number:

200-578-6


64-17-5


10.11 Title: Exposure Scenario for Consumer use of Ethanol as domestic fuel




10.11.1.2 Consumer






-












In STP (mg/l) 0.34 580 0.000586 -

10.12 Title: Exposure Scenario for Consumer use of Ethanol in products (<50g per event)

Ethanol REACH Association reference no. ES9c



10.12.1.2 Consumer






Consumer exposure for PC39 is regulated by theCosmetic Directive 76/768/EEC and therefore outof scope for this section.












In STP (mg/l) 0.34 580 0.000586 -

EC number:

200-578-6


64-17-5


10.13 Title:Exposure Scenario for Consumer use of Ethanol in products in enclosed systems

Ethanol REACH Association reference no. ES9d



10.13.1.2 Consumer




Inhalation (mg/m3) 0.04 LTS 114 <0.001


-












In STP (mg/l) 0.017 580 0.0000293 -

10.14 Title: Exposure Scenario for Consumer use of Ethanol in products in coatings and paints

Ethanol REACH Association reference no. ES9e



10.14.1.2 Consumer


Dermal (mg/kd/day) (chronic) 0.3 LTS 206 0.001


Inhalation (mg/m3) (event)

Inhalation (mg/m3) (chronic)

375

0.5

950

LTS 114

0.395

0.004

All routes systemic (chronic) - - 0.005

-












In STP (mg/l) 0.34 580 0.000586 -

EC number:

200-578-6


64-17-5


10.15 Title: Exposure Scenario for Consumer use of Ethanol in antifreeze, deicing, andscreenwash products

Ethanol REACH Association reference no. ES9f



10.15.1.2 Consumer






Based on one use a day of 0.25hr / event












In STP (mg/l) 0.0011 580 0.0000019 -

10.16 Title: Exposure Scenario for Consumer use of Ethanol in washing and cleaningproducts

Ethanol REACH Association reference no. ES9g



10.16.1.2 Consumer






Based on daily use












In STP (mg/l) 0.681 580 0.00117 -

EC number:

200-578-6


64-17-5


10.17 Title: Exposure Scenario for Industrial and Professional use of Ethanol as laboratoryagent





Dermal (mg/kd/day) 0.34 343 0.001


-

10.17.1.2 Consumer













In STP (mg/l) 0.17 580 0.000293 -

10.18 Title: Exposure Scenario for Industrial and Professional use of Ethanol as heattransfer fluid, or other functional fluid





Dermal (mg/kd/day) 1.71 343 0.005


-

10.18.1.2 Consumer













In STP (mg/l) 0.0 (negligible) 580 0.0 (negligible)

EC number:

200-578-6


64-17-5


10.19 Overall exposure (combined for all relevant emission sources)

10.19.1 Human Health (combined for all exposure routes)The exposure scenarios for workers are not considered to exist in combination. Each has beencreated to cover all likely operational procedures in that particular part of the supply chain.Consideration of consumer scenarios in combination with worker scenarios needs to be in the contextof the very rapid metabolism of ethanol � any likely body burden from exposures to ethanols that fallwithin the conditions of the exposure scenarios are likely to have cleared from the bloodstream afterexposure ceases. Relevant combinations of consumer and worker scenarios that are relevant arelikely to be rare. The following combinations of worker and consumer scenarios that could occursimultaneously or in very close proximity are considered possible, if unlikely. References are the ESreference number according to the Ethanol REACH Association reference number:

Consumer scenarios in

combination

Worker

scenario

RCR of

worker

scenarioES9a ES9f

Combined

RCR

ES1 0.08 0.184 0.094 0.358

ES2 0.08 0.184 0.094 0.358

ES3 0.08 0.184 0.094 0.358

ES4 0.12 0.184 0.094 0.362

ES5 0.32 0.184 0.094 0.598

ES6a 0.005 0.184 0.094 0.283

ES6b 0.005 0.184 0.094 0.283

ES7 0.295 0.184 0.094 0.573

ES8 0.342 0.184 0.094 0.620

ES10 0.009 0.184 0.094 0.287

ES11 0.02 0.184 0.094 0.298

It is exceedingly unlikely that all consumer scenarios would be performed simultaneously in the spaceof the same day and every day. Even if this was the case, the combined RCR for exposure scenariosES9a to ES9g would be 0.916, ie still less than 1.Consideration of use in cosmetics is outside of the scope of this assessment.It can be considered that all feasible combinations of exposure scenarios would not lead to RCRsgreater than 1.

EC number:

200-578-6


64-17-5


10.19.2 Environment (combined for all exposure routes)

Note: The RCRs are calculated based on PECs that are derived from the TOTAL tonnage of ethanol that is used

in Europe and not a single supply chain. These tonnages were derived from information provided by the

Ethanol REACH Association, Den Haag, Netherlands.

Predicted Exposure

Concentrations

PNEC

Regional scenario

value unit value unit

RCR

Freshwater 7.72 µg/l 0.96 mg/l 0.00804

Freshwater sediments 0.060 µg/kg 3.6 mg/kg <0.0001

Soil 0.252 µg/kg 0.63 mg/kg 0.00040

Air 1.11 µg/m3 n/a n/a

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