List of Publications - caro.pci.uni- · PDF file1 Prof. Dr. rer. nat. habil. J. Caro Institut...

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1 Prof. Dr. rer. nat. habil. J. Caro Institut für Physikalische Chemie und Elektrochemie der Universität Hannover List of Publications (As of Dec 2017) a) PUBLICATIONS 1 J. Caro, J. Kärger, H. Pfeifer und R. Schöllner, Zur Selbstdiffusion von Methan in 5A-Zeolithen, Z. phys. Chemie (Leipzig), 256 (1975) 698. 2 J. Caro, Diplomarbeit: Adsorption und Diffusion in PAREX-Molekularsieben, Sektion Chemie der Universität Leipzig, 1975. 3 J. Caro, J. Kärger, G. Finger, H. Pfeifer und R. Schöllner, Zur Selbstdiffusion von Methan und Äthan in A-Zeolithen, Z. phys. Chemie (Leipzig), 257 (1976) 903. 4 J. Kärger und J. Caro, Intracrystalline Self-Diffusion of Methane in 5A Molecular Sieves, J. Coll. Interf. Sci., 52 (1975) 623. 5 J. Kärger, J. Caro und M. Bülow, Zum Einfluß von Oberflächenbarrieren auf den Sorptionsvorgang an 5A-Zeolithen, Z. Chem., 16 (19876) 331. 6 J. Kärger, J. Caro und M. Bülow, Zawisimost Kinetiki Adsorbcii Alkanow na Ceolite NaCaA ot Razmera Kristallow, Izw. Akad. Nauk SSSR, ser. khim., 12 (1977) 2666. 7 J. Kärger und J. Caro, Interpretation and Correlation of Zeolitic Diffusivities Obtained from Nuclear Magnetic Resonance and Sorption Experiments, J.C.S., Faraday Trans. I, 73 (1977) 1363. 8 J. Caro, Promotion A: Untersuchungen zum Transportverhalten am Adsorbatsystem n-Alkan/5A-Zeolith, Sektionen Physik und Chemie der Universität Leipzig, 1977. 9 J. Kärger, R. Danz und J. Caro, Anwendung der Interferenzmikroskopie bei der Beobachtung intrakristalliner Transportvorgänge, Feingerätetechnik, 27 (1978) 539. 10 J. Caro, M. Bülow und J. Kärger, Sorption Kinetics of n-Decane on 5A-Zeolites from a Nonadsorbing Liquid Solvent, AIChE Journal, 26 (1980) 1044. 11 J. Caro, M. Bülow, W. Schirmer, J. Kärger, W. Heink, H. Pfeifer und S.P. Zdanow, Microdynamics of Methane, Ethane and Propane in ZSM-5 Type Zeolites, J.C.S., Faraday Trans. I, 81 (1985) 2541. 12 J. Caro, M. Bülow und J. Kärger, Comment on Hydrocarbon Diffusivity in Zeolites, Chem. Engng Sci., 40 (1985) 2169. 13 J. Caro, S. Hocevar, J. Kärger und L. Riekert,

Transcript of List of Publications - caro.pci.uni- · PDF file1 Prof. Dr. rer. nat. habil. J. Caro Institut...

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Prof. Dr. rer. nat. habil. J. Caro Institut für Physikalische Chemie und Elektrochemie der Universität Hannover

List of Publications (As of Dec 2017)

a) PUBLICATIONS 1 J. Caro, J. Kärger, H. Pfeifer und R. Schöllner, Zur Selbstdiffusion von Methan in 5A-Zeolithen, Z. phys. Chemie (Leipzig), 256 (1975) 698. 2 J. Caro, Diplomarbeit: Adsorption und Diffusion in PAREX-Molekularsieben, Sektion Chemie der Universität Leipzig, 1975. 3 J. Caro, J. Kärger, G. Finger, H. Pfeifer und R. Schöllner, Zur Selbstdiffusion von Methan und Äthan in A-Zeolithen, Z. phys. Chemie (Leipzig), 257 (1976) 903. 4 J. Kärger und J. Caro, Intracrystalline Self-Diffusion of Methane in 5A Molecular Sieves, J. Coll. Interf. Sci., 52 (1975) 623. 5 J. Kärger, J. Caro und M. Bülow, Zum Einfluß von Oberflächenbarrieren auf den Sorptionsvorgang an 5A-Zeolithen, Z. Chem., 16 (19876) 331. 6 J. Kärger, J. Caro und M. Bülow, Zawisimost Kinetiki Adsorbcii Alkanow na Ceolite NaCaA ot Razmera Kristallow, Izw. Akad. Nauk SSSR, ser. khim., 12 (1977) 2666. 7 J. Kärger und J. Caro, Interpretation and Correlation of Zeolitic Diffusivities Obtained from Nuclear Magnetic Resonance and Sorption Experiments, J.C.S., Faraday Trans. I, 73 (1977) 1363. 8 J. Caro, Promotion A: Untersuchungen zum Transportverhalten am Adsorbatsystem n-Alkan/5A-Zeolith, Sektionen Physik und Chemie der Universität Leipzig, 1977. 9 J. Kärger, R. Danz und J. Caro, Anwendung der Interferenzmikroskopie bei der Beobachtung intrakristalliner Transportvorgänge, Feingerätetechnik, 27 (1978) 539. 10 J. Caro, M. Bülow und J. Kärger, Sorption Kinetics of n-Decane on 5A-Zeolites from a Nonadsorbing Liquid Solvent, AIChE Journal, 26 (1980) 1044. 11 J. Caro, M. Bülow, W. Schirmer, J. Kärger, W. Heink, H. Pfeifer und S.P. Zdanow, Microdynamics of Methane, Ethane and Propane in ZSM-5 Type Zeolites, J.C.S., Faraday Trans. I, 81 (1985) 2541. 12 J. Caro, M. Bülow und J. Kärger, Comment on Hydrocarbon Diffusivity in Zeolites, Chem. Engng Sci., 40 (1985) 2169. 13 J. Caro, S. Hocevar, J. Kärger und L. Riekert,

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Intracrystalline Self-Diffusion of H2O and CH4 in ZSM-5 Zeolites, Zeolites, 6 (1986) 213. 14 H. Pfeifer, J. Kärger, A. Germanus, W. Schirmer, M. Bülow und J. Caro, Concentration Dependence of Intracrystalline Self-Diffusion in Zeolites, Ads. Sci. & Technol., 2 (1985) 229. 15 J. Kärger, H. Pfeifer, J. Caro, M. Bülow, J. Richter-Mendau, B. Fahlke und L.V.C. Rees, Comparison of Molecular Transport in ZSM-5 Crystals of Different Habit, Appl. Catal., 24 (1986) 187. 16 J. Kärger, H. Pfeifer, J. Caro, M. Bülow, H. Schlodder, R. Mostowicz und J. Völter, Controlled Coke Deposition on Zeolite ZSM-5 and its Influence on Molecular Transport, Appl. Catal., 29 (1987) 21. 17 M. Bülow, J. Caro, J. Völter und J. Kärger, Coke Deposition on HZSM-5 Type Zeolites, in: Catalyst Deactivation (B.Delmon, G.F.Froment), Elsevier, 1987, S. 343. 18 J. Caro, M. Bülow, J. Richter-Mendau, J. Kärger, M. Hunger, D. Freude und L.V.C. Rees, Nuclear Magnetic Resonance Self-Diffusion Studies of Methanol-Water Mixtures in Pentasil-Type Zeolites, J.C.S., Faraday Trans. I., 83 (1987) 1843. 19 C. Förste, A. Germanus, J. Kärger, H. Pfeifer, J. Caro, W. Pilz und A. Zikanova, Molecular Mobility of Methane Adsorbed on ZSM-5 Containing Co- adsorbed Benzene, and the Location of Benzene Molecules, J.C.S., Faraday Trans.I, 83 (1987) 2301. 20 M. Hunger, J. Kärger, H. Pfeifer, J. Caro, B. Zibrowius, M. Bülow und R. Mostowicz, Investigation of Internal Silanol Groups as Structural Defects in ZSM-5-Type Zeolites, J.C.S., Faraday Trans.I, 83 (1987) 3459. 21 J. Völter, J. Caro, M. Bülow, B. Fahlke, J. Kärger und M. Hunger, Diffusion, Cracking and Coking on HZSM-5 of Various Morphologies, Appl. Catal., 42 (1988) 15. 22 B. Zibrowius, J. Caro und H. Pfeifer, Deuterium NMR Studies of the Molecular Dynamics of Benzene Sorbed on Zeolites, J.C.S., Faraday Trans.I, 84 (1988) 2347. 23 B. Zibrowius, J. Caro und J. Kärger, Application of NMR Spectroscopy to Study Diffusion Anisotropy in Polycrystalline Samples, Z. phys. Chem. (Leipzig), 269 (1988) 1101. 24 J. Kärger, M. Hunger, D. Freude, H. Pfeifer, J. Caro, M. Bülow und H. Spindler, NMR Investigations on Molecular Transport in ZSM-5 Typ Zeolites Containing Structural Defects, Catalysis Today, 3 (1988) 493. 25 K.-P. Roethe, R. Gutsche, W. Richter, A. Roethe, J. Caro und J. Kärger, Adsorption of aromatics on silica gel, Ads. Sci. & Techn., 3 (1986) 65. 26 J. Völter, G. Lietz, U. Kürschner, E. Löffler und J. Caro, Some Problems of Activity, Selectivity and Diffusivity in H-ZSM-5 Catalysts, Catalysis Today, 3 (1988) 407. 27 J. Caro, M. Bülow, J. Kärger und H. Pfeifer, The Influence of Chemisorbed Molecules on Mass Transfer in H-ZSM-5-Type Zeolites and the Location of Bronsted Acid Sites,

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J. Catal., 114 (1988) 186. 28 N. Van-Den-Begin, L.V.C. Rees, J. Caro und M. Bülow, Fast Adsorption-Desorption Kinetics of Hydrocarbons in Silicalite-1 by the Single-Step Frequency Response Technique, Zeolites, 9 (1989) 287. 29 M. Bülow, J. Caro, B.Röhl-Kuhn und B. Zibrowius, Molecular Mobility of Benzene and p-Xylene in MFI Structures, in: "Zeolites as Catalysts, Sorbents and Detergent Builders", Studies in Surface Science and Catalysis 46 (Eds. H. Karge etal.), Elsevier (1989) 505. 30 H. Jobic, M. Bee, J. Caro, M. Bülow und J. Kärger, Molecular Self-Diffusion of Methane in Zeolite ZSM-5 by Quasi-elastic Neutron Scattering and NMR Pulsed Field Gradient Technique, J.C.S., Faraday Trans. I, 85 (1989) 4201. 31 J. Caro, Promotion B (Habilitationsschrift): Struktur-Eigenschaft-Beziehungen bei der molekularen Selbstdiffusion von Gastmolekülen in Zeolithen, Akademie der Wissenschaften, Berlin, 1989. 32 H. Jobic, M. Bee, J. Kärger, H. Pfeifer und J. Caro, On the Translational Mobility of Benzene adsorbed on Na-type Zeolites, J. Chem. Soc., Chem. Commun., 1990, 341. 33 A. Micke, M. Kocirik und J. Caro, Volterra Integral Equations for the Determination of Diffusion Coefficients in Fast Pressure Jump Sorption Kinetics Experiments, J. Chem. Soc., Faraday Trans., 86 (1990) 3087. 34 J. Caro, M. Bülow, M. Derewinski, J. Haber, M. Hunger, J. Kärger, H. Pfeifer, W. Storek und B. Zibrowius, NMR and IR Studies of Zeolite H-ZSM-5 Modified with Orthophosphoric Acid, J. Catal., 124 (1990) 367. 35 H. Jobic, M. Bee, J. Caro, M. Bülow, J. Kärger und H. Pfeifer, Microdynamics of Guest Molecules in Zeolites Studied by Quasielastic Neutron Scattering and NMR Pulsed Field Gradient Technique, in : "Studies in Surface Science and Catalysis 65 (Eds. G. Öhlmann et al.), Elsevier (1991) 445. 36 D. Shen, L.V.C. Rees, J. Caro, M. Bülow, B. Zibrowius und H. Jobic, Diffusion of C4 Hydrocarbons in Silicalite-1, J. Chem. Soc. Faraday Trans., 86 (1990) 3943. 37 J. Caro, M. Bülow, M. Derewinski, M. Hunger, J. Kärger, U. Kürschner, H. Pfeifer, W. Storek und B. Zibrowius, NMR Characterization of Zeolite ZSM-5 after postsynthesis modification with H3PO4, in: Studies in Surface Science and Catalysis 52 (Eds. J. Klinowski and P. Barrie), Elsevier (1989), 295. 38 P. Kölsch, P. Toussaint und J. Caro, Testung von Adsorbenzien für die Druck-Wechsel-Adsorption, Chem.-Ing.-Technik, 8 (1991) 866. 39 L. Werner, J. Caro, G. Finger und J. Kornatowski, SHG on large AlPO4-5 and ZSM-5 crystals, Zeolites, 12 (1992) 658. 40 J. Caro, G. Finger, J. Kornatowski, J. Richter-Mendau, L. Werner und B. Zibrowius, Aligned Molecular Sieve Crystals,

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Advanced Materials, 4 (1992) 273. 41 Invited Chapter in "Advances in Catalysis": J. Caro, M. Bee, M. Bülow, H. Jobic, J. Kärger und B. Zibrowius, Molecular Mobility Measurement of Hydrocarbonsin Zeolites by NMR Techniques, Adv. Catal., 39 (1993) 351. 42 J. Caro, Aligned Molecular Sieve Crystals: New Horizons in Adsorption Science and Technology? Adsorption News, 3 (1992) 10. 43 F. Marlow und J. Caro, On the Anisotropy of the Optical Properties of Zeolites Loaded with Organic Molecules, Zeolites, 12 (1992) 433. 44 H. Jobic, M. Bee und J. Caro, Translational Mobility of n-Butane and n-Hexane in ZSM-5 Measured by Quasi-Elastic Neutron Scattering, Proc. 9th Intern. Zeolite Conf., Montreal 1992 (eds. R.von Ballmoos et al.), Butterworth-Heinemann 1993, S.121. 45 J. Caro, G. Finger, E. Jahn, J. Kornatowski, F. Marlow, M. Noack, L. Werner und B. Zibrowius, On the Innovation Potential of Aligned Molecular Sieve Crystals, Proc. 9th Intern. Zeolite Conf., Montreal 1992 (eds. R.von Ballmoos et al.), Butterworth-Heinemann 1993, S.683. 46 J. Caro, M. Noack, F. Marlow, D. Petersohn, M. Griepentrog und J. Kornatowski, On the Diffusion Anisotropy of ZSM-5, J. Phys. Chem., 97 (1993) 13685. 47 F. Marlow, W. Hill und J. Caro, Raman Study of p-Nitroaniline in the Channels of the Molecular Sieve AlPO4-5, J. of Raman Spectroscopy, 24 (1993) 603. 48 U. Rolle-Kampczyk, J. Kärger, M. Noack, J. Caro, B. Röhl-Kuhn und P. Klobes, PFG NMR Self-Diffusion Study of n-Alkanes in Silica Gel, J. Colloid Interf. Sci., 159 (1993) 366. 49 F. Marlow und J. Caro, Nonlinear Optical Effects on Dye Containing Molecular Sieves, Molec. Cryst. and Liquid Cryst., 240 (1994) 175. 50 F. Marlow, J. Caro, L. Werner, J. Kornatowski und S. Dähne, Optical Second Harmonic Generation of DMABN Molecules Incorporated in the Molecular Sieve AlPO-5, J. Phys. Chem., 97 (1993) 11286. 51 K. Hoffmann, F. Marlow, J. Caro und S. Dähne, Suppression of Twisted Excited States of DMABN by Adsorption in ZSM-5, Chem. Phys. Lett., 234 (1994) 2356. 52 K. Hoffmann, F, Marlow und J. Caro, Fluorescence of p-N,N-Dimethylaminobenzonitrile Incorporated in Pores of Molecular Sieves, J. of Fluorescence, 4 (1994) 75. 53 R. Mahrwald, U. Lohse, I. Girnus und J. Caro, Stereoselective Alkylation on Alumophosphate Molecular Sieves, Zeolites, 14 (1994) 486. 54 F. Marlow, M. Wübbenhorst und J. Caro,

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Pyroelectric Effects on Molecular Sieve Crystals Loaded with Dipole Molecules, J. Phys. Chem., 98 (1994) 12315. 55 I. Girnus, K. Hoffmann, F. Marlow und J.Caro, Large CoAPO-5 Single Crystals: Microwave Synthesis and Aniso-tropic Optical Absorption, Microporous Materials, 2 (1994) 537. 56 M. Noack, P. Kölsch, D. Venzke, P. Toussaint und J. Caro, A new One-Dimensional Membrane: Aligned AlPO4-5 Molecular Sieve Crystals in a Nickel Foil, Microporous Materials, 3 (1994) 201. 57 P. Kölsch, D. Venzke, M. Nooack, P. Toussaint und J. Caro, Zeolite-in-Metal Membranes: Preparation and Testing, J. Chem. Soc., Chem. Commun., 1994, 2491. 58 I. Girnus, K. Jancke, R. Vetter, J. Richter-Mendau und J. Caro, Large AlPO4-5 Crystals by Microwave Heating, Zeolites, 15 (1995) 33. 59 Invited Research News: J. Caro, F. Marlow und M. Wübbenhorst, Chromophore-Zeolite-Composites: On the organizing role of molecular sieves, Adv. Materials, 6 (1994) 413. 60 P. Kölsch, D. Venzke, M. Noack, E. Lieske, P. Toussaint und J. Caro Preparation and Testing of Silicalite-in-Metal-Membranes, in: Studies in Surface Science and Catalysis (Hrsgb. J. Weitkamp et al.), Elsevier Science, Vol. 84B, 1994, S. 1075. 61 F. Marlow, K. Hoffmann, W. Hill, J. Kornatowski und J. Caro, Optical Properties of Self-assembled Dipole Chains in Zeolites, in: Studies in Surface Science and Catalysis, (Hrsgb. J. Weitkamp et al.) Elsevier Science 84C, 1994, S. 2277. 62 I. Girnus, M.-M. Pohl, J. Richter-Mendau, M. Schneider, M. Noack und J. Caro Growth of Nanoporous Aluminiumphosphate Molecular Sieve Crystals for Membrane Applications by Microwave Heating Adv. Mat., 7 (1995) 711. 63 J. Caro und I. Girnus, Contribution to the Synthesis Atlas of the International Zeolite Association (ed. H. Robson): The AlPO4-5 synthesis (AFI), in: Microporous and Mesoporous Materials 22 (1998) 561. 64 F. Marlow, K. Hoffmann, G.-G. Lindner, I. Girnus, G. van de Goor, J. Kornatowski und J. Caro, Polarized Absorption Spectroscopy - An essential tool for the characterization of new zeolite materials, Microp. Mater., 6 (1996) 43. 65 P. Kölsch, D. Venzke und J. Caro, Neue Techniken mit dem Ion-Trap GC-MS, GIT Fachz. Lab. 5/95, 429. 66 G. Reck, F. Marlow, J. Kornatowski, W. Hill und J. Caro, On the Structure of Dipole Chains in an MFI type Molecular Sieve, J. Phys. Chem., 100 (1996) 1698. 67 K. Hoffmann, F. Marlow und J. Caro, Optical Characterization of Organized Adsorbates in Zeolite Microcrystals, Zeolites, 16 (1996) 281. 68 F. Marlow und J. Caro,

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Linear and Nonlinear Optical Effects of Guest Molecules in Molecular Sieve Crystals, in: Studies in Classical and Quantum Nonlinear Optics (ed: O. Keller), Nova Science Publishers, New York 1995, S. 653. 69 K. Hoffmann, F. Marlow, J. Caro und S. Dähne, Modification of fluorescence of p-N,N-dimethylaminobenzonitrile by adsorption in molecular sieves, Zeolites, 16 (1996) 138. 70 F. Marlow, J. Kornatowski, B. Reck, I. Leike, K. Hoffmann und J. Caro, Dipole chains in zeolite pores: The effects of symmetry breaking, Mol. Cryst. Liq. Cryst. 276 (1996) 295. 71 J. Caro, Trendbericht Physikalische Chemie: Nanoporöse Wirt/Gast-Systeme Nachr. Chem. Tech. Lab. 44 (1996) 195. 72 J. Caro, W. Lutz, K. Hoffmann, I. Girnus und B. Zibrowius, Microwave assisted preparation of one-dimensional molecular sieves, GIT Special, Chromatography International 96, 49 (1996). 73 J. Caro, F. Marlow, K. Hoffmann, C. Striebel, J. Kornatowski, I. Girnus, M. Noack und P. Kölsch, News from AlPO4-5: Microwave synthesis, application as medium to organize molecules for spectroscopy and nonlinear optics, material for one-dimensional membranes, in: Progress in Zeolite and Micropoporous Materials (eds. H.Chon, S.-K. Ihm, Y.S.Uh),

Stud. Surf. Science and Catal., 105 (1997), 2171. 74 K. Hoffmann, F. Marlow und J. Caro Photoinduced Switching in Nanocomposites of Azobenzene and Molecular Sieves, Adv. Mater., 9 (1997) 567. 75 V.V. Poborchii, A.V. Kolobov, J. Caro, V.V. Zhuravlev und K. Tanaka, Polarized Raman spectra of selenium species confined in nanochannels 0f AlPO4-5 single crystals, Chem. Phys. Lett., 280 (1997) 17. 76 K. Weh, M. Noack, R. Ruhmann, K. Hoffmann, P. Toussaint, J. Caro, Modification of mass transport through a PMMA-azobencene composite membrane by photochemical switching, Chem. Eng. Technol. 21 (1998) 5 77 P. Kölsch, M. Noack, P. Druska, D. Müller, P. Toussaint, J. Caro Keramik-Membranen mit molekularen Trenneigenschaften Teil I: SiOx-funktionalisierte Membranen, Chemie Ingenieur Technik, 70 (1998) 860. 78 M. Noack, P. Kölsch, P. Toussaint, P. Druska, J. Caro, Keramik-Membranen mit molekularen Trenneigenschaften Teil II: Funktionalisierung keramischer Membranen durch Silylierung, Chemie Ingenieur Technik, 70 (1998) 992. 79 M. Noack, P. Kölsch, U. Bentrup, P. Druska, P. Toussaint, J. Caro, Keramik-Membranen mit molekularen Trenneigenschaften Teil III: Phosphonylierung kommerzieller UF-Membranen für die molekulare Trennung, Chemie Ingenieur Technik, 70 (1998) 1331. 80 J. Caro, M. Noack, P. Kölsch, Chemically modified ceramic membranes for molecular separations, Microporous and Mesoporous Materials, 22 (1998) 321.

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81 P. Kölsch, M. Noack, J. Caro, L. Weh, Anwendungsmöglichkeiten mikroporöser Keramikmembranen mit molekularen Trenneigenschaften, Keramische Zeitschrift, 51 (1999) 112. 82 J. Hedlund, M. Noack, P. Kölsch, D. Creaser, J. Caro, J. Sterte, ZSM-5 membranes synthesized without organic templates using a seeding technique, J. Membr. Sci., 159 (1999) 263. 83 M. Noack, P. Kölsch, J. Caro, M. Schneider, P. Toussaint, I. Sieber, MFI membranes of different Si/Al for pervaporation and steam permeation, Microporous and Mesoporous Materials, 35/36 (2000) 253. 84 V.V. Poborchii, A.V. Kolobov, J. Caro, V.V. Zhuravlev, K. Tanaka,

Dynamics of single selenium chains confined in one-dimensional nanochannels of AlPO4-5: Temperature dependencies of the first and second order Raman spectra, Phys. Rev. Lett., 82 (1999) 1955.

85 V.V. Poborchii, A.V. Kolobov, H. Oyanagi, J. Caro, V.V. Zhuravlev, K. Tanaka, Raman and X-ray absorption spectra of selenium species in the channels of AlPO4-5 single crystals, Materials Research Society, Proc. 12

th Intern. Zeolite Conference, MRS, 1999, 2217.

86 P. Kölsch, M. Noack, J. Caro,

Hydrophile Membranen für die molekulare Trennung, 7. Aachener Membrankolloquium, 9.-11. März 1999, RWTH Aachen, ISBN 3-89653-550-1, 435.

87 Invited Review:

J. Caro, M. Noack, P. Kölsch, R. Schäfer, Zeolite Membranes – State of their Development and Perspectives, Microporous and Mesoporous Materials, 38 (2000) 3.

88 J. Caro, P. Kölsch, M. Noack, R. Schäfer, I. Voigt, G. Fischer, P. Puhlfürß, H. Richter,

Entwicklung poröser keramischer Membranen mit molekularer Trennleistung, Chemische Technik, 52 (2000) 1.

89 M. Noack, P. Kölsch, R. Schäfer, P. Toussaint, I. Sieber, J. Caro, Zeolite Membranes, Industrial Applications of Zeolites, ISBN 90-76019-13-4, 2000, p.25.

90 H. Kosslick, M. Richter, R. Fricke, M. Noack, J. Caro, Microwave-assisted zeolite crystallization, Ceramic Transactions 89 (1997) 523.

91 J. Caro, J.-P. Müller, in “Catalysis from A to Z” (ed. B. Cornils et al.), “Plasma-supported Catalyst Techniques”, Wiley-VCH, Weinheim 2000. 92 P. Kölsch, M. Noack, J. Caro, M. Sziladi, K. Kotsis, I. Sieber,

Keramische Membranen zur Wasserabtrennung aus Lösungsmitteln, Chemie Ingenieur Technik, 72 (2000) 1167.

2001 93 S. Thomas, R. Schäfer, J. Caro, A. Seidel-Morgenstern,

Investigation of mass transfer through inorganic membranes with several layers, Catal. Today, 67 (2001) 205.

94 M. Noack, P. Kölsch, R. Schäfer, P. Toussaint, J. Caro,

Molekularsiebmembranen für industrielle Anwendungen - Probleme, Fortschritte, Lösungen,

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Chemie Ingenieur Technik, 73 (2001) 958. 95 M. Noack, P. Kölsch, R. Schäfer, P. Toussaint, J. Caro, Preparation of MFI Membranes of enlarged area with high reproducibility, Microporous and Mesoporous Materials, 49 (2001) 25. 96 R. Schäfer, M. Noack, P. Kölsch, S. Thomas, A. Seidel-Morgenstern, J. Caro, Development of a H2-selective SiO2-membrane for the catalytic dehydrogenation of propane,

Separation and Purification, 25 (2001) 3.

97 U. Illgen, R. Schäfer, M. Noack, P. Kölsch, A. Kühnle, J. Caro, Membrane supported catalytic dehydrogenation of iso-butane using a MFI zeolite membrane,

Catalysis Communications, 2 (2001) 339.

2002 98 P. Kölsch, M. Noack, R. Schäfer, G. Georgi, R. Omorjan, J. Caro, Development of a permselective membrane reactor for increased yield in partial oxidation of

propane to acrolein, Journal of Membrane Science, 198 (2002) 119. 99 K. Weh, M. Noack, I. Sieber, J. Caro,

Permeation of single gas mixtures through faujasite type molecular sieve membranes, Microporous and Mesoporous Materials, 54 (2002) 27.

100 K. Weh, M. Noack, K. Hoffmann, K.-P. Schöder, J. Caro,

Change of gas permeation by photoinduced switching of zeolite azobenzene membranes of type MFI and FAU, Microporous and Mesoporous Materials, 54 (2002) 15.

101 J. Caro, Handbook of Porous Materials (eds. J. Weitkamp, F. Schüth, K.W. Sing)

Chapter 2.8 „Fluid Flow“ Wiley-VCH, 2002, 352 – 368.

102 P. Kölsch, M. Sziladi, M. Noack, J. Caro, L. Kotsis, I. Kotsis, I. Sieber, Ceramic Membranes for Water Separation from Organic Solvents, Chem. Eng. Technol. 25 (2002) 357

103 M. Noack, J. Caro, Handbook of Porous Materials (eds. J. Weitkamp, F. Schüth, K.W. Sing)

Chapter 6.2.2 „Zeolite Membranes » Wiley-VCH, 2002, 2433 - 2500

2003 104 R. Schäfer, M. Noack, P. Kölsch, M. Stöhr, J. Caro,

Comparison of different catalysts in the membrane-supported dehydrogenation of propane, Catal. Today, 82 (2003) 15. 105 P. Kölsch, Q. Smejkal,

M. Noack, R. Schäfer, J. Caro,

Partial oxidation of propane to acrolein in a membrane reactor - Experimental data and computer simulation, Catalysis Communications, 3 (2002) 465.

106 P. Kölsch, R. Schäfer, M. Noack, V. Seefeld, J. Caro, Water management of burning gases for the PEM,

9. Aachener Membrankolloquium, 18.-20.3. 2003, Verlag Mainz, ISBN 3-86130-185-7. 107 J.B. Stelzer, H. Kosslick, J. Caro, D. Habel, E. Feike, H. Schubert,

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Aufbau und katalytische Aktivität hierarchisch strukturierter Oxidkatalysatoren Teil I, Chemie Ingenieur Technik, 75 (2003) 873. 108 J.B. Stelzer, D. Habel. M.-M. Pohl, H. Kosslick, E. Feike, J. Caro, H. Schubert, Aufbau und katalytische Aktivität hierarchisch strukturierter Oxidkatalysatoren Teil II, Chemie Ingenieur Technik, 75 (2003) 1656. 109 D. Habel, J. B. Stelzer, J. Caro, M.-M. Pohl, E. Feike, H. Schubert,

Hierarchical nanostructured design of metal-oxide catalysts, EuroMAT 2003, Laussane, Switzerland, September 1 - 5, (2003)

2004 110 J.B. Stelzer, A. Feldhoff, J. Caro, M. Fait, D. Habel, E. Feike, H. Schubert,

Aufbau und katalytische Aktivität hierarchisch strukturierter Oxidkatalysatoren – Teil III: Einfluss der Calcinierungstemperatur auf Stabilität und katalytisches Verhalten geträgerter V2O5/TiO2-Katalysatoren,

Chemie Ingenieur Technik, 76 (2004) 1086. 111 J. Caro,

Invited Plenary Lecture: Zeolites and mesoporous materials as advanced functional material, Proc. 14

th International Zeolite Conference, Cape Town, South Africa, 25 30 April 2004, ISBN:

0-958-46636-X, p. 82. 112 O. Bartels, D. Wöhrle, J. Caro, M. Wark,

Immobilization and photocatalytic properties of phthalocyanines anchored to the surface of Si-MCM-41 and SBA-15, Proc. 14

th International Zeolite Conference, Cape Town, South Africa, 25 - 30 April 2004,

ISBN: 0-958-46636-X, p. 988. 113 J.B. Stelzer, U. Bentrup, B. Kubias, H.-J. Eberle, M. Fait, J. Caro,

Nano-structured vanadia catalysts with hierarchical architecture in the oxyhydrative scission of 1-butene to acetic acid,

Chemical Engineering Technology, 27 (2004) 1296. 114 J. Caro, G. Grubert, S. Schirrmeister, K.-J. Caspary, Membranreaktoren in der Stoffwandlung – Stand und Perspektiven, Chemie Ingenieur Technik, 76 (2004) 1270. 115 J.B. Stelzer, J. Caro,

Das Konzept der hierarchischen Metalloxid-Katalysatoren, Chemie Ingenieur Technik, 76 (2004) 1298.

116 B. Stelzer, J. Caro, D. Habel, E. Feike, H. Schubert, M. Fait, G. Hidde,

Hierarchical nano-structured design of metal-oxide catalysts, Part I “Influence of nano-structuring on the activity of the catalysts”,

Chem. Eng. Technol. 27 (08/2004) 839.

2005 117 J.B. Stelzer, M. Fait, J. Caro,

Oxidative dehydrogenation of propane (ODP) on TiO2 supported antimony oxide/vanadia catalysts with hierarchical nano-structure,

Catalys. Commun. 6 (01/2005) 1. 118 J.B. Stelzer, R. Nitzsche, J. Caro, Zeta potential measurement in catalyst preparation, Chemical Engineering Technology, 28 (2005) 182. 119 J.B. Stelzer, C. Schröder, J. Caro, M. Fait, U. Bentrup,

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Aufbau und katalytische Aktivität hierarchisch nanostrukturierter Oxid-Katalysatoren – Teil 4: Einfluss der Vanadiumprecursoren auf das katalytische Verhalten von TiO2/SbO2/VOx,

Chemie Ingenieur Technik, 77 (2005) 406. 120 M. Noack, P. Kölsch, V. Seefeld, P. Toussaint, G. Georgi, J. Caro, Influence of the Si/Al-ratio on the permeation properties of MFI-membranes, Microporous and Mesoporous Materials 79 (2005) 329. 121 H. Wang, W. Yang, C. Tablet, J. Caro, Oxygen diffusion through perovskite membranes, Online Journal http://www.diffusion-fundamentals.org. 122 C. Tablet, G. Grubert, H. Wang, T. Schiestel, M. Schroeder, B. Langanke, J. Caro Oxygen permeation study of perovskite hollow fiber membranes, Catalysis Today 104 (2005) 126. 123 A. Kleinert, G. Grubert, X. Pan, C. Hamel, A. Seidel-Morgenstern, J. Caro, Compatibility of hydrogen transfer via Pd-membranes with the rates of heterogeneously

catalyssed steam reforming, Catalysis Today 104 (2005) 267. 124 T. Oekermann, T. Yoshida, C. Boeckler, J. Caro, H. Minora, Capacitance and Field-driven

Electron Transport in Electrochemically Self-Assembled Nonaoporous ZnO/Dye Hybrid Films, J. Phys. Chem. B 109 (2005) 12560

125 M. Noack, G.T.P. Mabande, J. Caro, G. Georgi, W. Schwieger, P. Kölsch, A. Avhale,

Influence of Si/Al ratio, pre-treatment and measurement conditions on permeation properties of MFI membranes on metallic and ceramic supports,

Microporous Mesoporous Materials 82 (2005) 147. 126 H. Wang, C. Tablet, G. Grubert, A. Feldhoff, J. Caro,

A novel cobalt-free oxygen permeable membrane based on the perovskite-type based oxide

Ba0.5Sr0.5Zn0.2Fe0.8O3- Adv. Mater., 17 (2005) 1785. 127 J. Caro, K. Stephan,

Keramische Membranen für die Katalyse, Advanced Engineering Materials, DGMK Aktuell,7 (2005) 3. 128 T. Schiestel, M. Kilgus, S. Peter, K.J. Kaspary, H. Wang, J. Caro, Hollow fibre perovskite membranes for oxygen separation, J. Membr. Sci., 258 (2005) 1 129 S. Peter, J. Caro, H. Wang, T. Schiestel, Herstellung von Synthesegas unter Verwendung perowskitischer Membranen, Chemie Ingenieur Technik, 77 (2005) 1001. 130 H. Wang, C. Tablet, A. Feldhoff, J. Caro,

Investigation of phase structure, sintering, and permeability of perovskite-type

Ba0.5Sr0.5Co0.8Fe0.2O3- membranes, J. Membr. Sci. 262 (2005) 20.

131 H. Wang, W. Yang, C. Tablet, J. Caro,

Oxygen diffusion in oxide crystals – Tracing new routes to identify the rate limiting step of oxygen permeation through perovskite membranes, Diffusion Fundamentals (eds. J. Kärger, F. Grinberg, P. Heitjans), Leipziger Universitätsverlag, p. 246, ISBN 3-86583-073-0, 2005.

132 H. Wang, C. Tablet, W. Yang, J. Caro

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In situ temperature X-ray diffraction studies of mixed ionic and electronic conducting perovskite-type membranes,

Mater. Lett., 59 (2005) 3750. 133 H. Wang, S. Werth, T. Schiestel, J. Caro, Perovskite hollow-fiber membranes for the production of oxygen-enriched air, Angew. Chem. Int. Ed.44 (2005) 6906 und Angew. Chem. 117 (2005) 2. 134 J. Caro, M. Noack, P. Kölsch, Zeolite Membranes: From the laboratory scale to technical applications, Adsorption, 11 (2005) 215.

2006 135 X. Yang, D. Albrecht, J. Caro, Revision of Charnell’s procedure towards the synthesis of large and uniform crystals of

zeolites A and X, Micropoporous and Mesoporous Materials 90 (2006) 53 136 J. Caro, H. Wang, A. Kleinert, T. Schiestel, P. Kölsch, A. Wolf, R. Schomäcker, A. Schmidt, R.

Dittmeyer, D. Urbanczyk, S. Werth Partial oxidation and selective hydrogenation in catalytic membrane reactors, Proc. 9

th Intern. Conf. Inorg. Membranes, ICIM 9, Lillehammer, June 25- 29, 2006, ISBN

13:978-82-14-04026-5, p. 575. 137 J. Caro, H. Wang, T. Schiestel, M. Noack, R. Dittmeyer, S. Werth, Oxygen and hydrogen separation using perovskite hollow fiber and zeolite membranes in

comparison with organic membranes, Proc. 9

th Intern. Conf. Inorg. Membranes, ICIM 9, Lillehammer, June 25- 29, 2006, ISBN

13:978-82-14-04026-5, p. 268. 138 H. Wang, T. Schiestel, C. Tablet, J. Caro,

Ceramic hollow fiber membranes for oxygen production and conversion of methane, Proc. 9

th Intern. Conf. Inorg. Membranes, ICIM 9, Lillehammer, June 25- 29, 2006, ISBN

13:978-82-14-04026-5, p. 313.

139 M. Arnold, P. Kortunov, J. Kärger, J. Caro, First approaches to prepare supported metal-organic framework (MOF) membranes, Proc. 9

th Intern. Conf. Inorg. Membranes, ICIM 9, Lillehammer, June 25- 29, 2006, ISBN

13:978-82-14-04026-5, p. 461 140 J. Caro, Membranreaktoren für die katalytische Oxidation, Chemie Ingenieur Technik, 78 (2006) 899. 141 C. Hamel, A. Seidel-Morgenstern, T. Schiestel, S. Werth, C. Tablet, J. Caro, H. Wang,

Experimental and modelling study on dense perovskite hollow fiber membranes for production of O2-enriched air, AIChE J., 52 (2006) 3118.

142 J. Caro, A. Kleinert, H. Wang, C. Tablet, T. Schiestel, M. Kilgus, S. Peter,

Evaluation of hollow fiber perovskite membranes in catalytic membrane reactors for selective partial oxidation and in separators for oxygen production,

Catal. Today, 118 (2006) 128. 143 H. Wang, T. Schiestel, C. Tablet, J. Caro, Hollow fiber membrane reactors for oxidative activation of light hydrocarbons, Catal. Today, 118 (2006) 98. 144 A. Kleinert, T, Schiestel, H. Wang, J. Caro,

Novel Hollow fiber membrane reactor for partial oxidation of methane,

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Catal. Today, 118 (2006) 44.

145 J. Caro, T. Schiestel, S. Werth, H. Wang, M. Noack, Can inorganic membranes compete with organic ones? Perovskite hollow fibers for O2-separation and supported H2-selective zeolite membranes,

Desalination, 199 (2006) 365. 146 J. Caro, T. Schiestel, S. Werth, H. Wang, A. Kleinert, P. Kölsch,

Perovskite hollow fiber membranes in partial oxidation of methane to synthesis gas, Desalination. 199 (2006) 415.

147 M. Kilgus, H. Wang, S. Werth, J. Caro, T. Schiestel, Dense perovskite hollow fibre membranes, Desalination, 199 (2006) 355. 148 H. Wang, C. Tablet, T. Schiestel, S. Werth, J. Caro, Partial oxidation of methane to syngas in a perovskite hollow fiber membrane reactor, Catal. Commun., 7 (2006) 907. 149 H. Wang, P. Kölsch, T. Schiestel, C. Tablet, S. Werth, J. Caro, Production of high-purity oxygen by perovskite hollow fiber membranes swept with steam, J. Membr. Sci. 284 (2006) 5. 150 M. Noack, P. Kölsch, A. Dittmar, M. Stöhr, G. Georgi, R. Eckelt, J. Caro,

Effect of crystal intergrowth supporting substances (ISS) on the permeation properties of MFI membranes with enhanced Al-content,

Micropor. Mesopor. Mater. 97 (2006) 88. 151 A. Möller, X. Yang, J. Caro, R. Staudt, Adsorptionsmessungen von n-Alkanen am 5A-Zeolith, Chemie Ingenieur Technik 78 (2006) 1831 152 H.H. Wang, T. Schiestel, C. Tablet, M. Schroeder, J. Caro Mixed oxygen ion and electron conducting hollow fiber membranes for oxygen separation, Solid State Ionics 177 (2006) 2255. 153 D. Habel, J.B. Stelzer, E. Feike, C. Schröder, A. Hösch, A. Knop-Gericke, C. Hess, J. Caro, H.

Schubert, Phase development in the catalytic system V2O5/TiO2 under oxidizing conditions,

J. Europ. Ceram. Soc. 26 (2006) 3287.

2007 154 R. Marschall, I. Bannat, J. Caro, M. Wark, Proton conductivity of sulfonic acid functionalized mesoporous materials, Micropor. Mesopor. Mater. 99 (2007) 190. 155 G.T.P. Mabande, M. Noack, A. Avhale, P. Kölsch, G. Georgi, W. Schwieger, J. Caro, Permeation properties of bi-layered Al-ZSM-5/Silicalite-1 membranes, Micropor. Mesopor. Mater. 98 (2007) 55. 156 M. Arnold, P. Kortunov, D. Jones, Y. Nedellec, J. Kärger, J. Caro, Oriented Crystallization on Supports and Anisotropic Mass Transport of the Metal Organic

Framework Manganese Formate, Europ. J. Inorg. Chem., 2007, 60. 157 J. Caro, K.J. Caspary, C. Hamel, B.Hoting, P. Kölsch, B. Langanke, K. Nassauer, T. Schiestel,

A. Schmidt, R. Schomäcker, A. Seidel-Morgenstern, E. Tsotsas, I. Voigt, H.H. Wang, R. Warsitz, S. Werth, A. Wolf,

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Catalytic membrane reactors for partial oxidation using perovskite hollow fiber membranes and for partial hydrogenation using a catalytic membrane contactor,

Ind. Eng. Chem. Res. 46 (2007) 2286. 158 M. Krutyeva, S. Vasenkov, X. Yang, J. Caro, J. Kärger,

Surface barriers on nanoporous particles: A new method of their quantitation by PFG NMR, Micropor. Mesopor. Mater. 104 (2007) 89.

159 M. Noack, P. Kölsch, A. Dittmar, M. Stöhr, G. Georgi, M. Schneider, U. Dingerdissen, A.

Feldhoff, J. Caro, Proof of the ISS-concept for LTA and FAU membranes and their characterization by extended

gas permeation studies, Micropor. Mesopor. Mater. 102 (2007) 1. 160 P. V. Kortunov, M. Arnold, Y. Nedellec, D. Jones, J. Caro, J. Kärger, Guest arrangement in nanoporous host system follows one-dimensional lattice-gas model, J. Am. Chem. Soc., 129 (2007) 8041. 161 J. Caro, K.J. Caspary, C. Hamel, B. Hoting, P. Kölsch, B. langanke, K. Nassauer, M. Noack,

T. Schiestel, M. Schroeder, Y.C. Byun, A. Seidel-Morgenstern, E. Tsotsas, H. Wang, S. Werth,

Perowskit-Hohlfasermembranen für die katalytische Partialoxidation von Methan zu Synthesegas,

Chemie Ingenieur Technik, 79 (2007) 831. 162 J. Martynczuk, M. Arnold, J. Caro, A. Feldhoff,

How the (Ba0.5Sr0.5)(Fe0.8Zn0.2)O3- and Ba0.5Sr0.5)(Co0.8Zn0.2)O3-

perovskites form by the

EDTA/citratic acid complexing method, Adv. Mater., 19 (2007) 2134. 163 R. Scheffler, A. Huth, G. Hübner, M. Wark, J. Caro,. Präparation und Evaluation neuer Hybrid-Protonenleiter – Teil 1: Ionische Flüssigkeiten als

Modifikator in Nafion-Hybridmembranen, Chemie Ingenieur Technik 79 (2007) 1175. 164 S. Brandani, J. Caro, H. Jobic, J. Kärger, C. Krause, R. Staudt, Diffusion of n-alkanes in zeolites: the benefit of observation over different length scales, in: From Zeolites to Porous MOF Materials, Proc. 15th International Zeolite Conference,

Beijing, August 2007, by R. Xu, Z. Gao, J. Chen, W. Yan (eds.), in: Studies Surf. Sci. & Catal. 170, Elsevier, 2007, p. 981.

165 J. Caro, M. Noack, Zeolite Membranes – from Barrers vision to technical applications: new concepts in zeolite

membrane R&D, in: From Zeolites to Porous MOF Materials, Proc. 15th International Zeolite Conference,

Beijing, August 2007, by R. Xu, Z. Gao, J. Chen, W. Yan (eds.), in: Studies Surf. Sci. & Catal. 170, Elsevier, 2007, p. 96.

166 R. Marschall, M. Wark, M. Jeske, M. Wilhelm, G. Grathwohl, J. Caro, Functionalized mesoporous materials used as proton conductive additives for high

temperature PEM fuel cell membranes, in: From Zeolites to Porous MOF Materials, Proc. 15th International Zeolite Conference,

Beijing, August 2007, by R. Xu, Z. Gao, J. Chen, W. Yan (eds.), in: Studies Surf. Sci. & Catal. 170, Elsevier, 2007, p. 1540.

167 J. Caro, Catalytic Membrane Reactors, in: Catalise: Energia e Desenvolvimento Sustentavel, Sociedade Brasiliera de Catalise, ISSN 1980-9263, p. 62. 168 J. Caro,

14

Nobel Prize for our advisor, Gerhard Ertl, Germany, Chinese Journal of Catalysis, 28 (2007) 1 169 R. Scheffler, A. Huth, G. Hübner, R. Marschall, J. Caro, M. Wark, Präparation und Evaluation neuer Hybrid-Protonenleiter – Teil II: Anorganische Nanoteilchen

als Modifikator in Nafion-Hybridmembranen, Chemie Ingenieur Technik 79 (2007) 2035.

2008 170 A. Huth, R. Scheffler, G. Hübner, F. Seyfried, J. Caro, M. Wark, Präparation und Evaluation neuer Hybrid-Protonenleiter – Teil III: Phosphorsäureimprägnierte

Polybenzamidazol-Polymerelektrolytmembran für Brennstoffzellbetrieb Chemie Ingenieur Technik 80 (2008) 307. 171 R. Dittmeyer, J. Caro, Catalytic Membrane Reactors, in: G. Ertl, H. Knözinger, F. Schüth, J. Weitkamp (eds.),

Handbook of Heterogeneous Catalysis, second edition, volume 4, chapter 10.7, Wiley-VCH, 2008.

172 X. Yang, D. Albrecht, J. Caro, An unusual hydrothermal phase transformation of quartz-type gallium phosphate into zeotype

GaPO4-LTA and backwards, Micropor. Mesopor. Mater. 112 (2008) 637. 173 M. Wilhelm, M. Jeske, R. Marschall, W.L. Cavalcanti, P. Tölle, C. Köhler, D. Koch, T.

Frauenheim, G. Grathwohl, J. Caro, M. Wark, New proton conducting hybrid membranes for HAT-PEMFC systems based on polysiloxanes

and SO3H-functionalized Mesoporous Si-MCM-41 particles, J. Membr. Science 316 (2008) 164. 174 J. Caro, M. Noack (invited review), Zeolite membranes – recent developments and progress, Micropor. Mesopor. Mater. 115 (2008) 215. 175 S. Münzer, J. Caro, P. Behrens Preparation and caracterization of sodium-free nanocrystalline sodalite, Micropor. Mesopor. Mater. 110 (2008) 3. 176 J. Caro, M. Noack, Zeolite Membranes – Status and Prospective (invited chapter in Nanostructured Materials), Elsevier, 2009, in press. 177 S. Münzer, J. Caro, P. Behrens, Preparation and characterization of silica-sodalite membranes, Z. Anorg. Allg. Chemie 634 (2008) 2065. 178 H. Jiang, H.H. Wang, S. Werth, T. Schiestel, J. Caro, Simultaneous production of hydrogen and synthesis gas by combining water splitting with

partial oxidation of methane in a hollow-fiber membrane reactor, Angew. Chem. 47 (2008) 9341. 179 M. Wurz, T. Oekermann, P. Wagner, C. Ruffert, J. Caro, H.H. Gatzen, Investigation on the Embedding of Nanoparticles by Electroplating, Proc. 214

th Meeting of The Electrochemical Society, Honolulu, Hawei, Oct. 12-17, 2008.

180 J. Caro, Catalysis in micro-structured membrane reactors with nano-designed membranes, Chinese J. Catal. 29 (2008) 1169.

15

181 M.Y. Cai, H.X. Luo, Z. Li, A. Feldhoff, J. Caro, H.H. Wang,

Preparation and hydrogen permeation properties of Ba Ce0.95Nd0.o5O3- membranes, Chinese Chemic. Lett. 19 (2008) 1256. 182 H.H. Wang, C. Tablet, J. Caro, Oxygen production at low temperature using dense perovskite hollow fiber membranes, J. Membr. Sci. 322 (2008) 214.

2009 183 M. Noack, M. Schneider, A. Dittmar, G. Georgi, J. Caro, The change of the unit cell dimension of different zeolite types by heating and its influence on

supported membrane layers, Micropor. Mesopor. Mater. 117 (2009) 10. 184 E.V. Kondratenko, H.H. Wang, V.A. Kondratenko, J. Caro, Selective oxidation of CH4 and C2H6 over a mixed oxygen ion and electron conducting

perovskite – A TAP and membrane reactor study, J. Molecular Catalysis A: Chemical 297 (2009) 142. 185 H. Jiang, H.H. Wang, F. Liang, S. Werth, T. Schiestel, J. Caro, Direct decomposition of nitrous oxide to nitrogen by in situ oxygen removal with a perovskite

membrane, Angew. Chem. Int. Ed. 48 (2009) 2983. 186 H. Jiang, H.H. Wang, F. Liang, S. Werth, T. Schiestel, J. Caro, Zersetzung von Lachgas in die Elemente mit In-situ-Entfernung des Sauerstoffs durch eine

Perowskitmembran, Angew. Chem. 121 (2009) 3027. 187 D. Tzoulaki, L. Heinke, H. Lim. J. Li, D. Olson, J. Caro, R. Krishna, C. Chmelik Assessing surface permeabilities from transient guest profiles in nanoporous host materials, Angew. Chem. Int. Ed. 48 (2009) 3525. 188 K. Ulrich, D. Freude, P. Galvosas, C. Krause, J. Kärger, J. Caro, P. Poladli, H. Papp, Diffusion of aromatic guest molecules in zeolite NaX studied by pulsed field gradient NMR, Micropor. Mesopor. Mater. 120 (2009) 98. 189 H. Voß, A. Diefenbacher, G. Schuch, H. Richter, I. Voigt, M. Noack, J. Caro, Butene isomers separation on titania supported MFI membranes at conditions relevant for

practice, J. Membr. Sci. 329 (2009) 11-17. 190 S. Frisch, L.M. Rösken, J. Caro, M. Wark, Ion conductivity of nano-scaled Al-rich ZSM-5 synthesized in the pores of black carbon, Micropor. Mesopor. Mater. 120 (2009) 47. 191 J. Caro, D. Albrecht, M. Noack Why is it so extremely difficult to prepare shape-selective Al-rich zeolitemembranes like LTA

and FAU for gas separation? Separ. Purif. Technology 66 (2009) 143. 192 D. Tzoulaki, L. Heinke, H. Lim. J. Li, D. Olson, J. Caro, R. Krishna, C. Chmelik, Bestimmung der Oberflächenpermeabilitäten aus transienten Konzentrationsprofilen in

nanoporösen Materialien, Angew. Chemie, 121 (2009) 3577.

16

193 C. Chmelik, J. Kärger, M. Wiebcke, J. Caro, J.M. van Baten, R. Krishna, Adsorption and diffusion of alkanes in CuBTC crystals investigated using infra-red microscopy

and molecular simulations, Micropor. Mesopor. Mater. 117 (2009) 22. 194 A. Huang, J. Caro, Hydrothermal synthesis of uniform and well-shaped ITQ-29 crystals, Micropor. Mesopor. Mater. 124 (2009) 153. 195 J. Caro, Diffusion in porous functional materials: Zeolite gas separation membranes, proton exchange

membrane fuel cell, dye sensitized solar cells Micropor. Mesopor. Mater. 125 (2009) 79. 196 J. Caro, Energetische und stoffliche Nutzung von Erdgas, Uni Magazin der Leibniz Universität Hannover, Sonderheft Energie, 01/02 (2009) 34. 197 M. Cai, S. Liu, K. Efimov, J. Caro, A, Feldhoff, H.H. Wang,

Preparation and hydrogen permeation ofBaCe0.95Nd0.05O3- membranes J. Membr. Sci. 343 (2009) 90. 198 X. Chen, H. Liu, Y. Wie, J. Caro, H.H. Wang, A novel zincum-doped perovskite-type ceramic membrane for oxygen separation J. Alloys and Compounds 484 (2009) 386 199 A. Feldhoff, J. Caro, H. Jobic, J. Ollivier, C.B. Krause, P. Galvosas, J. Kärger, Intracrystalline Transport Resistances in Nanoporous Zeolite X, ChemPhysChem 10 (2009) 2359. 200 A. Huang, J. Caro, Fabrication of MTN-type zeolite by self-assembling of supramolecular compound, J. Cryst. Growth 311 (2009) 4570. 201 O. Czuprat, S. Werth, S. Schirrmeister, T. Schiestel, J. Caro, Oxidative Dehydrierung niederer Alkane in einem selektiven Membranreaktor mit gestufter

Sauerstoffzugabe und in situ-Wasserstoffoxidation, Chemie Ingenieur Technik 81 (2009) 1591. 202 O. Czuprat, S. Werth, S. Schirrmeister, T. Schiestel, J. Caro, Olefin Production by a Multistep Oxidative Dehydrogenation in a Perovskite Hollow-Fiber

Membrane Reactor, ChemCatChem 1 (2009) 401. 203 R. Scheffler, G. Hübner, F. Seyfried, K. Schröder, H. Steffen, M. Wark, J,. Caro, Plasmamodifizierung von Polybenzimidazol-Polymermembranen für die PEM-Brennstoffzelle, Chemie Ingenieur Technik 81 (2009) 1911. 204 H. Bux, F. Liang, Y. Li, J. Cravillon, M. Wiebcke, J. Caro,

Zeolitic Imidazolate Framework Membrane with Molecular Sieve Properties by Microwave Assisted Solvothermal Growth,

J. Amer. Chem. Soc. 131 (2009) 16000. 205 H.H. Wang, A. Feldhoff, J. Caro, T. Schiestel, S. Werth, Oxygen selective ceramic hollow fiber membranes for partial oxidation of methane, AIChE J. 55 (2009) 2657. 206 H. Jiang, L. Xing, O. Czuprat, H.H. Wang, S. Schirrmeister, T. Schiestel, J. Caro,

Highly effective NO decomposition by in situ removal of inhibitor oxygen using an oxygen transporting membrane,

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Chem. Commun. 2009, 6738

2010

207 A. Huang, J. Caro, Preparation of large and well-shaped LTA-type AlPO4 crystals by using crown ether Kryptofix

222 as structure directing agent, Micropor. Mesopor. Mater. 129 (2010) 90. 208 Y. Li, F. Liang, H. Bux, A. Feldhoff, W. Yang, J. Caro, Molecular Sieve Membrane: Supported Metal-Organic Framework with High Hydrogen

selectivity, Angew. Chem. Int. Ed. 49 (2010) 548. 209 H. Luo, B. Tian, Y. Wei, H.H. Wang, H. Jiang, J. Caro, Oxygen permeability and structural stability of a novel tantalum-doped perovskite

BaCo0.7Fe0.2Ta0.1O3-δ AIChE J., 56 (2010) 604. 210 H. Luo, Y. Wei, H. Jiang, W. Yuan, Y. Lv, J. Caro, H.H. Wang,

Performance of a ceramic membrane reactor with high oxygen flux Ta-containing perovskite for the partial oxidation of methane to syngas,

J. Membr. Sci. 350 (2010) 154. 211 K. Efimov, T. Halfer, A. Kuhn, P. Heitjans, J. Caro, A. Feldhoff,

Novel cobalt-free oxygen-permeable perovskite type membrane, Chem. of Mater. 22 (2010) 1540.

212 A. Huang, J. Caro, Novel zinc oxide twins with perfect mirror symmetry by solvothermal synthesis method, CrystEngCommun. 12 (2010) 685. 213 A. Huang, C. Weidenthaler, J. Caro, Facile and reproducible synthesis of ITQ-29 zeolite by using Kryptofix 222 as structure

directing agent Micropor. Mesopor. Mater. 130 (2010) 352. 214 C. Chmelik, H. Bux, J. Caro, L. Heinke, F. Hibbe, T. Titze, J. Kärger, Mass Transfer in a Nanoscale Material Enhanced by an Opposite Flux Phys. Rev. Lett. 104 (2010) 085902 215 A. Huang, J. Caro, Controlled growth of zinc oxide crystals with tunable shape, J. Cryst. Growth 312 (2010) 947. 216 C. Chmelik, F. Hibbe, D. Tzoulaki, L. Heinke, J. Caro, J. Li, J. Kärger, Exploring the Nature of Surface Barriers on MOF Zn(tbip) by Applying IR Microscopy in High

Temporal and Spatial Resolution, Micropor. Mesopor. Mater. 129 (2010) 340. 217 A. Huang, F. Liang, F. Steinbach, T.M. Gesing, J. Caro, Neutral and cation-free LTA-type aluminiumphosphate (AlPO4) molecular sieve membrane

with hydrogen selectivity, J. Amer. Chem. Soc. 132 (2010) 2140. 218 A. Huang, F. Liang, F. Steinbach, J. Caro, Preparation and separation properties of LTA membrane by using APTES as covalent linker, J. Membr. Sci. 350 (2010) 5.

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219 H. Richter, H. Voß, I. Voigt, A. Diefenbacher, G. Schuch, F. Steinbach, J. Caro, High-flux ZSM-5 membranes with an additional non-zeolite pore system by alcohol addition to

the synthesis batch and their evaluation in the 1-butene/i-butene separation, Sep. Purif. Techn. 72 (2010) 388. 220 J. Caro, Neue nanoporöse Molekularsiebmembranen: Zeolithe contra MOFs – Gewinner und Verlierer, Chemie Ingenieur Technik 82 (2010) 837. 221 A. Huang, H. Bux, F. Steinbach, J. Caro, Molecular Sieve Membrane with Hydrogen Permselectivity: ZIF-22 in LTA Topology Prepared

with 3-Aminopropyltriethoxysilane as Covalent Linker, Angew. Chem. Int. Ed. 49 (2010) 4958. 222 H. Jiang, F. Liang, O. Czuprat, K. Efimov, A. Feldhoff, S. Schirrmeister, T,. Schiestel, H.H.

Wang, J. Caro Hydrogen production by water dissociation in surface-modified BaCoFeZrO3 hollow fiber

membrane reactor with improved oxygen permeability, Chemistry – a European Journal 16 (2010) 7898. 223 Y. Li, F. Liang, H. Bux, W. Yang, J. Caro, Zeolitic imidazolate framework ZIF-7 based molecular sieve membrane for hydrogen

separation, J. Membr. Sci. 354 (2010) 48. 224 Y.-S. Li, H. Bux, A. Feldhoff, G.-L. Li, W.-S. Yang, J. Caro, Controllable Synthesis of metal-Organic Frameworks: From MOF Nanorods to oriented MOF

Membranes, Advanced Materials 22 (2010) 3322. 225 J. Caro, Basic Aspects of membrane Reactors. In: E. Drioli and L. Giorno, Comprehensive Membrane

Science and Engineering, vol. 3, pp 1-24, Oxford, Academic press. 226 H. Jiang, Z. Cao, S, Schirrmeister, T. Schiestel, J. Caro, A coupling strategy to produce hydrogen and ethylene in a membrane reactor, Angew. Chem. Int. Ed. 49 (2010) 5656. 227 A. Huang, J. Caro, Cationic Polymer Used to Capture Zeolite Precursor Particles for the Facile Synthesis of

Oriented Zeolite LTA Molecular Sieve Membrane, Chem. of Mater. 22 (2010) 4353. 228 O. Czuprat, J. Caro, V.A. Kondratenko, E.V. Kondratenko, Dehydrogenation of propane with selective hydrogen combustion: A mechanistic study by

transient analysis of products, Catal. Commun. 11 (2010) 1211. 229 O. Czuprat, S. Werth, J. Caro, T. Schiestel, Oxidative Dehydrogenation of propane in a Perovskite Membrane Reactor with Multi-Step

Oxygen Insertion, AIChE J. 56 (2010) 2390. 230 O. Czuprat, M. Arnold, S. Schirrmeister, T. Schiestel, J. Caro,

Influence of CO2 on the oxygen permeation performance of perovskite-type BaCoxFeyZrzO3-

hollow fiber membranes, J. Membr. Sci. 364 (2010) 132. 231 F. Liang, H. Jiang, T. Schiestel, J. Caro, High-purity oxygen production from air using perovskite hollow fiber membranes,

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Ind. Eng. Chem. Res. 49 (2010) 9377. 232 O. Czuprat, T. Schiestel, H. Voss, J. Caro, Oxidative coupling of methane in a BCFZ perovskite hollow fiber membrane reactor, Ind. Eng. Chem. Res. 49 (2010) 10230. 233 A. Huang, J. Caro, Steam-stable hydrophobic ITQ-29 molecular sieve membrane with H2 selectivity prepared by

secondary growth using Kryptofix 222 as SDA, Chem. Commun. 46 (2010) 7748. 234 H. Bux, C. Chmelik, J.M. van Baten, R. Krishna, J. Caro, Novel MOF-membrane for molecular sieving predicted by IR-diffusion studies and molecular

modeling, Advanced Materials 22 (2010) 4741. 235 A. Huang, J. Caro, Steam-stable zeolitic imidazolate framework ZIF-90 membrane with hydrogen selectivity

through covalent functionalization, J. Amer. Chem. Soc. 132 (2010) 15562. 236 H. Jiang, H.H. Wang, F. Liang, S. Werth, S. Schirrmeister, T. Schiestel, J. Caro, Improved water dissociation and nitrous oxide decomposition by in situ oxygen removal in

perovskite catalytic membrane reactor, Catal. Today 156 (2010) 187. 237 H. Liu, Y. Wei, J. Caro, H.H. Wang, Oxidative coupling of methane with high yield by using chlorinated perovskite BaSrFeCoO as

catalyst and N2O as oxidant, ChemCatChem 2 (2010) 1539-1542.

2011 238 Z. Adem, J. Caro, F. Furtado, P. Galvosas, C.B. Krause, J. Kärger, Tracing pore-space heterogeneities in X-type zeolites by diffusion studies, Langmuir 27 (2011) 416. 239 H. Luo, K. Efimov, H. Jiang, A. Feldhoff, H. Wang, J. Caro, CO2 stable and cobalt-free dual-phase membrane for oxygen separation, Angew. Chemie Int. Ed. 50 (2011) 759. 240 H. Luo, K. Efimov, H. Jiang, A. Feldhoff, H. Wang, J. Caro, CO2-stabile und cobaltfreie Zweiphasenmembran zur Sauerstoffabtrennung, Angew. Chemie 123 (2011) 785. 241 H. Bux, C. Chmelik, R. Krishna, J. Caro, Ethene/ethane separation by the MOF membrane ZIF-8: Molecular correlation of permeation,

adsorption, diffusion, J. Membr. Sci. 369 (2011) 284. 242 C. Chmelik, H. Bux, H. Voß, J. Caro, Adsorption and Diffusion – Basis for Molecular Understanding of Permeation through

Molecular Sieve membranes, Chemie Ingenieur Technik 83 (2011) 104. 243 A. Huang, J. Caro, Application of Microwave Heating on the Facile Synthesis of Porous Molecular Sieve

Membranes, InTech, (2011) 641.

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244 A. Huang, J. Caro, Highly oriented, neutral and cation-free AlPO LTA: from seed crystal monolayer to a molecular

sieve membrane, Chem. Commun. 47 (2011) 4201. 245 H. Bux, A. Feldhoff, J. Cravillon, M. Wiebcke, Y.S. Li, J. Caro, Oriented zeolitic imidazolate framework-8 membrane with sharp H2/C3H8 molecular sieve

separation, Chem. of Mater. 23 (2011) 2262. 246 A. Huang, J. Caro, Facile synthesis of LTA molecular sieve membranes on covalently functionalized supports by

using diisocyanates as molecular linkers, J. Mater. Chem. 21 (2011) 11424-11429. 247 J. Caro, Are MOF membranes better in gas separation than those made of zeolites? Current Opinions in Chemical Engineering 1 (2011) 77. 248 T. Binder, Z. Adem, C.B. Krause, M. Krutyeva, A. Huang, J. caro, J. Kärger, Surface permeability on zeolite NaCaA enhanced by layer deposition, Micropor. Mesopor. Mater. 146 (2011) 151. 249 F. Liang, H. Jiang, H. Luo, J. Caro, A. Feldhoff,

Phase stability and permeation behavior of dead-end Ba0.5Sr0.5Co0.8Fe0.2O3- tube membrane in high-purity oxygen production,

Chem. of Mater. 23 (2011) 4765. 250 Y. Selk, M. Minnermann, T. Oekermann, M. Wark, J. Caro, Solid-state dye-sensitized ZnO solar cells prepared by low-temperature methods, J. Appl. Electrochem. 41 (2011) 445.

2012 251 J. Cravillon, C.A. Schröder, H. Bux, A. Rothkirch, J. Caro, M. Wiebcke, Formate modulated solvothermal synthesis of ZIF-8 investigated using time-resolved in situ X-

ray diffraction and scanning electron microscopy, CrystEngComm 14 (2012) 492. 252 A. Huang, N. Wang, J. Caro, Seeding-free synthesis of dense zeolite FAU membranes on 3-aminopropyltriethoxysiolane-

functionalized alumina supports, J. Membr. Science 389 (2012) 272. 253 A. Huang, N. Wang, J. Caro, Stepwise synthesis of sandwich-structured compoite zeolite membranes with enhanced

separation selectivity, Chem. Commun. 48 (2012) 3542. 254 A. Betard; H. Bux, S. Henke, D. Zacher, J. Caro, R. Fischer, Fabrication of a CO2-selective membrane by stepwise liquid-phase deposition of an alkylether

functionalized pillared-layered metal-organic framework [Cu2L2P]n on a macroporous support, Micropor. Mesopor. Mater. 150 (2012) 76. 255 F. Hibbe, J. Caro, C. Chmelik, A. Huang, T. Kirchner, D. Ruthven, R. Valiullin, J. Kärger,

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Monitoring Molecular Mass Transfer in Cation-free Nanoporous Host Crystals of type AlPO-LTA,

J. Amer. Chem. Soc. 134 (2012) 7725. 256 F. Liang, H. Jiang, H. Luo, R. Kriegel, J. Caro,

High-purity oxygen production by a dead-end Ba0.5Sr0.5Co0.8Fe0.3O3- tube membrane, Catal. Today 193 (2012) 95-100. 257 Z. Cao, H. Jiang, H. Luo, S. Baumann, W.A. Meulenberg, H. Voß, J. Caro Simultaneous overcome of the equilibrium limitations in BSCF oxygen-permeable membrane

reactor: Water splitting and methane coupling, Catal. Today 193 (2012) 2-7. 258 L. Diestel, H. Bux, D. Wachsmuth, J. Caro, Pervaporation studies of n-hexane, benzene, mesitylen and their mixtures on zeolitic

imidazolate framework ZIF-8 membranes, Micropor. Mesopor. Mater. 164 (2012) 288 259 A. Huang, N. Wang, J. Caro, Synthesis of multi-layer zeolite LTA membranes with enhanced gas separation performance

by using 3-aminopropyltriethoxysilane, Micropor. Mesopor. Mater. 164 (2012) 294. 260 A. Huang. N. Wang, C. Kong, J. Caro, Organosilica-functionalized zeolitic imidazolate framework ZIF-90 membrane with high gas-

separation performance, Angew. Chem. Int. Ed. 51 (2012) 10551. 261 H. Luo, H. Jiang, T. Klande, F. Liang, Z. Cao, H.H. Wang, J. Caro, Rapid glycine-nitrate combustion synthesis of the CO2-stable dual phase membrane 40

Mn1.5Co1.5O4--60Ce0.9Pr0.1O2- for CO2 capture via an oxy-fuel process, J. Membr. Sci. 423/424 (2012) 450. 262 A. Huang, Y. Chen, N. Wang, Z. Hu, J. Jiang, J. Caro, A highly permeable and selective zeolitic imidazolate framework ZIF-95 membrane for H2/CO

separation Chem. Commun. 48 (2012) 10981. 263 H. Luo, H.H. Jiang, T. Klande, Z. Cao, F. Liang, H.H. Wang, J. Caro

Novel cobalt-free, noble metal-free oxygen-permeable 40Pr0.6Sr0.4O3- -60Ce0.9Pr0.1O2- dual-phase membrane,

Chem. of Mater. 24 (2012) 2148.

2013 264 Y. Wei, W. Yang, J. Caro, H.H. Wang, Dense ceramic oxygen permeable membranes and catalytic membrane reactors, Chem.

Engineering J. 220 (2013) 185-203.

265 F. Liang, K. Partovi, H. Jiang, H. Luo, J. Caro

B-site La-doped BaFe0.95-xLaxZr0.05O3- perovskite-type membranes for oxygen separation, J. Mater. Chemistry A 1 (2013) 746. 266 A. Huang, Q. Liu, N. Wang, X. Tong, B. Huang, M. Wang, J. caro,

Covalent synthesis of dense zeolite LTA membranes on various 3-chloropropyltrimethoxysilane functionalized supports,

J. Membr. Sci. 437 (2013) 57-64. 267 U. Böhme, B. Barth, C. Paula, A. Kuhnt, W. Schwieger, A. Mundstock, J. Caro, M. Hartmann,

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Ethene/ethane and propene/propane separation via the olefin and paraffin selective metal-organic framework adsorbents CPO-27 and ZIF-8,

Langmuir 29 (2013) 8592-8600. 268 X. Liu, Y. Li, Y. Ban, Y. Peng, H. Jin, H. Bux, L. Xu, J. Caro, W. Yang Improvement of hydrothermal stability of zeolitic imidazolate frameworks, Chem. Commun. 49 (2013) 9140-9142. 269 A. Mundstock, U. Böhme, B. Barth, M. Hartmann, J. Caro, Propylen/Propan-Trennung im Festbettreaktor und durch Membranpermeation, Chemie Ingenieur Technik 85 (2013) 1694. 270 U. Böhme, C. Paula, V.R.R. Marthala, J. Caro, M. Hartmann, Ungewöhnliche Adsorptions- und Trenneigenschaften des Molekularsiebs ZIF-8, Chemie Ingenieur Technik 85 (213) 1707. 271 Q. Liu, N. Wang, J. Caro. A. Huang,

Bio-inspired polydopamine: A versatile and powerful platform for covalent synthesis of molecular sieve membranes,

JACS 135 (2013) 17679-17682 272 Z. Cao, H. Jiang, H. Luo, S. Baumann, W.A. Meulenberg, J. Assmann, L. Mleczko, Y. Liu, J.

Caro, Natural gas to fuels and chemicals: improved methane aromatization in the oxygen-permeable membrane reactor,

Angew. Chem. Int. Ed. 52 (2013) 13794-13797. 273 T. Chokbunpiam, R. Chanajaree, O. Saengsawang, S. Reimanm, C-. Chmelik, S. Fritsche, J.

Caro, T. Remsungen, S. Hannongbua, The importance of lattice flexibility for the migration of ethane in ZIF-8: Molecular dynamics simulations,

Micropor. Mesopor. Mater. 174 (2013) 126-134.

2014 274 C. Chmelik, A. Mundstock, P.D.C. Diestel, J. Caro Idiosyncrasies of Co2(dhtp): In situ-annealing by methanol Micropor. Mesopor. Mater. 183 (2014) 117-123.

275 G. Bellussi, J. Caro, J. Kärger, F. Schüth, M. Stöcker, J. Weitkamp, Hellmut Karge (1931-2013), Micropor. Mesopor. Mater. 184 (2014) 70-71. 276 F. Liang, H. Luo, K. Partovi, O. Ravkina, Z. Cao, Y. Liu, J. Caro, A novel CO2-stable dual phase membrane with high oxygen permeability, Chem. Commun. 50 (2014) 2451-2454. 277 L. Diestel, X.L. Liu, Y.S. Li, W.S. Yang, J. Caro,

Comparative permeation studies on three supported membranes: Pure ZIF-8, pure polymethylphenylsiloxane, and mixed matrix membrane, Micropor. Mesopor. Mater. 189 (2014) 210-215.

278 Y. Liu, N. Wang, L. Diestel, F. Steinbach, J. Caro MOF membrane synthesis in the confined space of a vertically aligned LDH network, Chem. Commun. 50 (2014) 4225-4227. 279 Y. Liu, N. Wang, Z.W. Cao, J. Caro, Molecular sieving through interlayer galleries, J. Mater. Chem. A 2 (2014) 1235-1238.

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280 B. Huang, Q. Liu, J. Caro, A. Huang, Iso-Butanol dehydration by pervaporation using zeolite LTA membranes prepared by APTES-modified alumina tubes,

J. Membr. Sci. 455 (2014) 200-206. 281 T. Chokbunpiam, R. Chanajaree, T. Remsungnen, O. Saengsawang, S. Fritzsche, C.

Chmelik, J. Caro, W. Janke, S. Hannonbua, N2 in ZIF-8: Sorbate induced structural changes and self-diffusion, Micropor. Mesopor. Mater. 187 (2014) 1-5. 282 A. Huang, Y. Chen, Q. Liu, N. Wang, J. Jiang, J. Caro,

Synthesis of highly hydrophobic and permselective metal-organoc framework Zn(BDC)(TED)0.5 membranes for H2/CO2 separation,

J. Membr. Sci. 454 (23014) 126-132. 283 H. Luo, T. Klande, Z. Cao, F. Liang, H.H. Wang, J. Caro, A CO2-stable reduction-tolerant Nd-containing dual phase membrane for oxyfuel CO2 capture, J. Mater. Chem. A. 2 (2014) 7780-7787. 284 A. Huang, Q. Liu, N. Wang, J. Caro,

Organosilica functionalizedzeolitic imidazolate framework ZIF-90 membrane for CO2/CH4 separation,

Micropor. Mesopor. Mater. 192 (2014) 18-22. 285 N. Wang, Y. Liu, A. Huang, J. Caro,

Supported SOD membrane with steam selectivity by a two-step repeated hydrothermal synthesis,

Micropor. Mesopor. Mater. 192 (2014) 8-13. 286 Z.W. Cao, H.Q. Jiang, H.X. Luo, S. Baumann, W.A. Meulenberg, H. Voss, J. Caro,

An efficient oxygen activation route for improved ammonia oxidation through an oxygen-permeable catalytic membrane,

ChemCatChem 6 (2014) 1190-1194. 287 D.I. Kolokolow, L. Diestel, J. Caro, D. Freude, A.G. Stepanov

Rotational and translational motion of benzene in ZIF-8 srtudied by 2H NMR: Estimation of

microscopic self-diffusivity and its comparison with macroscopic measurements, J. Phys. Chem. C 118 (2014) 12873-12879. 288 K. Partovi, F. Liang, O. Ravkina, J. Caro

High-flux oxygen-transporting membrane Pr0.6Sr0.4Co0.5Fe0.5O3-: CO2 stability and microstructure

Appl. Materials & Interfaces 6 (2014) 10274-10282. 289 A. Huang, Q. Liu, N. Wang, Y. Zhu, J. Caro

Bicontinuous zeolitic imidazolate framework FIF-8@GO membrane with enhanced hydrogen selectivity J. Amer. Chem. Soc. 136 (2014) 14686-14689.

290 A. Schulz, F. Steinbach, J. Caro Pressed graphite crystals as gas separation membrane for steam reforming of ethanol, J. Membr. Sci. 469 (2014) 284-291. 291 J. Caro Catalytic Membrane Reactors – Lab Curiosity or Key Enabling Technology? Chemie Ingenieur Technik 86 (2014) 1901-1905. 292 Yi Liu, N. Wang, J.H. Pan, F. Steinbach, J. Caro, In situ synthesis of MOF membranes on ZnAl-CO3 LDH buffer layer-modified substrates, J. Amer. Chem. Soc. 136 (2014) 14353-14356.

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293 Y. Liu, N. Wang, J. Caro,

In situ formation of LDH membranes of different microstructures with molecular sieve gas selectivity, J. Mater. Chem. A. 2 (2014) 5716-5723.

294 A. Huang, Q. Liu, N. Wang, J. Caro,

Highly hydrogen permselective ZIF-8 membranes supported on polydopamine functionalized macroporous stainless-steel- nets, J. Mater. Chem. A. 2 (2014) 8246-8251.

2015 295 N. Wang, Y. Liu, A. Huang, J. Caro,

Hydrophilic SOD and LTA membranes for membrane-supported methanol, dimethylether and dimethylcarbonate synthesis. Micropor. Mesopor. Mater. 207 (2015) 33-38.

296 N. Wang, Y. Liu, Z. Qiao, L. Diestel, J. Zhou, A. Huang, J. Caro,

Polydopamine-based synthesis of zeolite imidazolate framework ZIF-100 membrane with high H2/CO2 selectivity. J. of Materials Chemistry A 3 (2015) 4722-4728.

297 L. Diestel, N. Wang, A. Schulz, F. Steinbach, J. Caro,

Matrimid-based mixed matrix membranes: Interpretation and correlation of experimental findings for zeolitic imidazolate frameworks as fillers in H2/CO2 separation,

Ind. Eng. Chem. Res. 54 (2015) 1103-1112. 298 N. Wang, A. Mundstock, Y. Liu, A. Huang, J. Caro,

Amine-modified Mg-MOF-74/CPO-27-Mg membrane with enhanced H2/CO2 separation. Chemi. Engin. Sci. 124 (2015) 27-36.

299 Yi Liu, T. Yu, R. Cai, Y. Li, W. Yang, J. Caro, One-pot synthesis of NiAl-CO3 LDH anti-corrosion coatings from CO2-saturated precursors, Rsc: Advances; 5 (2015) 29552-29557. 300 Yi Liu, J.H. Pan, N. Wang, F. Steinbach, X. Liu, J. Caro,

Remarkably enhanced gas separation by partial self-conversion of a laminated membrane to metal-organic frameworks,

Angew. Chemie Int. Ed. 54 (2015) 3028-3032. 301 S. Friebe, B. Geppert, J. Caro,

Inverted Fuel cell: Room-temperature hydrogen separation from an exhaust gas by using a commercial short-circuited fuel cell without applying any electrical voltage,

Angew. Chem. Int. Ed. 54 (2015) 7790-7794. 302 S. Friebe, B. Geppert, J. Caro,

Umgekehrte Brennstoffzelle: Wasserstoffabtrennung aus einem Abgas mithilfe einer kurzgeschlossenen kommerziellen PEM-Brennstoffzelle ohne Anlegen einer äußeren Spannung bei Raumtemperatur,

Angew. Chem. 127 (2015) 7900-7904 303 Y. Wei, J. Xue, W. fang, Y. Chen, H.H. Wang, J. Caro

Enhanced stability of Zr-doped Ba(CeTb)O3- -Ni cermet membrane for hydrogen separation, Chem. Commun. 51 (2015) 11619-11621. 304 L. Diestel, N. Wang, B. Schwiedland, F. Steinbach, U. Giese, J. Caro, MOF based MMMs with enhanced selectivity due to hindered linker distortion, J. Membr. Sci., 492 (2015) 181-186.

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305 B. Seoane, J. Coronas, I. Gascon, M.E. Benavides, O. Karvan, J. Caro, F. Kapteijn, J. Gascon,

Metal-organic framework based mixed matrix membranes: a solution for highly efficient CO2 capture?

Chem. Soc. Rev. 44 (2015) 2421-2454. 306 N. Rangnekar, N. Mittal, B. Elyassi, J. Caro, M. Tsapatsis, Zeolite membranes – a review and comparison with MOFs, Chem. Soc. Rev. 44 (2015) 7128-7154. 307 A. Mundstock, N. Wang, S. Friebe, J. Caro,

Propane/propene permeation through Na-X membranes: The interplay of separation performance and pre-synthetic support functionalization,

Microporous Mesoporous Mater. 215 (2015) 20-28.

2016 308 S. Friebe, N. Wang, L. Diestel, Y. Liu, A. Schulz, A. Mundstock, J. Caro, Deuterium/hydrogen permeation through different membranes: ZIF, LDH, zeolite, Micropor. Mesopor. Mater. 216 (2015) 127-132. 309 Y. Zhu, K.M. Gupta, Q. Liu, J. Jiang, J. Caro, A. Huang,

Synthesis and seawater desalination of molecular sieving zeolitic imidazolate framework membranes,

Desalination, 385 (2016) 75-82.

310 T. Chokbunpiam, S. Fritzsche, C. Chmelik, J. Caro, W. Janke, S. Hannongbua,

Gate opening for carbon dioxide in ZIF-8 by molecular dynamics – Confirmed, but at high CO2 pressure,

Chem. Phys. Lett. 648 (2016) 178-181. 311 A. Knebel, S. Friebe, N.C. Bigall, M. Benzaqui, C. Serre, J. Caro Comparative Study of MIL-96(Al) as Continuous MOF-Layer and Mixed-Matrix-Membrane, ACS Applied Materials and Interfaces, 8 (2016) 7536-7544

312 J. Xue, Y. Chen, Y. Wie, A. Feldhoff, H.H. Wang, J. Caro,

Gas to liquids: Natural gas conversion to aromatic fuels and chemicals in a hydrogen-permeable ceramic hollow fiber membrane reactor,

ACS Catalysis, 6 (2016) 2448-2451. 313 K. Xu, C. Yuan, J. Caro, A. Huang, Silver-exchanged zeolite LTA molecular sieve membrane with enhanced hydrogen selectivity, J. Membr. Sci. 511 (2016)1-8. 314 A. Wollbrink, K. Volgmann, J. Koch, K. Kanthasamy, C. Tegenkamp, Y. Li, H. Richter, S.

Kämnitz, F. Steinbach, A. Feldhoff, J. Caro, Amorphous, turbostratic and crystalline carbon membranes with hydrogen selectivity, Carbon 106 (2016) 93-105. 315 J. Sanchez-Lainez, B. Zornoza, S. Friebe, J. Caro, S. Cao, A. Sabetghadam, B. Seoane, J.

Gascon, F. Kapteijn, C. le Guillouzer, G. Clet, M. Daturi, C. Tellez, J. Coronas, Influence of ZIF-8 particle size in the performance of polybenzimidazole mixed matrix membranes for pre-combustion CO2 capture and its validation through interlaboratory test,

J. Membr. Sci. 515 (2016) 45-53. 316 J. Caro,

Hierarchy in inorganic membranes, Chem. Soc. Rev., 45 (2016) 3468-3478. DOI: 10.1039/C5CS00597C.

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317 S. Friebe, A. Mundstock, D. Unruh, F. Renz, J. Caro, NH2-MIL-125 as membrane for carbon dioxide sequestration: Thin supported MOF layers contra Mixed-Matrix-Membranes

J. Membr. Sci. 516 (2016) 185-193. 318 S. Cheng, Y. Wang, L. Zhuang, J. Xue, Y. Wie, A. Feldhoff, J. Caro, H. Wang

A dual-phase ceramic membrane with extremely high H2 permeation flux prepared by autoseparation of a ceramic precursor,

Angew. Chemie Int. Ed. 55 (2016) 10895-10898. 319 S. Cheng, Y. Wang, L. Zhuang, J. Xue, Y. Wie, A. Feldhoff, J. Caro, H. Wang

Eine zweiphasige Keramikmembran mit extrem hohem Wasserstoff-Fluss durch Entmischung einer keramischen Vorstufe,

Angew. Chem. 128 (2016) 11055-11058. 320 C. Zhou, N. Wang, Y. Qian, X. Liu, J. Caro, A. Huang, Efficient synthesis of dimethyl ether from methanol in a bifunctional zeolite membrane reactor, Angew. Chem. Int. Ed. 55 (2016) 12678-12682. 321 C. Zhou, N. Wang, Y. Qian, X. Liu, J. Caro, A. Huang,

Effiziente Synthese von Dimethylether aus Methanol in einem Membranreaktor mit bifunktioneller Membran,

Angew. Chemie 128 (2016) 12869-12873. 322 A. Wolf, L. Diestel, F. Lübkemann, T. Kodanek, T. Mohamed, J. Caro, D. Dorfs,

Plasmonic semiconductor nanoparticles in a metal-organic framework structure and their in situ cation exchange,

Chem. Mater. 28 (2016) 7511-7518. 323 S. Friebe, L. Diestel, A. Knebel, A. Wollbrink, J. Caro MOF-based mixed-matrix membranes in gas separation – Mystery and reality, Chem. Ing. Tech. 88 (2016) 1788-1797. 324 Z. Wang, A. Knebel, S. Grosejan, D. Wagner, S. Bräse, C. Wöll, J. Caro, L. Heinke, Tunable molecular separation by nanoporous membranes, Nature Commun. 7:13872, 2016. 325 H. Jin, A. Wollbrink, R. Yao, Y. Li, J. Caro, W. Yang, A novel CAU-10-H MOF membrane for hydrogen separation under hydrothermal conditions, J. Membr. Sci. 513 (2016) 40-46.

2017 326 A. Wollbrink, C.H. Rüscher, K. Volgmann, J. Koch, A. Breuksch, C. tegenkamp, J. Caro

Improved hydrogen selectivity of surface modiefied graphite (SMG) membranes: Permeation experiments and characterization by micro-Raman spectroscopy and XPS,

J. Membr. Sci. 528 (2017) 316-325. 327 L. Ding, Y.Y. Wei, Y. Wang, H.B. Chen, J. Caro, H.H. Wang, A two-dimensional Lamellar Membrane: MXene Nanosheet Stacks, Angew. Chem. Int. Ed. 56 (2017) 1825-1829. 328 A. Knebel, L. Sundermann, A. Mohmeyer, I. Strauß, S. Friebe, P. Behrens, J. Caro,

Azobenzene guest molecules as light-switchable CO2 valves in an ultrathin UiO-67 membrane,

Chemistry of Materials, 29 (2017) 3111-3117. 329 S. Friebe, B. Geppert, F. Steinbach, J. Caro,

Metal-organic framework UiO-66 layer: A highly oriented membrane with good selectivity and hydrogen permeance,

ACS Appl. Mater. Interfaces 9 (2017) 12878 – 12885.

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330 K. Lange, M. Schulz-Ruhtenberg, J. Caro,

Platinum electrodes for oxygen reduction catalysis designed by ultrashort pulse laser structuring,

ChemElectroChem 4 (2017) 570-576. 331 K. Müller, A. Knebel, F. Zhao, D. Bleger, J. Caro, L. Heinke, Switching thin films of azobenzene-containing metal-organic frameworks with visible light, Chem. Eur. J. 23 (2017) 5434-5438 332 S. Friebe, A. Mundstock, D. Schneider, J. Caro

An untrodden path: Versatile fabrication of self-supporting polymer-stabilized percolation membranes (PSPMs) for gas separation,

Chem. Eur. J. 23 (2017) 6522-6526 333 H. Richter, H. Voss, N. Kaltenborn, S. Kämnitz, A. Wollbrink, A. Feldhoff, J. Caro, S. Roitsch,

I. Voigt, High-flux carbon molecular sieve membrane for gas separation, Angew. Chem. Int. Ed. 56 (2017) 7760-7763. 334 Y. Wang, L. Li, Y. Wei, J. Xue, H. Chen, L. Ding, J. Caro, H.H. Wang,

Water transport with ultralow friction through partially exfoliated g-C3N4 nanosheet membranes with self-supporting spacers,

Angew. Chem. Int. Ed. 56 (2017) 8974-8980. 335 H.Q. Jiang, J. Caro, Interfacial Au/MoC catalyst for low-temperature water – gas shift reaction, Chem. 3 (2017) 209-210. 336 A. Knebel, B. Geppert, K. Volgmann, D.I. Kolokov, A.G. Stepanov, J. Twiefel, P. Heitjans, D.

Volkmer, J. Caro, Defibrillation of soft porous metal-organic frameworks with electric fields, Science, 358 (2017) 347-351. 337 W. Liang, Z. Cao, G. He, J. Caro, H. Jiang,

Oxygen Transport Membrane for Thermochemical Conversion of Water and Carbon Dioxide into Synthesis Gas,

ACS Sustainable Chem. Eng. 5 (2017) 8657-8662.

2018 338 A. Huang, L. Wan, J. Caro, Microwave-assisted synthesis of well-shaped UiO-66-NH2 with high adsorption capacity, Mater: Res. Bull. 98 (2018) 308-313.

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b) BOOK CHAPTERS

1 J. Caro, Fluid Flow, in: F. Schüth, K.S.W. Sing, J. Weitkamp (eds.), Handbook of Porous Solids, Wiley-

VCH, pp 352-370, 2002. 2 M. Noack, J. Caro, Zeolite Membranes, in: F. Schüth, K.S.W. Sing, J. Weitkamp (eds.), Handbook of Porous

Solids, Wiley-VCH, pp 2433-2506, 2002. 3 R. Dittmeyer, J. Caro, Catalytic Membrane Reactors, in: G. Ertl, H. Knözinger, F. Schüth, J. Weitkamp (eds.),

Handbook of Heterogeneous Catalysis, Wiley-VCH, pp 2198- 2247, 2008. 4 J. Caro, M. Noack, Zeolite Membranes – Status and Prospective, in: S. Ernst (ed.) Advances in Nanoporous

Materials, Elsevier, pp 1 – 96, 2009. 5 J. Caro, Basic Aspects of Membrane Reactors, in: E. Drioli, L. Giorno (eds.) Comprehensive

Membrane Science and Technology, Elsevier, pp 1-24, 2010. 6. A. Huang, J. Caro, Application of Microwave Heating on the Facile synthesis of Porous Molecular Sieve

Membranes, in: S. Grundas (ed.) Advances in Induction and Microwave Heating of Mineral and Organic Materials, InTech, pp 641-672, 2011.

7 J. Caro, Diffusional Transport in Functional Materials, in: N. Kanellopoulos (ed.), Nanoporous

Materials- Advanced Techniques for Characterization, Modeling, and Processing, CRC Press (Taylor & Francis), pp 423 – 448, 2011.

8 F. Liang, J. Caro, Perovskite Membranes for High-temperature Oxygen Separation, in: E. Drioli, G. Barbieri

(eds.), Membrane Engineering for the Treatment of Gases, RSC Publishing, pp 192-222, 2011.

9 Y.Y. Wei, J. Caro, Ceramic Membranes with Ion Conductivity, in: Basile (ed), Membrane Reactor Engineering,

Wiley-VCH, in press. 10 J. Caro,

Supported zeolite and MOF molecular sieve membranes - Preparation, characterization,

application, in: L. Kustov (ed), Zeolites and Zeolite-like Materials, Elsevier, ISBN

9780444635068, 2016.

29

c) PATENTE 1 J. Caro, C. Förste, W. Heink, J. Kärger und H. Pfeifer, Verfahren zur adsorptiven Charakterisierung von Zeolithen, DD 253 191 A1. 2 J. Caro, M. Bülow, J. Kärger, H. Pfeifer und B. Zibrowius, Verfahren zur adsorptiven Charakterisierung zeolithischer Adsorbenzien und Katalysatoren, DD 253 190 A1. 3 J. Caro, R. Entner, W. Ermischer, W. Heink, J. Kärger und H. Pfeifer, Verfahren zur Charakterisierung von Koksabscheidungen auf mikroporösen Adsorbenzien, DD 251 502 A1. 4 J. Caro, H. Fürtig, W. Heink, J. Kärger, W. Höse, H. Pfeifer, W. Roscher und R. Seidel, Verfahren zur Charakterisierung der hydrothermalen Stabili- tät von Molekularsieben, DD 251 503 A1. 5 J. Caro, M. Bülow, W. Heink, J. Kärger und H. Pfeifer, Verfahren zur Charakterisierung der Anordnung azider Zentren in Zeolithkatalysatoren, DD 251 504 A1. 6 J. Caro, M. Bülow, W. Heink, J. Kärger, H. Spindler und J. Völter, Verfahren zur Charakterisierung von Koksabscheidungen auf mikroporösen Katalysatoren, DD 251 505 A1. 7 J. Caro, W. Heink, J. Kärger, H. Pfeifer und H. Spindler, Verfahren zur Charakterisierung von Modifizierungen in mikroporösen Katalysatoren, DD 251 506 A1. 8 J. Caro, M. Bülow, J. Kärger, H. Pfeifer und J. Völter, Verfahren zur Modifizierung mikroporöser Katalysatoren durch gezielte Koksabscheidung, DD 251 507 A1. 9 J. Caro, M. Bülow, D. Freude, M. Hunger, J. Kärger, H. Pfeifer und H. Spindler, Verfahren zur Herstellung eines Zeolithkatalysators vom Pentasiltyp für formselektive katalytische Umsetzungen, DD 261 746 A1. 10 J. Caro, M. Bülow, D. Freude, M. Hunger, J. Kärger, H. Pfeifer und H. Spindler, Verfahren zur Herstellung von aluminiumfreien Pentasilzeolithe als Kationenaustauscher, DD 261 747 A1. 11 M. Bülow, J. Caro, B. Fahlke, J. Kärger und J. Völter, Verfahren zur Herstellung eines hochsilikatischen Pentasilzeolithen, DD 271 060 A1. 12 K. Becker, J. Caro, E. Hodek, J. Kärger, H. Pfeifer und H. Spindler, Verfahren zur Charakterisierung sekundärer Porensysteme in zeolithischen Adsorbentien und Katalysatoren, DD 278 069 A1. 13 J. Caro, M. Bülow, G. Finger, J. Kornatowski, W. Hübner und B. Zibrowius, Verfahren zur Herstellung von Membranen mit ausgerichteten Molekularsiebkristallen als transportaktiver Komponente Anmeldung durch J. Caro am 15.3.1991, offengelegt am 17.9.1992 unter DE4109038A1 14 J. Caro, G. Finger, J. Richer-Mendau und B. Zibrowius, Verfahren zur Orientierung von Molekülen durch Ausrichten von Molekularsiebkristallen, Anmeldung durch J. Caro am 15.3.1991, offengelegt am 17.9.1992 unter DE4109037A1

30

15 P. Kölsch, J. Caro, M. Noack, D. Venzke, P. Toussaint, H. Nickel

Verfahren zur Herstellung von zeolithischen Hochtemperatur-Molekularsieb-Membranen mit

trennenden und reaktiven Eigenschaften

Anmeldung durch ACA am 8.9.1993, offengelegt am 23.3.1995 unter DE 4.330.949A12

16 P. Kölsch, M. Noack, J. Caro, P. Toussaint,

Poröser, fester anorganischer Körper mit modifizierter Oberfläche,

Anmeldung durch ACA am 29.5.1997, offengelegt am 3.12.1998 unter DE19722902A1

17 M. Noack, P. Kölsch, J. Caro, P. Toussaint, U. Bentrup, Poröser, fester, anorganischer

Poröser, fester, anorganischer Körper mit modifizierter Oberfläche für molekulare

Stofftrennungen und -wandlungen, Anmeldung durch ACA am 29.5.1997, offengelegt am

3.12.1998 unter DE19722901A1

18 J. Caro, M. Noack, P. Kölsch

Verfahren zum selektiven Aufheizen graphitischer Kohlenstoffspezies,

Anmeldung durch ACA am 24.9.1998, offengelegt am 30.3.2000 unter DE19845 821A1

19 M. Noack, U. Illgen, P. Kölsch, J. Caro, A. Kühnel, M. Duda, G. Hörpel, C. Hying,

Feinstporiger Verbundstoff, Verfahren zu dessen Herstellung und die Verwendung des

Verbundwerkstoffes, und Extremely fine-pored composite Material, method for producing said

composite material and use of the same,

Anmeldung durch CREAVIS GmbH am 9.11.2000, offengelegt am 23.5.2002 unter DE

10055610A1 und AU 000200220665A

20 M. Noack, P. Kölsch, J. Caro, K. Weh,

Gasdurchlässige Membran und deren Verwendung zur Steuerung des Gasdurchganges,

Anmeldung durch ACA am 26.10.1999, offengelegt am 17.5.2001 unter DE199 52 725C1

21 P. Kölsch, M. Noack, R. Schäfer, J. Caro, H. Knauer, B. Holz.

Osmometer zur Molekulargewichtsbestimmung mit anorganischen nano-/mikroporösen

Membranen,

Anmeldung durch Knauer GmbH am 24.12.199, offengelegt am 5.7.2001unter DE199 63

729A1

22 M. Noack, P. Kölsch, C. Weh, R. Schäfer, J. Caro

Verfahren zur Herstellung von Molekularsiebmembranen auf porösen Trägern,

Anmeldung durch ACA am 26.5.2000, offengelegt am 6.12.2001 unter DE10027 685A1 und

offengelegt am 10.11.2005 unter DE10027 685B4

23 M. Noack, P. Kölsch, R. Schäfer, J. Caro

Keramischer Körper mit ultrafeinen Poren, Verfahren zu seiner Herstellung und Verwendung

Anmeldung durch ACA am 27.4.2000, offengelegt am 8.11.2001 unter DE 10021580A1und

EP 151.97.412

24 M. Noack, P. Kölsch, R. Schäfer, J. Caro

31

Oxidkeramischer Körper mit ultrafeinen Poren, Verfahren zu seiner Herstellung und

Verwendung,

Anmeldung durch ACA am 267.4.2000, offengelegt am 9.12.2002 unter DE 10021580C2, EP

1151974 (26.04.2001) 25 M. Noack, P. Kölsch, C. Weh, R. Schäfer, J. Caro Verfahren zur Herstellung von Molekularsiebmembranen auf porösen Trägern, DE 10027685 (Anmeldung vom 23.5.2001), EP 1157735 (23.05.2001) 26 M. Noack, P. Kölsch, R. Schäfer, K. Weh, P. Toussaint, J. Caro,

Molekularsiebmembran auf Basis poröser Träger und Kristallisationsverfahren, Anmeldung durch ACA am 19.7.2001, offengelegt am 6.2.2003 unter DE 10136621A1 und DE 10136621C2 sowie EP 1277511 (18.07.2002)

27 A. Köckritz, P. Kölsch, J. Caro, B. Lücke, Verfahren zur Abtrennung von flüssigen Produkten aus einem Produktgemisch und Festkörpermembran dafür, Anmeldung durch ACA am 17.5.2002, offengelegt am 4.12.2003 unter DE 102 23 103A1 und DE 102 23 103B4

28 P. Kölsch, M. Noack, R. Schäfer, J. Caro, Verfahren zur Herstellung von Propenoxid aus Propen und Membranreaktor,

Anmeldung durch ACA am 16.1.2003, offengelegt am 29.7.2004 unter DE10302095A1 29 S. Bitterlich, H. Voß, G. Schuch, A. Diefenbacher, M. Noack, R. Schäfer, I. Voigt, H. Richter,

J. Caro, Verfahren zur Herstellung von Membranen,

Anmeldung durch BASF am 13.01.2004, offengelegt am 06.10.2005 unter DE 102004001975A1 sowie EP-Anmeldung

30 S. Bitterlich, H. Voß, G. Schuch, A. Diefenbacher, M. Noack, R. Schäfer, I. Voigt, H. Richter,

J. Caro, Komposit-Membran,

Anmeldung durch BASF am 13.01.2004, offengelegt am 04.08.2005 unter DE 102004001974.A1 sowie WO 2005/068057 (05.01.2005)

31 H. Wang, G. Grubert, C. Tablet, J. Caro,

Sauerstoff transportierende Oxidkeramiken mit kontrolliertem Sauerstoff-Fluss und Verfahren zur Herstellung der Oxidkeramiken Anmeldung durch Uni Hannover am 6.4.2005, offengelegt am 27.4.2006 unter EP 1 630 148

32 N. Ignatev, U. Welz-Biermann, G. Hübner, A. Huth, M. Wark, J. Caro,

Feuchteunabhängige protonenleitende Elektrolytmembran mit erweitertem Betriebstemperaturbereich auf Basis ionischer Flüssigkeiten, VW-Erf.-Nr. 2005/0177, Anmeldung durch Büro Hengelhaupt Schneider für die VW AG.

33 …J. Caro et al., Komposit-Membran zur Gastrennung und zur Pervaporation, Anmeldung durch BASF (2005-1203-WO) 34 A. Dieffenbacher, H. Voss, G. Schuch, M. Noack, I. Voigt, H. Richter, J. Caro,

Process for producing a composite membrane (Anmeldung durch BASF am 21.12.2007)

35 J. Caro, H. Wang, M. Noack, P. Kölsch, F. Kapteijn, N. Kanellopoulos, J. Nolan, Composite membrane, EP 06112764.3, durch Anwaltsbüro Taruttis

36 R.U. Dietrich, Dr.-Ing. A. Lindermeir, J. Caro, Hochtemperatur-Brennstoffzellensystem und Verfahren zum Erzeugen von Strom und Wärme mit Hilfe eines Hochtemperatur-Brennstoffzellensystems, angemeldet am 20.2.2008 durch Gramm, Lins & Partner, unter DE 2781-020-1.

32

Von den genannten Patenten wurden die unter den Positionen 4, 6 und 12 aufgeführten Patente

"Verfahren zur Charakterisierung der hydrothermalen Stabilität von Molekularsieben", "Verfahren zur

Charakterisierung von Koksabscheidungen auf mikroporösen Katalysatoren" und "Verfahren zur

Charakterisierung sekundärer Porensysteme in zeolithischen Adsorbentien und Katalysatoren" gemäß

Paragraph 18 des PatG erteilt und befanden sich wie folgt in Nutzung: No.4: 1988 bis 1990 in der

Chemie-AG Bitterfeld, No.6 1989 und No.10 1988-1989 in der Leuna AG.