Molekulare Mechanismen der Tumor-Nekrose-Faktor- Rezeptor ...
Mechanismen der Catastrophic Phase Inversion in ......Mechanismen der Catastrophic Phase Inversion...
Transcript of Mechanismen der Catastrophic Phase Inversion in ......Mechanismen der Catastrophic Phase Inversion...
-
Mechanismen der
Catastrophic Phase Inversion
in Emulsionen aus Polydimethylsiloxanen und Wasser
Inaugural-Dissertation
zur Erlangung des Doktorgrades
der Mathematisch-Naturwissenschaftlichen Fakultät
der Heinrich-Heine-Universität Düsseldorf
vorgelegt von
Alice Schneider aus Solingen
Düsseldorf, September 2011
-
aus dem Institut für Physikalische Chemie
der Heinrich-Heine Universität Düsseldorf
Gedruckt mit der Genehmigung der
Mathematisch-Naturwissenschaftlichen Fakultät der
Heinrich-Heine-Universität Düsseldorf
Referent: Prof. Dr. Claus A. M. Seidel
Korreferent: Prof. Dr. Wolfgang von Rybinski
Tag der mündlichen Prüfung: 23.11.2011
-
•
•
•
•
-
X
-
•
•
•
•
•
•
-
=
=
=
-
Schwanzgruppe
(hydrophob)
-
•
•
•
-
=
+
+
+
=
-
a b
c d
-
·
·
=( )
-
•
•
•
•
-
= =( )
( )
-
=
-
= +
-
=
-
•
•
•
-
= =+
+
-
=
-
X
-
•
•
•
•
•
•
•
•
•
-
a
b
-
=
-
=
-
·
-
=
-
=
=
=
•= =
-
•=
=•
=
-
X
-
· ·
-
· ·
· · ·
[ ] [ ] [ ] [ ] [ ] [ ]
· ·
· ·
-
[μ ]
[ ]
[μ]
[ ]
[μ]
[ ]
-
[ ]
[ ]
[]
[ ]
-
[ ]
[]
[]
-
[]
[ ]
-
=
-
[ ]
[]
[ ]
[]
[ ]
[]
[ ]
[]
-
•
•
•
•
•
-
[ ]
-
[ ]
-
[ ]
[ ]
[]
[ ][
][ ]
[]
[ ]
[]
[ ]
[]
[ ]
-
[]
[]
-
[μ]
[ ]
-
=+
-
[μ]
[ ]
[μ]
[ ]
[μ]
[ ]
-
·
[]
[ ]
[ ]
[]
[ ]
-
[ ]
-
[ ]
-
[ ]
-
[ ]
[ ]
-
[ ]
-
[ ]
[ ]
-
[ ]
-
[ ]
-
[ ]
-
·
-
1 2
3 a 3 b
4 a 4 b
5 a 5 b
6
-
[ ]
-
[]
-
[]
[]
[]
[]
[]
[]
-
[μ]
[ ]
-
[ ]
[ ]
-
[ ]
-
±
-
a
b c
-
a b
-
[μ]
[ ]
-
μ
-
•
•
•
•
•
-
[ ] [ ] [ ]
[ ] [ ]
[ ]
[ ] [ ]
[]
-
3
O W
25 14 12 6 8 5 x
25
14 12
6
8
5
3 EIP
1,0
0,5
5 10 15 HLB
-
=
=
-
•
•
[ ] [ ] [ ] [ ]
-
[ ]
[ ]
+
-
[ ]
[]
[]
-
=
a) s < 1 b) s = 1 c) s > 1
-
= + ( )
=
=
-
[ ]
-
a) C11EO3
c) C11EO8
b) C11EO5
d) C11EO11
-
= +
-
=+
=
= +
+
-
μ
-
a) T/O
b) W/O
d) O/W/O
e) O/W
c) Fl.krist./O
-
[ ]
-
[ ]
[ ]
-
[ ]
-
[ ]
[μ]
[ ]
-
•
•
•
[μ]
[ ]
-
X
-
X
-
μ
[]
[μ ]
[μ ]
[]
-
[μ ]
[]
[μ ]
[]
[μ ]
[]
-
[μ ]
[]
[μ ]
[]
[μ ]
[]
-
[μ ]
[]
[μ ]
[]
-
[μ ]
[]
[μ ]
[]
[μ ]
[]
-
[μ ]
[]
[μ ]
[]
-
X
-
X
-
X
-
X