Rotationsspektrum (MW) von HCl

Click here to load reader

  • date post

    29-Jan-2022
  • Category

    Documents

  • view

    0
  • download

    0

Embed Size (px)

Transcript of Rotationsspektrum (MW) von HCl

Folie 101
82
Der nicht-starre Rotator (2-atomig)
starr / nicht-starr
(genauer: 4138.3 cm-1)
Stark-Effekt
= −1/3
= −1/10
= +1/5
= −6/126
Rotation im symmetrischen Kreisel
JM Hollas, Modern Spectroscopy
JM Hollas, Modern Spectroscopy
~8 10−6
2-atomig, starr
)1(2~ 1 JBv JJ
Symm. Kreisel, starr
Banwell & McCash, Molekülspektroskopie
Haken&Wolf
Unraveling the internal dynamics of the benzene dimer: a combined theoretical and microwave spectroscopy study Melanie Schnell *ab, Undine Erlekam c, P. R. Bunker cd, Gert von Helden c, Jens-Uwe Grabow e, Gerard Meijer c and Ad van der Avoird *cf PhysChemChemPhys 2013, 15, 10207-10223
http://scitation.aip.org/content/aip/journal/jcp/45/6/10.1063/1.1727868
C2v
C2h