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OSHA/EPA Occupational Chemical Database

Chemical IdentificationChemical Name: GASOLINE

CAS #: 8006-61-9 UN No: 1203 Formula:

Synonyms: Motor fuel; Motor spirits; Natural gasoline; Petrol [Note: A complex mixtur

hydrocarbons (paraffins; cycloparaffins & aromatics).]

Physical Properties

Physical Description: Clear liquid with a characteristic odor.

BP: 102F MW: 72 (approx)LEL:

1.4%NFPA Fire Rating: 3

FRZ/MLT: FRZ: NA VP: 38-300 mmHgUEL:

7.6%NFPA Health Rating: 1

FP: -45F VD: NA NFPA Reactivity Rating: 0

Sp. GR: (60F):0.72-0.76

IP: NA NFPA Sp. Inst.: NA

Exposure Limits

OSHA NIOSH Related Information

PEL-TWA ppm: NA REL-TWA ppm: NA AIHA Emergency Resp

Guidelines - ERPG-1/E

3:

NA

PEL-TWA mg/m3: NA REL-TWA mg/m3: NA

PEL-STEL ppm: NA REL-STEL ppm: NA

PEL-STEL mg/m3: NA REL-STEL mg/m3: NAPEL-C ppm: NA REL-C ppm: NA

PEL-C mg/m3: NA REL-C mg/m3: NA Carcinogen Classificati

NIOSH-Ca, TLV-A3Skin Notation: No Skin Notation: No

Notes: NANotes: CARCINOGEN (Ca);

LOQ 15 ppm

IDLH ppm: NA

IDLH mg/m3: NA

IDLH Notes: Ca

NIOSH Pocket Guide to Chemical Hazards (Current through Jun

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Gasoline CAS: 8006-

Formula: NA RTECS: LX

Synonyms & Trade Names: Motor fuel, Motor spirits, Natural gasoline,

Petrol

DOT ID &

128

Exposure Limits

NIOSH REL: Ca See Appendix A OSHA PEL : none

IDLH: Ca [N.D.] Conversion: 1 ppm = 4.5 mg/m3 (ap

Physical Description

Clear liquid with a characteristic odor.

MW: 110 (approx) BP: 102F FRZ: ? Sol: Insolu

VP: 38-300 mmHg IP: ? RGasD: NA Sp.Gr(60F)

Fl.P: -45F UEL: 7.6% LEL: 1.4% MEC: NA

Class IB Flammable Liquid (See flammable and combustible liquid classes)

Incompatibilities & ReactivitiesStrong oxidizers such as peroxides, nitric acid & perchlorates

Measurement Methods

OSHA PV2028

Personal Protection & Sanitation First Aid

Skin: Prevent skin contact

Eyes: Prevent eye contact

Wash skin: When contam

Remove: When wet (flamm)

Change: N.R.

Provide: Eyewash, Quick drench

Eye: Irr immed

Skin: Soap flush immed

Breath: Resp support

Swallow: Medical attention immed

(See procedures)

NIOSH Respirator Recommendations

NIOSH : SCBAF:PD,PP/SAF:PD,PP:ASCBA Escape: GMFOV/SCBAE

(See symbols and codes)

Exposure Routes

Inh Abs Ing Con

Symptoms

Irrit eyes, skin, muc memb; derm; head, ftg, blurred vision, dizz, slurred speech, conf,

chemical pneu (aspir liquid); possible liver, kidney damage; [carc]

(See abbreviations)

Target Organs

Eyes, skin, resp sys, CNS, liver, kidneys

(See abbreviations)

DOT Emergency Response Guidebook (ERG 2004)

Guide Number: 128

128 Flammable Liquids (Non-Polar/Water-Immiscible)POTENTIAL HAZARDS

FIRE OR EXPLOSION

* HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.

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* Vapors may form explosive mixtures with air.

* Vapors may travel to source of ignition and flash back.

* Most vapors are heavier than air. They will spread along ground and

collect in low or confined areas (sewers, basements, tanks).

* Vapor explosion hazard indoors, outdoors or in sewers.

* Those substances designated with a P may polymerize explosively when

heated or involved in a fire.* Runoff to sewer may create fire or explosion hazard.

* Containers may explode when heated.

* Many liquids are lighter than water.

* Substance may be transported hot.

HEALTH

* Inhalation or contact with material may irritate or burn skin and eyes.

* Fire may produce irritating, corrosive and/or toxic gases.

* Vapors may cause dizziness or suffocation.

* Runoff from fire control or dilution water may cause pollution.

PUBLIC SAFETY

* CALL Emergency Response Telephone Number on Shipping Paper first. IfShipping Paper not available or no answer, refer to appropriate

telephone number listed on the inside back cover.

* Isolate spill or leak area immediately for at least 25 to 50 meters

(80 to 160 feet) in all directions.

* Keep unauthorized personnel away.

* Stay upwind.

* Keep out of low areas.

* Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

* Wear positive pressure self-contained breathing apparatus (SCBA).

* Structural firefighters' protective clothing will only provide limitedprotection.

EVACUATION

Large Spill

* Consider initial downwind evacuation for at least 300 meters

(1000 feet).

Fire

* If tank, rail car or tank truck is involved in a fire, ISOLATE for

800 meters (1/2 mile) in all directions; also, consider initial

evacuation for 800 meters (1/2 mile) in all directions.

EMERGENCY RESPONSE

FIRE

CAUTION: All these products have a very low flash point: Use of water spray

when fighting fire may be inefficient.

Small Fires

* Dry chemical, CO2, water spray or regular foam.

Large Fires

* Water spray, fog or regular foam.

* Use water spray or fog; do not use straight streams.

* Move containers from fire area if you can do it without risk.

Fire involving Tanks or Car/Trailer Loads

* Fight fire from maximum distance or use unmanned hose holders or

monitor nozzles.

* Cool containers with flooding quantities of water until well afterfire is out.

* Withdraw immediately in case of rising sound from venting safety

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devices or discoloration of tank.

* ALWAYS stay away from tanks engulfed in fire.

* For massive fire, use unmanned hose holders or monitor nozzles; if this

is impossible, withdraw from area and let fire burn.

SPILL OR LEAK

* ELIMINATE all ignition sources (no smoking, flares, sparks or flames

in immediate area).* All equipment used when handling the product must be grounded.

* Do not touch or walk through spilled material.

* Stop leak if you can do it without risk.

* Prevent entry into waterways, sewers, basements or confined areas.

* A vapor suppressing foam may be used to reduce vapors.

* Absorb or cover with dry earth, sand or other non-combustible material

and transfer to containers.

* Use clean non-sparking tools to collect absorbed material.

Large Spills

* Dike far ahead of liquid spill for later disposal.

* Water spray may reduce vapor; but may not prevent ignition in closed

spaces.

FIRST AID

* Move victim to fresh air.

* Call 911 or emergency medical service.

* Apply artificial respiration if victim is not breathing.

* Administer oxygen if breathing is difficult.

* Remove and isolate contaminated clothing and shoes.

* In case of contact with substance, immediately flush skin or eyes with

running water for at least 20 minutes.

* Wash skin with soap and water.

* Keep victim warm and quiet.

* Ensure that medical personnel are aware of the material(s) involved,and take precautions to protect themselves.

Additional Emergency Response Information (CAMEO Data)

Non-fire Spill Response: Keep sparks, flames, and other sources of ignition away. Ke

of water sources and sewers. Build dikes to contain flow as necessary. Attempt to stop l

undue personnel hazard. Use water spray to knock-down vapors. ( AAR, 1999)

Firefighting: Do not extinguish fire unless flow can be stopped. Use water in flooding q

fog. Solid streams of water may spread fire. Cool all affected containers with flooding q

water. Apply water from as far a distance as possible. Use foam, dry chemical, or carbo( AAR, 1999)

Reactivity: This compound is incompatible with the following:Strong oxidizers such as

acid & perchlorates (NIOSH, 1997)

First Aid: Eye: If this chemical contacts the eyes, immediately wash the eyes with larg

water, occasionally lifting the lower and upper lids. Get medical attention immediately.

should not be worn when working with this chemical. Skin: If this chemical contacts the

immediately flush the contaminated skin with soap and water. If this chemical penetrat

immediately remove the clothing and flush the skin with water. If irritation persists afte

medical attention. Breathing: If a person breathes large amounts of this chemical, mov

person to fresh air at once. If breathing has stopped, perform mouth-to-mouth resuscit

affected person warm and at rest. Get medical attention as soon as possible. Swallow: I

has been swallowed, get medical attention immediately. (NIOSH, 1997)

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