enantioselective catalysts in Michael reactionsSupporting information for Synthesis of...
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Supporting information for Synthesis of α-D-galactose-based azacrown ethers and their application as enantioselective catalysts in Michael reactions Zsolt Rapi, a Alajos Grün, a György Keglevich, a András Stirling, b Péter Bakó a,* a Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, PO Box 91, 1521 Budapest, Hungary, E-mail: [email protected] b Institute of Organic Chemistry, Research Centre for Natural Sciences, Hungarian Academy of Sciences, Budapest, Hungary Content 1 H and 13 C NMR spectrum of crown ether 4a 1 H and 13 C NMR spectrum of crown ether 4b HPLC spectra of selected chiral compounds Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2016
Transcript of enantioselective catalysts in Michael reactionsSupporting information for Synthesis of...
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Supporting information for
Synthesis of α-D-galactose-based azacrown ethers and their application as
enantioselective catalysts in Michael reactions
Zsolt Rapi,a Alajos Grün,
a György Keglevich,
a András Stirling,
b Péter Bakó
a,*
aDepartment of Organic Chemistry and Technology, Budapest University of Technology and Economics, PO
Box 91, 1521 Budapest, Hungary, E-mail: [email protected]
bInstitute of Organic Chemistry, Research Centre for Natural Sciences, Hungarian Academy of Sciences,
Budapest, Hungary
Content
1H and
13C NMR spectrum of crown ether 4a
1H and
13C NMR spectrum of crown ether 4b
HPLC spectra of selected chiral compounds
Electronic Supplementary Material (ESI) for New Journal of Chemistry.This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2016
mailto:[email protected]
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File name: BA-13-117002.CH1
Info:
AS-H hexane:2-propanol 9:1, 2 ml/min, 256 nm, 20 °C
Peak RT Area [μV.sec] Quantity
#1 4.575 1679709.500 0.000
Total Area of Peak = 1679709.500 [μV.sec]
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File name: BJ-15-58001.CH1
Info:
AD-H hexane:2-propanol 9:1, 2 ml/min, 256 nm, 20 °C
Peak RT Area [μV.sec] Quantity
#1 28.400 1645929.889 0.000
Total Area of Peak = 1645929.889 [μV.sec]
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File name: BJ-15-63001.CH1
Info:
AD-H hexane:2-propanol 9:1, 2 ml/min, 256 nm, 20 °C
Peak RT Area [μV.sec] Quantity
#1 16.058 2389597.883 0.000
#2 18.225 1488846.777 0.000
Total Area of Peak = 3878444.661 [μV.sec]
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File name: RZ-16-129001.CH1
Info:
AS-H hexane:2-propanol 8:2, 2 ml/min, 256 nm, 20 °C
Peak RT Area [μV.sec] Quantity
#1 7.800 2730263.671 0.000
Total Area of Peak = 2730263.671 [μV.sec]
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File name: RZ-16-119001.CH1
Info:
AD-H hexane:2-propanol 8:2, 2 ml/min, 256 nm, 20 °C
Peak RT Area [μV.sec] Quantity
#1 6.050 3585430.500 0.000
Total Area of Peak = 3585430.500 [μV.sec]
-
File name: BA-13-115001.CH1
Info:
AS-H hexane:2-propanol 9:1, 2 ml/min, 256 nm, 20 °C
Peak RT Area [μV.sec] Quantity
#1 5.733 74908.500 0.000
#2 8.708 599563.659 0.000
Total Area of Peak = 674472.159 [μV.sec]
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File name: Y-15-08001.CH1
Info:
AD-H hexane:2-propanol 8:2, 2 ml/min, 256 nm, 20 °C
Peak RT Area [μV.sec] Quantity
#1 3.483 1103579.000 0.000
#2 5.017 12026.706 0.000
Total Area of Peak = 1115605.706 [μV.sec]
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File name: RZ-16-115001.CH1
Info:
AD-H hexane:2-propanol 8:2, 2 ml/min, 256 nm, 20 °C
Peak RT Area [μV.sec] Quantity
#1 6.783 1180350.311 0.000
#2 19.292 8475878.000 0.000
Total Area of Peak = 9656228.311 [μV.sec]
