Struktur Atom 2014

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    Partikel ini berada dalam gerakan yang

    konstan, tetapi dapat bergabung

    membentuk suatu kombinasi yang mantap.

    Potongan paling kecil dari materi yang tidakbisa dibagi lagi disebut atom

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    Melibatkan kejadian kimia

    Berdasarkan asumsinya pada data

    kuantitatif

    Ditunjang oleh 2 percobaan ( 2 hukum alam)

    Hukum kekekalan massa

    Hukum perbandingan tetap

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    Using the Law of Conservat ion of Mass

    You heat 2.53 g of metallic mercury in air, which produces 2.73 g of a red-orange residue. Assume that the chemical change is the reaction of the

    metal with oxygen in air.

    Mercury + oxygen red-orange residue

    What is the mass of oxygen that reacts?

    When you strongly heat the red-orange residue, it

    decomposes to give back mercury and releases the

    oxygen, which you collect.

    What is the mass of oxygen you collect?

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    Jumlah massa zat-zat yang ada sebelumreaksi sama dengan jumlah massa zat-zat yang ada setelah reaksi

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    Percobaan ke

    :

    Sebelum

    pemanasan (g

    Mg)

    Setelah

    pemanasan (g

    MgO)

    Perbandingan

    Mg/MgO

    1 0.62 1.02 0.61

    2 0.48 0.79 0.60

    3 0.36 0.60 0.60

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    Setiap senyawa tersusun dari unsur-unsur

    tertentu dengan perbandingan tetap

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    Tiap-tiap unsur kimia tersusun dari partikel-partikel kecilyang tidak bisa dihancurkan dan dibagi yang disebut atom.Selama perubahan kimia, atom tidak bisa diciptakan dandimusnahkan.

    Semua atom dari suatu unsur mempunyai massa dan sifatyang sama, tetapi atom-atom dari suatu unsur berbedadengan atom-atom dari unsur lain, baik masa maupun sifat-sifatnya.

    Dalam senyawa kimia, atom-atom dari unsur yang berlainanmelakukan ikatan dengan perbandingan numerik yangsama, exs. 1 atom A dengan 2 atom B (AB2)

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    8 X2Y16 X 8 Y+

    2.1

    Law of _________________________________

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    Adanya awan yang bermuatan positif dengansejumlah elektron yang terpusat yang cukup untukmenetralkan.

    However, if there are electrons (-), there must be a +component.

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    2.2

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    1. atoms positive charge is concentrated in the nucleus

    2. proton (p) has opposite (+) charge of electron

    3. mass of p is 1840 x mass of e-(1.67 x 10-24g)

    particle velocity ~ 1.4 x 107m/s

    (~5% speed of light)

    (1908 Nobel Prize in Chemistry)

    2.2

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    Sebagian besar masa dan semua muatan positif terpusat

    pada daerah yang sempit yang disebut inti atom nuklei)

    Sebagian besar atom merupakan ruang kosong

    Besarnya muatan pada inti berbeda untuk atom yang

    berbeda, kira-kira setengah dari nilai numerik dari bobot

    atom suatu unsur

    Di luar inti suatu atom harus terdapat elektron yang

    jumlahnya sama dengan satuan muatan inti

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    atomic radius ~ 100 pm = 1 x 10-10m

    nuclear radius ~ 5 x 10-3pm = 5 x 10-15m

    Rutherfords Model of

    the Atom

    2.2

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    H atoms - 1 p; He atoms - 2 p

    mass He/mass H should = 2

    measured mass He/mass H = 4

    +9

    Be1

    n +12

    C + energy

    neutron (n) is neutral (charge = 0)

    n mass ~ p mass = 1.67 x 10-24g

    2.2

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    ParticleMass

    (g)Charge

    (Coulombs)Charge(units)

    Electron (e-) 9.1 x 10

    -28 -1.6 x 10

    -19 -1

    Proton (p) 1.67 x 10-24

    +1.6 x 10-19

    +1

    Neutron (n) 1.67 x 10-24

    0 0

    mass p = mass n = 1840 x mass e-

    2.2

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    ParticleMass

    (g)Charge

    (Coulombs)Charge(units)

    Electron (e-) 9.1 x 10

    -28 -1.6 x 10

    -19 -1

    Proton (p) 1.67 x 10-24

    +1.6 x 10-19

    +1

    Neutron (n) 1.67 x 10-24

    0 0

    mass p = mass n = 1840 x mass e-

    2.2

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    The Atom

    Nucleus Electron

    Shell or Orbit

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    The Atom Hydrogen

    Proton Electron

    Hydrogen has one proton, one electron and NO neutrons

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    The Atom Helium

    ElectronProton

    Neutron

    Helium has two electrons, two protons and two neutrons

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    The Atom Helium

    ElectronProton

    Neutron

    Helium has two electrons, two protons and two neutrons

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    The Atom Lithium

    Protons

    Neutrons

    Electrons

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    The Atom Beryllium

    Protons

    Neutrons

    Electrons

    Beryllium has four electrons, four protons and five neutrons.

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    The Atom Boron

    Protons

    Neutrons

    Electrons

    Boron has five electrons, five protons and six neutrons.

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    The Atom Carbon

    Protons

    Neutrons

    Electrons

    Carbon has six electrons, six protons and six neutrons.

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    The Atom Nitrogen

    Protons

    Neutrons

    Electrons

    Nitrogen has seven electrons, seven protons and seven neutrons.

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    The Atom Oxygen

    Protons

    Neutrons

    Electrons

    Oxygen has eight electrons, eight protons and eight neutrons.

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    The Atom Fluorine

    Protons

    Neutrons

    Electrons

    Fluorine has nine electrons, nine protons and ten neutrons.

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    The Atom Neon

    Protons

    Neutrons

    Electrons

    Neon has ten electrons, ten protons and ten neutrons.

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    The Atom Sodium

    Protons

    Neutrons

    Electrons

    Sodium has eleven electrons, eleven protons and twelve neutrons.

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    _______________(Z) = number of protons in nucleus

    ______________(A) = number of protons + number of neutrons

    = atomic number (Z) + number of neutrons

    ___________are atoms of the same element (X) with different

    numbers of neutrons in the nucleus

    XA

    Z

    H11 H (D)

    21 H (T)

    31

    U23592 U23892

    Mass Number

    Atomic NumberElement Symbol

    2.3

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    2.3

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    Menentukan perbandingan muatan terhadap massa (e/m)dari ion positif yang dihasilkan dalam sebuah tabung sinar

    kanal

    Dalam gas neon biasa kira-kira 91% dari atom-atom

    mempunyai massa normal dan 9% dari atom-atom

    tersebut 22/20 lebih berat dari normal.

    KESIMPULAN

    Atom-atom dari unsur yang sama dapat sedikit berbeda

    dalam massanya

    SOTOP

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    Symbols

    Find each of these:a) number of protons

    b) number of neutrons

    c) number of electrons

    d) Atomic number

    e) Mass Number

    symbol Cl

    name Chlorine

    atomic number 17

    mass number 35.453

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    An____is formed when an atom, or group of atoms, has a net positive or

    negative charge (why?).

    _____ion with a positive charge

    If a neutral atom_______one or more electrons

    it becomes a cation.

    _____ion with a negative charge

    If a neutral atom_______one or more electrons

    it becomes an anion.

    Na 11 protons11 electrons Na+ 11 protons

    10 electrons

    Cl 17 protons

    17 electronsCl-

    17 protons

    18 electrons

    2.5

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    PeriodG

    roup

    Alkali

    Metal

    Noble

    Gas

    Ha

    logen

    AlkaliEarth

    Metal

    2.4

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    Naturally occurring carbon consists of three isotopes, 12C, 13C,and 14C. State the number of protons, neutrons, and electrons

    in each of these carbon atoms.12C 13C 14C

    6 6 6

    #p _______ _______ _______

    #n_______ _______ _______

    #e _______ _______ _______

    LecturePLUS Timberlake 38

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    12C 13C 14C

    6 6 6

    #p __6___ _ 6___ ___6___

    #n __6___ _ _7___ ___8___

    #e __6___ _ 6___ ___6___

    LecturePLUS Timberlake 39

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    Listed on the periodic table

    Gives the mass of average atom of each

    element compared to 12C

    Average atom based on all the isotopesand their abundance %

    LecturePLUS Timberlake 40

    Na22.99

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    Percent(%) abundance of isotopes

    Mass of each isotope of that element

    Weighted average =mass isotope1(%) + mass isotope2(%) +

    100 100

    LecturePLUS Timberlake 41

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    Isotopes Mass of Isotope Abundance24Mg = 24.0 amu 78.70%

    25Mg = 25.0 amu 10.13%

    26Mg = 26.0 amu 11.17%

    Atomic mass (average mass) Mg = 24.3 amu

    LecturePLUS Timberlake 42

    Mg24.3

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    Gallium is a metallic element found in

    small lasers used in compact discplayers. In a sample of gallium, there is

    60.2% of gallium-69 (68.9 amu) atoms and

    39.8% of gallium-71 (70.9 amu) atoms.What is the atomic mass of gallium?

    LecturePLUS Timberlake 43

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    Ga-69

    68.9 amu x 60.2 = 41.5 amu for 69Ga

    100

    Ga-71 (%/100)70.9 amu x 39.8 = 28.2 amu for 71Ga

    100

    Atomic mass Ga = 69.7 amu

    LecturePLUS Timberlake 44

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    A sample of boron consists of 10B (mass10.0 amu) and 11B (mass 11.0 amu). If theaverage atomic mass of B is 10.8 amu,

    what is the % abundance of each boronisotope?

    LecturePLUS Timberlake 45

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    Assign X and Y values:

    X = % 10B Y = % 11B

    Determine Y in terms of X

    X + Y = 100Y = 100 - X

    Solve for X:

    X (10.0) + (100 - X )(11.0) = 10.8100 100

    Multiply through by 100

    10.0 X + 1100 - 11.0X = 1080

    LecturePLUS Timberlake 46

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    Collect X terms

    10.0 X - 11.0 X = 1080 - 1100

    - 1.0 X = -20

    X = -20 = 20 %10

    B- 1.0

    Y = 100 - X

    % 11B = 100 - 20% = 80% 11B

    LecturePLUS Timberlake 47

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    Copper has two isotopes 63Cu (62.9 amu)and 65Cu (64.9 amu). What is the %abundance of each isotope? (Hint:Check periodic table for atomic mass)