VAPOR-LIQUID EQUILIBRIUM DATA COLLECTION · Continuing the publication of our Vapor-Liquid...

21
J. Gmehling U. Onken W. Arlt VAPOR-LIQUID EQUILIBRIUM DATA COLLECTION Aliphatic Hydrocarbons C1- C1s Chemistry Data Series Vol. I, Part 6b Published by DECHEMA Deutsche Gesellschaft fur Chemisches Apparatewesen, Chemische Technik und Biotechnologie e. V. Executive Editor: Gerhard Kreysa

Transcript of VAPOR-LIQUID EQUILIBRIUM DATA COLLECTION · Continuing the publication of our Vapor-Liquid...

Page 1: VAPOR-LIQUID EQUILIBRIUM DATA COLLECTION · Continuing the publication of our Vapor-Liquid Equilibrium Data Collection we are presenting Part 6, subdivided into Parts 6a and 6b. Completion

J. Gmehling U. Onken W. Arlt

VAPOR-LIQUID EQUILIBRIUM DATA COLLECTION Aliphatic Hydrocarbons

C1- C1s

Chemistry Data Series Vol. I, Part 6b

Published by DECHEMA

Deutsche Gesellschaft fur Chemisches Apparatewesen,

Chemische Technik und Biotechnologie e. V.

Executive Editor: Gerhard Kreysa

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Vapor-Liquid Equilibrium

Data Collection

6b

Aliphatic Hydrocarbons

C7-Cts

Tables and diagrams of data for binary and

multicomponent mixtures up to moderate pressures.

Constants of correlation equations for computer use.

J. Gmehling, U. Onken, W. Arlt

Technische Chemie

Universitat Oldenburg

Universitat Dortmund

lnstitut fOr Verfahrenstechnik

Technische Universitat Berlin

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Die Deutsche Bibliothek- CIP-Einheitsaufnahme

Chemistry data series I publ. by DECHEMA, Deutsche Gesellschaft fOr Chemisches Apparatewesen, Chemische Technik und Biotechnologie e.V. Executive ed.: Gerhard Kreysa.- Frankfurt am Main : DECHEMA.

Teilw. hrsg. von DECHEMA, Deutsche Gesellschaft fOr Chemisches Apparatewesen. - Teilw. hrsg. von Dieter Behrens und Reiner Eckermann. - Teilw. hrsg. von Reiner Eckermann und Gerhard Kreysa

Vol 1. Vapor liquid equilibrium data collection. Pt. 6. Aliphatic hydrocarbons. b. C7- C18• - 2. ed. with minor changes and corr. -1997 Vapor liquid equilibrium data collection I publ. by DECHEMA, Deutsche Gesellschaft fOr Chemisches Apparatewesen, Chemische Technik und Biotechnologie e.V. - Frank­furt am Main : DECHEMA.

Chemistry data series ; Vol. 1) Teilw. hrsg. von DECHEMA, Deutsche Gesellschaft fOr Chemisches Apparatewesen

Pt. 6. Aliphatic hydrocarbons. b. C7 - C18 : tables and diagrams of data for binary and multicomponent mixtures up to moderate pressures ; constants of correlation equations for computer use I J. Gmehling ; U. Onken; W. Arlt.- 2. ed. with minor changes and corr. -1997 ISBN 3-926959-87-8 NE: Gmehling, JOrgen

© DECHEMA Deutsche Gesellschaft fOr Chemisches Apparatewesen, Chemische Technik und Biotechnologie e. V. Postfach 15 01 04, D-60061 Frankfurt am Main, Germany, 1997

Dieses Werk ist urheberrechtlich geschOtzt. Alle Rechte, auch die der Obersetzung, des Nach­drucks und der Vervielfii.ltigung des Buches oder Teilen daraus sind vorbehalten.

Kein Teil des Werkes dart ohne schriftliche Genehmigung der DECHEMA in irgendeiner Form (Fotokopie, Mikrofilm oder einem anderen Verfahren), auch nicht fOr Zwecke der Unterrichts­gestaltung, reproduziert oder unter Verwendung elektronischer Systeme verarbeitet, vervielfii.l­tigt oder verbreitet werden.

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This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, including those of translation, reprinting, reproduction by photocopying machine or similar means.

No part of this work may be reproduced, processed or distributed in any form, not even for teaching purposes - by photocopying, microfilm or other processes, or implement in electronic information storage and retrieval systems- without the written permission of the publishers.

The publishers accept no liability for the accuracy and completeness of the published data.

This volume of the Chemistry Data Series was printed using acid-free paper.

Printed by Sch6n & Wetzel GmbH, D-60599 Frankfurt am Main, Germany

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6b Aliphatic Hydrocarbons

c7-C1s

Systems with:

1 ,5-Cyclooctadiene

Decahydronaphthalene

Decane

�X-Dicyclopentadiene

2,3-Dimethylpentane

2,4-Dimethylpentane

Dodecane

Ethylcyclohexane

Heptadecane

Heptane

1-Heptene

2-Heptene

3-Heptene

Hexadecane

1-Hexadecene

lsopropylcyclohexane

Methylcyclohexane

3-Methylheptane

3-Methylhexane

Nonane

1-0ctadecene

Octane

1-0ctene

<X-Pinene

Tetradecane

2,2,3-Trimethylbutane

1 ,3,5-Trimethylcyclohexane

2,2,5-Trimethylhexane

2,2,4-Trimethylpentane

Undecane

2-Vinyl-(2,2, 1 )-bicycloheptane

2-Vinyl-(2,2, 1 )-bicyclo-5-heptene

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VI

SUBJECTS OF VOLUME I

The table lists the parts of Volume I already published or in preparation.

Subtitle Vol. I, Part

Aqueous Systems 1 (1980) Supplement 1 1a (1981) Supplement 2 1b (1988)

Organic Hydroxy Compounds Alcohols 2a (1977) Alcohols and Phenols 2b (1978) Supplement 1 2c (1982) Supplement 2 2d (1982) Supplement 3 2e (1988) Supplement 4 2f (1990)

Aldehydes, Ketones, Ethers 3/4 (1979) Supplement 1 , Aldehydes 3a (1993) Supplement 1 , Ketones 3b (1993) Supplement 1 , Ethers 4a (1994)

Carboxylic Acids, Anhydrides, Esters 5 (1982) Supplement 1 5a (in prep.)

Aliphatic Hydrocarbons C4-C6 6a (1980)

Aliphatic Hydrocarbons C7-C18 6b (1980)

Supplement 1 6c (1984) Supplement 2 6d (in prep.)

Aromatic Hydrocarbons 7 (1980) Supplement 1 7a (in prep.)

Halogen, Nitrogen, Sulfur and other Compounds 8 (1984)

Supplement 1 Sa (in prep.)

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VII

AUTHORS' PREFACE

Continuing the publication of our Vapor-Liquid Equilibrium Data Collection we are presenting Part 6, subdivided into Parts 6a and 6b. Completion of Part 5 has been postponed, because in correlating systems containing carboxylic acids we also intend to include vapor phase non-ideality for more than one associa­ting component in a system; programming of this calculation procedure has not yet been finished.

From Part 5 onwards, parameters of activity coefficient equations are also given for "incomplete" x-y data (isothermal without P, resp. isobaric without T). In these cases, equilibrium ratios y/x have been used in the objective function for parameter optimization. A further additional information in the tables from Part 5 onwards concerns incomplete isothermal x-y data; here the result of the consistency test by method 2 (area test of Redlich and Kister) is given.

We again express our thanks to the great number of colleagues who have sup­ported our efforts by supplying VLE data from their laboratories. On this occasion we should like to repeat our plea to all workers in the field of vapor-liquid equilibrium to send us reprints of new experimental results.

·

Special thanks are due to Dipi.-Phys. G. Schwichtenberg, head of the computer center of the University of Dortmund, and to his staff, especially to H. Forster and U. Liebegut, for their co-operation. We are also grateful to Dr. R. Ecker­mann (DECHEMA, Frankfurt/M.) for his efforts in editing the data collection.

Finally, we wish to thank all members of our team who helped in the prepara­tion of Part 6 of the VLE Data Collection; these are: Mrs. U. Arlt, Dipl.-lng. P. Grenzheuser, Miss G. Hennig, W. Kirchhoff, Dipl.-lng. B. Kolbe, Mrs. S. Koort, Mrs. L. Kunzner, Dr. G. Nocon.

Dortmund, January 1980

Ulfert Onken Jurgen Gmehling Wolfgang Arlt

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VIII

PREFACE OF EDITORS

Subjects of this series are the physical and thermodynamic property data of chemica.l compounds and mixtures essentially for the fluid state covering PVT data, heat capacity, enthalpy, and entropy data, phase equilibrium data, transport and interfacial tension data.

The main purpose is to prov·ide chemists and engineers with data for process design and development. For computer based calculations in process design appropriate correlation methods and accurate data must be used. These are only in some cases available in the open literature. For that reason the most urgent requirement regarding the publication of data is to offer classified and critically evaluated data, thus giving an impression which of them are reliable or not. This will be the goal of the series.

DECHEMA gives the opportunity to authors especially from universities to publish not only their theoretical results, but also their measured or compiled data, most often a large amount, that would otherwise never have been published.

The work of Dr. Gmehling, Prof. Onken and Dipi.-Chem. Arlt on vapor-liquid equilibnia which was supported by the Federal Ministry of Research and Tech­nology and DECHEMA has been very fruitful; in particular, it led to an extension of the UNIFAC method. The authors have produced what is probablyfhe largest collection of vapor-liquid equilibrium data that is today available with evalua­tion programs and experimental data.

We present the evaluation of this material in several parts of the first volume of the series. We hope that this gives particularly the users an instrument that will allow them to solve their problems considerably more easily and quickly than before.

Frankturt/Main, January 1980 Dieter Behrens Reiner Eckermann

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Subjects of Volume I

CONTENTS Vol. I, Part 6b

Authors' Preface 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 • • • • • • • • •

Preface of Editors 0 0 • 0 0 0 • • • • • • • • 0 • 0 0 0 • • 0 0 • 0 0 • • • • • • • • • 0 0 0 • 0 • 0 • • • • 0 •

Contents Volume I, Part 6b . 0 0 • 0 • 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 • • • 0 • • • • • • • • • • • • 0

Contents Volume I, Part 1 . . . . . . . . 0 0 • 0 • • • 0 • • • 0 • • 0 • • • • • • • 0 • 0 • • 0 • • • •

Contents Volume I, Part 2a 0 • • • 0 • • 0 • • • 0 0 0 0 • • 0 0 0 0 • 0 0 0 0 0 0 0 • 0 • • • 0 • • •

Contents Volume I, Part 2b . 0 • • 0 0 0 0 • 0 • • • • 0 0 0 0 0 0 0 0 0 • 0 • • • • • • • • • • 0 • •

IX

VI

VII

VIII

IX

XI

XII

XIII

Contents Volume I, Parts 3+4 0 • • 0 • 0 0 0 0 0 0 • • 0 0 0 0 0 • • 0 0 • • • • • • • 0 • • • 0 • 0 XV

Contents Volume I, Part 6a . . 0 0 • 0 0 0 0 0 0 0 0 0 0 0 • • 0 0 0 0 0 • • • • • • • • • • • • • • • XVII

Guide to Tables 0 0 0 • 0 0 0 • • • 0 0 • • 0 • • 0 • 0 • 0 • 0 0 0 • • 0 0 • • 0 0 0 • 0 0 • • • 0 • • • 0 • • XIX

List of Symbols 0 • • • 0 • 0 • 0 0 • • 0 • 0 • 0 0 0 • • 0 • 0 0 0 0 0 0 0 0 0 0 0 • 0 0 • • 0 • • 0 • • • • • • • XXIX

References 0 0 0 • 0 • 0 • 0 0 • 0 • • • 0 0 • 0 0 • 0 0 • • • 0 • • • 0 • 0 0 0 • • • 0 0 • • • • • • • • • 0 • • XXXI

Data Tables

Binary Systems . 0 • • • • • • • • 0 • • • • • 0 • • • 0 0 0 • 0 • 0 0 0 • • • 0 • • • 0 0 0 0 • 0 • 0 • 0

1-Heptene 0 0 0 0 0 0 . 0 0 0 0 0 0 0 . 0 . 0 0 • • 0 . 0 0 0 0 • 0 0 • • • • 0 • 0 • • • • 0 . 0 . 0 . 0

2-Heptene . 0 0 • 0 • • 0 0 • • • • • • 0 • • 0 0 • 0 • 0 0 0 0 • 0 0 0 • 0 • 0 • • 0 • 0 • 0 • 0 0 • 0 • 4

3-Heptene 0 • • • • 0 • 0 0 0 0 • 0 • 0 • 0 0 0 0 • • • • • 0 0 • 0 • • • • • 0 • • • • • • • • • • • 0 • 5

Methylcyclohexane 6

2,3-Dimethylpentane . . . . . . . . 0 • • • • • 0 • • • • • • • • • • • • • 0 • • • • 0 • 0 0 0 • • 60

2,4-Dimethylpentane 0 • • • • 0 • • • • • • • • • • • • • • • • • • • • • • • • 0 • • 0 0 0 0 0 • • 61

Heptane . . . . . 0 • • • 0 • • • • • • • • • • • • • 0 • • • 0 • • 0 0 . 0 • • • 0 • • 0 . . . . . . . . . 67

3-Methylhexane . . . . . . . . . . . 0 • • • • • • • • • 0 • • • • • • • • • 0 • • • • 0 0 • 0 0 0 • 0 201

2,2,3-Trimethylbutane 0 • • • • • 0 • • • 0 • • • 0 • • • • • • • • • • • • • • • • 0 • • • • 0 • 206

1 ,5-Cyclooctadiene . . . . . . . . . . . . 0 0 • 0 0 • • 0 0 0 • • 0 0 • 0 0 0 0 • • • • • 0 0 • • 208

Ethylcyclohexane . 0 0 • • • • • • • • • 0 0 . 0 • • • • • • 0 0 . 0 • • • • • • • • • • • • 0 • 0 . 214

1-0ctene . 0 . 0 • • • • • • • 0 0 • • 0 • • 0 0 . 0 0 0 0 • • • • 0 • • • • • • • • 0 0 . 0 . 0 . 0 . 0 . 0 216

3-Methylheptane . . . . . . . . . . 0 • 0 0 • 0 • 0 0 0 • • 0 0 0 0 • 0 0 0 0 • • 0 0 • • 0 • • • • 224

Octane 0 0 0 0 . 0 . 0 0 0 • • • 0 • • • 0 . 0 • • • • 0 0 . 0 0 0 0 . 0 0 0 0 . 0 • • • • • 0 0 0 . 0 0 0 . 0 231

2,2,4-Trimethylpentane . . . . . . 0 • 0 • • 0 0 • 0 • • • 0 0 • • • 0 • • • • • 0 • • 0 • 0 • 0 0 284

2-Vinyl-(2,2,1)-bicyclo-5-heptene . . 0 0 • • • • • • • • 0 • • • • 0 . 0 . 0 0 . 0 0 . 0 334

2-Vi nyl-(2,2, 1 )-bicycloheptane . . 0 • 0 0 • • 0 • • • 0 • • • • • • • • 0 • • 0 • • • • • • • 341

lsopropylcyclohexane . 0 • 0 • 0 0 • • 0 • 0 • 0 • • • • • • 0 0 • 0 • 0 0 • • • 0 • • • 0 • • • 343

cis-1 ,3,5-Trimethylcyclohexane . . 0 0 0 0 0 0 0 • • • 0 • 0 • • • 0 0 • 0 0 • • 0 0 • 0 • 344

Nonane 0 0 0 • • • • • • • 0 0 • • 0 • • • • 0 0 0 0 0 0 0 0 • • • • 0 • • • • 0 . 0 0 0 . . . . . . . . . 348

2,2,5-Trimethylhexane 0 . 0 0 • • 0 . 0 0 0 . 0 . 0 . 0 0 • • • • 0 • • 0 0 . 0 . 0 • • • 0 . . . 357

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X

a-Dicyclopentadiene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 359

a-Pinene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 361

trans-Decahydronaphthalene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 372

Decane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 383

Undecane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 409

Dodecane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 410

Tetradecane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 425

1-Hexadecene

Hexadecane ............................................. .

Heptadecane ............................................. .

1-0ctadecene ............................................. .

Ternary Systems ............................................. .

1-Heptene ............................................... .

Methylcyclohexane ....................................... .

2,3-Dimethylpentane ....................................... .

Heptane ................................................. .

Octane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Decane

Quaternary Systems ......................................... .

Decane

445

446

453

456

463

463

464

469

470

477

479

485

485

Appendix A: Pure Component Parameters . . . . . . . . . . . . . . . . . . . . . . . . . . 489

Formula Index of Systems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 495

Alphabetical Index of Systems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 501

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1ST CJMPONENT

C4H9SR

C7'ti16

C8H 1 3

C7H1 4

CSH?N

C7H14

C?H1 S

C7H14

C2H3MOZ

CH6

CSH6

C SH?N

C jH11 CL

C7F14

C 7H l

C7H16

C8H 10

C3H19

495

Formula Index of Systemrs

R=RECOMMENDED VALUES

1 -HEP T EN E

BUTYL BROMIDE

HEPTI\NE

OCTANE

Z-HEPTENE

ANILINE

3-HEPT E•�E

HEPT!.NE

METHYL CYC LOHEXANE

TET R ACH LO ROME TH A NE

N !TROETHANE

HEXAFLUOR03ENZENE

BENZENE

ANILINE

CHLOROCYCLOHEXANE

CYCLOHEXY UHI�E

P ER FLUOROII ETH Y LCY C LOHEX AN E

TOLUENE

HEPTA�E

ETHYLBENZENE

2, 2,4-TRlMETH YLPEN TANE

cRD CCMPUNENT HH COfiPON ENT

C 3H1 8

C7H9 T O LU ENE

C7H16 HEPTANE

PAGE

463

4

6

8- 9

10- 12

13- 18 18 R

464-466

19- 21

2?- 25

30- 46 46 R

467-468

4 7- 53 53 R

54- �6

57- 5Q =========================================================== �=============================================

C ?H 1 S 2,3-0IMETHYLPENTANE

Co H6 BENZENE 6f

C12F27N PERFLUOROTRIBUTYLAMINE 469

2,4-0IHETHYLPENTANE

CCL4 TETR�CHLOROMETHANE 61

CSH6 B EN Z ENE

C?H16

C ':L4 TETRACHLOROMETHANE 67- 73

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496

Formula Index of System�s

= =�=========================================== =============== ============ ================================

C7H1S HEPT.1NE

C HCL3 CHLOROFOHrl

C6H6

C�HJN �CETONITRILE

C6H6

ETHYL BROH IDE

C2H51 ETHYL IODIDE

C �HS �o N-HETHYLFORMAHIOE

N ITROETHANE

C3H7�0 N,N-OIMETHYLFOR�AMIDE

C3H7N02 1-NITROPRJPANE

C31C'M02 2-NITROPRJPANE

C 4 C l3 F7 2.2,3-TRICHLOROHEPTAFLUOROBUTANE

C4H4S THIOPHENE

C6H6

C·>H98R BUTYL BROtH DE

C4H9CL BUTYL CHLuRIDE

C4H9�0 METHYL ETHYl KETOXIHE

C4H 11N BUTYLAIH NE

C 4H 11 N Dl ETHY lAM !NE

C>HSN PYRIDnE

C IH 5CL CHlOROBENZENE

C6H6 BENZENE

C6H7N ANILINE

C7H8

C�H15N TRIETHYLAMINE

c�FH PERFLUOROHEPTANE

C7H3 TOlUENE

C8H10 P-XYLEIIE

C3 H18 OCTANE

C 3H 18 2,2,4-TRIMETHYLPENTANE

C9H12 ISOPROPYlBENZENE

C7H1� 3-HETHY LHEXANE

CSH6 BENZENE

C?H1� PROPYLBENZ ENE

2,2,3-TRIMETHYLBUTANE

C IH 5 BENZENE

9ENZENE

�ENZENE

BENZENE

TOlUENE

74- 78 'R R

471-474

86

87- �9 R

90- Q1

92

93- 9�

99

101

102

�75

104

105-10� HB R

111-112

113-116

117-119

159-1�1

47h

162-164 164

165-H7

16�-HS 1 � 5 R

186-1R7

1 88-19 5

196-107

198-2�0

?06-?07

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C lHP

C lH1 �

C lHlS

C3H18

CJH18

C3H1�

C9H1�

C9H1 �

C10H12

C3HU

CJH 13

C CL4

ClH10

C JH 13

C CL4

C7F1o

CCL4

CZH 5N02

C �H7tl

CSH5N

C6H5N02

C SH S

C7H8

C3H10

C lH10

C8H1o

C3H1.3

4,7,J, �-TETRC\HYDROINOENE

497

Formula Index of Systemts

2-Vl��L-(2,2,1)-S!CYCL0-5-HEPTENE ?10 -211

ALPH�-J!CYCLOPE�TAD!ENE (ENDO)

ETHYLCYCLOHEXA�E

ETHYLBENZENE

OCTANE

1-0CTE �E

TETRACHLOROMETH�NE

BENZENE

E THYLBENZENE

OCTANE

3-METHYLHEPnNE

TETRACHLOROMETHANE

PERFLUOROHEPTANE

OCTANE

TETRACHLORC"ETHANE

NITROETHANE

C8H18

BUTYRON !!RI LE

PYRID!NE

NITROBENZENE

BENZENE

CYCLOHEXANE

TOLUENE

ETHYLBENZ ENE

P-XYLENE

ETHYLCYCLOHEXA�E

2,2,4-TRIMETHYLPENTANE

2,2,4-TRI�ETHYLPENTANE

2,2,4-TR!METHYLPENTANE

ETHYLBENI ENE

21 2-?13

21•

215

2H

21 7-218

?19

220-2'3

227-'30

231-234

'35

477

236

23 7-24e 240

241

242-250

25 1-? <3

254-269 269 R

478

270-274 274 R

275

282-283

-----------------------------------------------------------------------------------�-----

284-�9� ?.90 R

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498

Formula Index of System�s

=========================================================================================================

ClfilR3

C�H5'W?.

C .. H7:-l

C3H 3N

C6H5N02

C )H6

C6H?N

C7F16

C3H 10

C9H1�

OH1�

C9H12

C�H14

C9H1;

C9H14

C9H16

C9H1�

C9H18

C SF1 �

C9H2�

CH5N

C 3H )N

C7H9N

C9H2"1

C8H1�

C 1 �H 1 �

C6H1

C?H�

2,2,4-TRl�ETHYLPENTAHE

TR I BROf10NE 1 H .\ll E

NITROETHANE

BUTYRON !BI L E

PYR IHflE

NITROBENZENE

BENZENE

ANILINE

PERFLUOROHEPTANE

TOLUENE

E TH YLB ENZENE

2-VJNYL-12,2,1J-BICYCL0-5-HEPTEUE

2-ETHYLIOE�E-12,2,1l-BICYCL0-5-HEPTE�E

4,7,8,9-TETRAHYDqOJNDENE

2-VINYl-(�,2,1)-BlCYCLOHEPTANE

2-ETHYL-12,',1)-SICYCLOHEPTANE

2-Vl�Yl-(Z,2,1l-aiCYCLOHEPTANE

2-ETHYL-12,2,1J-BICYCLOHEPTANE

!SOPROPYLCYCLOHEXA�E

HEXAflUOROBENZENE

C!S-(1,3,5J-TRIMETHYLCYCLOHEX,NE

P ERFLUOROCYCLOHEXANE

NON AN E

ME THYLA'U �lE

PYRIO!NE

l,4-0IMETHYLPYR!Ol�E

2,2,5-TRINETHYLHEXANE

TET R"C H LO RO�ETH ANE

E T HYLBENZENE

ALPHA-OICYCLOPE�TAOIENE

BENZENE

TOLUENE

291

292-205 2 Q5 Q

296

297-301

30?

H3-312 31' R

313-3H

119-321

334-315

337-338

341-3£2

343

344-34 7

34R-351

352-355 3 55 •

356

357

35o

Page 14: VAPOR-LIQUID EQUILIBRIUM DATA COLLECTION · Continuing the publication of our Vapor-Liquid Equilibrium Data Collection we are presenting Part 6, subdivided into Parts 6a and 6b. Completion

C1 "'H 15 �lPH\-PIN!:NE

OELTA-�-CARENE

C 1 �H 1·1 LIMONENE

C 10H 16 BETA-PINENE

ClOH 13 TRANS-OlCAHYORJNAPHTHALENE

1.2,3-TRI�ETHYLBENZENE

C?H12 1 ,2,4-TRIMETHYLBENZENE

C 10H 22 0 ECAHE

C1-bH�2 OECANE

HETHA!lETHIOL

CSHSN PYR!OINE

C IH 3C l CHLOROBENZENE

C7H9N 2, 6-0l :1ETH lLPYHOI NE

C7H9� 0 -METHYLAN lL !'lE

C9H12 1,2,3-TRIHETHYldENZENE

C9H1Z 1,2,+-TRIMETHYLBENZENE

C9H12 1,1,5-TRIAETHYLBENZENE

C11H�4 UNOECA lE

C7H?N 2,4-0!HETHYLPYRIOINE

C1lH�� DODECANE

Cl 3H8 NAPHTHALE'IE

Cl >H32 1-HEXADECtNE

C18H36 1-0CTADECENE

TETRADECA!IE

C IH6 BENZENE

C 1 �H3 NAPHTHALENE

C15H.32 1-HEXADECENE

C1oH32 1-HEXAOECENE

C 10H8 NAPHTHALENE

499

Formula Index of Systemts

C9H12

C9H12 C9H 1 2

C9H12

C9H12

C9H12

1,�,4-TRIMETHYLBENZENE

1,2,4-TRIMETHYLBENZENE 1,3,5-TRIMETHYLBE�ZENE

1,2,5-TRIMETHYLBENZENE

1,3,5-TRIMETHYLBENZENE

1,2,5-TRIHETHYLBENZENE

361

36l

363-371

172-373

3H-V5

376-382

383

384-3�6

387-392

393

394

�95-399

479-430

48�-486

481

482

410-404

483-484

4�5-4�8

410-411

412-417

418-424

4�5-427

428-43 5

436-44 4 , 444 R

445

Page 15: VAPOR-LIQUID EQUILIBRIUM DATA COLLECTION · Continuing the publication of our Vapor-Liquid Equilibrium Data Collection we are presenting Part 6, subdivided into Parts 6a and 6b. Completion

500

Formula Index of System�s

C16H34 HEXA�EnNE

C CL4 TETR�CHLORO�ETHANE 44�-44 7

C �H6 BENZENE

C1 lH36 HEPT\OECAH

C5H6 BENZENE 453-4�5

1-0CTADECENE

C1 IH3 NAPHTH.ILENE 456-462

Page 16: VAPOR-LIQUID EQUILIBRIUM DATA COLLECTION · Continuing the publication of our Vapor-Liquid Equilibrium Data Collection we are presenting Part 6, subdivided into Parts 6a and 6b. Completion

501

Alphabetical Index of Systems

==================�============================================================================= =========

1ST COMPONENT

1,5-CYCLOOCT�DIENE

2ND COMPONENT

�LPHA-DICYCLOPENTADIENE (ENDO)

.t, 7, .3, �-TETRAHYORO INDENE

2-VINYL-<2,2,1)­BICYCL0-5-HEPTENE

TRANS-DECAHYDRO�APHTHALENE

DECANE

1,2,3-TRIMETHYLBENZENE

1,2,4-TRIMETHYLSENZENE

DE CANE

CH LO ROBENZENE

2,6-DIMETHYLPYRIOINE

0- METHYLANI LINE

PYRI DINE

1,2,3-TRJMETKYLBENZENE

1,2,4-TRIHETHYLBENZENE

1,3,5-TRIMETHYLBENZENE

]LPHA-DICYCLOPENTADIENE

BENZENE

TOLUENE

�.3-nt1ETHYLPENTANE

BENZENE

BENZENE

TETRACHLOROMETHANE

C8H12

C11H12

C9H12

C9H12

C !eH 18

CUH22

C9H12

C9H12

CUH22

C6H5 CL

C7H9N

CH4S

C7H9N

CSHSN

C9H 1�

C9H1 2

C9H1 2

C10H12

C6H6

C7H8

C7H16

C6H6

C7H16

C6H6

C C L4

3RD COMPONENT 4TH COMPONENT

1,2,.-TRIMETHYLBENZENE

1,2,4-TRIHETHYLBENZENE 1,3,5-TRIMETHYLBENZENE

1,2,5-TRIHETHYLBENZENE

1,3,5-TRIMETHYLBENZENE

1,2,5-TRIMETHYLBENIENE

PERFLUOROTRIBUTYL­AHINE

C9H12

C9H1 2 C9H12

C9H12

C9H12

C9H12

C12F27N

21?.-213

20�-209

ZH-211

37�-3R2

372-373

3H-375

387-392

393

383

394

384-3 �6

395-39Q

479-480

485-4�6

481

482

400-4414

359

36�

60

62- M R

61

Page 17: VAPOR-LIQUID EQUILIBRIUM DATA COLLECTION · Continuing the publication of our Vapor-Liquid Equilibrium Data Collection we are presenting Part 6, subdivided into Parts 6a and 6b. Completion

502

Alphabetical Index of Systems

============= =========================================== =========================== == == ==================

D•)DEC.HE C12H26

1-HEXADECENE C 16H32

N4PHTHALENE C10H8

1-0CHDECENE C 18H 36

ETHYLCYClDHEX�NE C8H16

ETHYlBENZEtlE C8H10

OCTANE C8H18

HEPT�DECANE C17H36

BENZENE C6H6

HEPH�E C7H16

ACETONITRILE C2H3N

AN I liNE C6H7N

BENZENE C6H6

BUTY LAM! �E C4H11N

BUTYL BROHIDE C4H9BR

BUTYl CHlORIDE C4H9CL

CH lOROBEN ZEN E C6H5CL

CHlOROFORH CH Cl3

DIETHYl.�MINE C4H11N

C3H7NO

ETHYl BROHIOE C2H5B R

ETHYL !OD I DE C2H5I

ISOPROPYlBENZENE C9H12

METHYl ETHYL KETOXIME C4H9NO

�-METHYlFORH A MIDE C2H5NO

NI TROETHANE C 2H5N02

1-N ITROPROP.\NE C3H7N02

2-N ITROPROPA•lE C3H7N02

OCTANE C8H18

PERFLUOROHEPHNE C7F16

PYRIDI NE C5H5N

TETRACHlOROHETH�NE cc l4

THIOPHENE C 4H4S

BENZEii[ C6H S

TOlUENE C?H8

BENZENE C6H6

BENZENE C6Hh

4P-4• 7

215

453-455

70- 85

150-1h1

476

103

117-110

470

111-112

93- 98

86

87- 89 R

198-200

105-H8 1tA R

H- 91

92

90

165-167

102

475

Page 18: VAPOR-LIQUID EQUILIBRIUM DATA COLLECTION · Continuing the publication of our Vapor-Liquid Equilibrium Data Collection we are presenting Part 6, subdivided into Parts 6a and 6b. Completion

503

Alphabetical Index of Systems

==;===============�=================================================================================== ===

H cPT\.�E

1-H EPTENE

C7H16

TOLUENE C7H8

?. :,3-TRICHLOROHEPTAFLUORO-BUTANE C 4CL3F7

TRIETHYL.\!HNE C6H1 5N

�,2,4-TRIMETHYLPENT�NE C8H18

P-XYLENE C8H10

C 7H14

BUTYL BROHIDE C4H9BR

HEPT ANE C7H16

OCTANE C8HH

0 CTA:lE C8H18

101

162-1�·

164 •

196-197

1�6-1�7

3 =========================================================================================================

�-HEPTENE C7H1 4

ANI LINE C6H7N 4

3-HEPTENE C7H14

HEPTANE C7H 1 6

HEX<nCHE C16H34

BENZENE C6H6 448-45>

TETRACHLORO'�ETH \NE CC L4 446-H7

1-tfC:Xt\DECENE C16H32

NAPHTHALENE C 10H8 H5

ISOP�CPYLCYCLOHEXA•E C9H18

HEXAFLUOROBENZENE C6F6 H3 ================================== ============================�==========================================

NETHYLCYCLOHEXANE C7H14

ANILINE C6H7N

BENZENE C6H6

CH LORO CV C LO HEX AN E C6H1HL

CY C lO HEXY LAt·1 I ��E C6H13N

E TH Yl8EN ZENE C8H10

HEPTANE C7HH

HEXAFLUOROBENZE"E C6F6

NITRUETH\�E C 2H5NO?

TOLUENE C7H8

13- 18

18 R

464-461>

H- 12

19- � 1

22- 25

54- 56

4 7- 53 53 R

8-

Page 19: VAPOR-LIQUID EQUILIBRIUM DATA COLLECTION · Continuing the publication of our Vapor-Liquid Equilibrium Data Collection we are presenting Part 6, subdivided into Parts 6a and 6b. Completion

504

Alphabetical Index of Systems

�cTHVLCYCLOHEXANE

3-HETH YLH EP TANE

3-ilETHYLH EXANE

NON AN E

1-0CT ADECENE

C7H14

PERFLUOKUMETHYLCYCLO-H E XAN E C7F14

TETRACHLOROMETHANE CCL4

TOLUENE C7 H8

�.2,i-TRIMETHYLPENTANl C8H 1 8

C8H18

PERFLUOROHEPTANE C7F16

TETRACHLOROMETH\NE CCL4

C7H16

BENZENE C6H6

PROPYLBENZ ENE C9H12

C9H20

2,4-DIHETHYLPYRIDINE C7H9N

METHYll\I'IINE CH5N

PYRIDINE C5H5N

C 18H 36

NAPHTHALENE C1tH8

C8H1 8

BENZENE C6H6

BUTYRONI TR LLE C4H7N

CYCLOHEXAN E C6H1 2

E THYLBENZENE C8H10

ETHY LCY CLOHEXANE C8H16

NITROBEN Z ENE C6H5N02

NI TROETHANE C 2 H 5N02

P YRIOINE C5H 5N

TETRACHLOROMETHANE CCL4

H EPTANE C7H16

2,2,\-T�IMETHYLPENTANE C3H13

2A- 29

6

467-46�

57- 59

203-2� 5

356

348-351

352-355

355

\56-4�2

2H-2�e

236

251-253

276-2P1 2�1 R

241

235

477

23 7 -21,.

240 �

'23 1-?.34 ----------------------------------------------------------------------------r ---

TOLUENE C7H8 254-2�9

21'19 R

ETHYLBENZENE C8H10 47�

2,2,4-TRIMETHYLP�NTANE C8H18 �82 -2�3

P-X YLE NE C8HH 275

Page 20: VAPOR-LIQUID EQUILIBRIUM DATA COLLECTION · Continuing the publication of our Vapor-Liquid Equilibrium Data Collection we are presenting Part 6, subdivided into Parts 6a and 6b. Completion

1-JCTE:IE

BENZENE

ETHYl BE�l EN E

OCTANE

TETRACHLORUMETHANE

J :LT A-3-CAPENE

LJI'IONENE

B ETA-P I�ENE

TETR ADECANE

BENZENE

1 -HEXADECENE

NAPHTHALENE

2,;,1-TRIMETHYLBUT�NE

BENZENE

C8H16

C6H6

CoH1t

C8H18

C CL4

C10H16

C10H16

C10H16

C10H 16

C14H3o

C6H6

C16H32

C 1 0H8

C7H16

C6H6

505

Alphabetical Index of Systems

?.19

?16

3�2

363-371

436-444 4H P

::: == ==== = == ==== === = ;;::;::; =:::; = ===== == === = ==== ===== = = == === === =========:::== ===.= == :;::::::::::::===== == ==== ========= == ====== =

CIS-(1,3,5l-TRIHETHYLCYCLOHEXANE C9H18

2,2,5-TRIMETHYLHEX�NE

�. -�,4-TRIMETHYLPENTAt�E

PERFLUOROCYCLOHE X�NE C6F12

C9H2 0

ETHYLBENZENE C8H10

TETRA CHLOROMETHANE CCL4

C8H18

ANILINE C6H7N

BENZENE C6H6

BUTYRON!TRILE C4H7N

ETHYLBENZ ENE C8HH

N ITROBENZ CNE C6H5N02

�ITROETHANE C2H5N02

PERFLUOROHEPTANE C7 F16

PYRIDINE C5H5N

TETRACHL090MCTHANE CC L4

TOLUENE C7HB

CHBR3

144-347

358

357

313-318

303-312

31>

29�

319-321

3V-33o

330 R

291

Page 21: VAPOR-LIQUID EQUILIBRIUM DATA COLLECTION · Continuing the publication of our Vapor-Liquid Equilibrium Data Collection we are presenting Part 6, subdivided into Parts 6a and 6b. Completion

506

Alphabetical Index of Systems

'J.JI)€';-\ �E

2, 4-0!METHYL�YRI�lllE

�-V I� YL- (?, 2, 1 ) -8 [ CYC lOHE PT ANE

2-fTHYL-<:, �.1 >­�ICYCLOHEPTA'l

�-VINYL- (2,?, 1) -B! :vc LO -5 -HfPTENE

�-ETHYl-C..!, 2, 1)­B!CYCLOHEPTAr�E

�-ETHYllDENE-(2,�,1)­BICYCL0-5-HEPTENE

'+,7, !!,9-TETRAHYDROIN;)ENE

2-VINYL-C;!, 2., 1 )­BICYCLOHEPJA,�E

C11H24

C 7 H9N

C9H14

C9H16

C9H12

C9H16

C9H12

C9H12

C9H14

�36